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ChBE 11: Chemical Engineering Thermodynamics
ChBE 11: Chemical Engineering Thermodynamics

... – If the system is free from forced flows, it will eventually achieve equilibrium – The Pliq = Pvap and Tliq = Tvap with more than one phase present with no tendency to change ...
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... on that sheet, not written in the booklet. Each student should be provided with an answer sheet and scratch paper, both of which must be turned in with the test booklet at the end of the examination. Local Sections may use an answer sheet of their own choice. The full examination consists of 60 mult ...
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Chapter 1.1 –Chemistry is a Physical Science Chemistry is one of

... The building blocks of matter are atoms. An atom is the smallest unit of an element that maintains the chemical identity of that  element. An element is a pure substance that cannot be broken down into simpler, stable substances and is made of only one type  of atom. A compound is a substance that c ...
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... boundaries prevent the flow of matter into and out of it (they are impermeable), whereas in an open system the boundaries permit such flow. The portion of the remainder of the universe that can exchange energy and matter with the system is the surroundings. Heat, q, is the amount of kinetic energy t ...
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... • Physical change: • A change in the state of matter. It does not involve a change in the substances. E.g. melting of wax and water. • Chemical change: • A change involving at least one of the substances making the matter. E.g. Electrolysis of water, formation of rust: reaction of iron and oxygen to ...
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Shifting Equilibrium

... because changing the temperature changes the relative amounts of reactants and products. Increasing the temperature is, in effect, the addition of energy in the form of heat. According to Le Châtelier’s principle, the stress of the added heat will be lessened by shifting the equilibrium in the direc ...
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Cheat Sheet for Chemical Equilibrium
Cheat Sheet for Chemical Equilibrium

... values.

They
therefore
need
different
concentrations
of
one
anion
for
precipitation
to
occur.
 • ∆G
=
∆G°
+
RTlnQ
‐
formula
used
to
relate
Gibbs
Free
Energy
at
standard
and
non‐standard
 ...
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... 3- Given the same number of moles of two gases at STP conditions, how do the volumes of two gases compare? How do the masses of the two gas samples compare? 4- How many moles of helium are contained in each volume at STP: (a) 5.0 L; (b) 11.2 L; (c) 50.0 mL? 5- How many moles of argon are contained i ...
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... Draw free-body diagrams. (This is a diagram that shows the relative magnitudes and directions of forces acting on a body/particle that has been isolated from its surroundings) Resolve a two-dimensional force (such as the weight of an object on an inclined plane) into its parallel (x) and perpendicul ...
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... c. neither a nor b b. chemical equilibrium. d. both a and b 8. According to collision theory, in order for a chemical reaction to occur, the reactant atoms must: a. make contact with each other. b. have a minimum level of kinetic energy. c. form an activated complex. d. all of the above ...
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... The student decided to use a measuring cylinder to obtain 25.0 cm3 of the supplier’s solution. This was poured into a 250 cm3 graduated flask and the liquid level was made up to the mark with de-ionised water. The student filled a burette with the acid solution. The following results were obtained w ...
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... The last page of this examination is a periodic table [Gas constant = 8.314 J/mol K; 0.08206 L*atm/mole*K,1 faraday = 96500 J/V mol e-; at 25oC] 1) The reaction has the rate law, Rate = k[A][B]2. Which will cause the rate to increase the most? A) doubling [A] B) doubling [B] C) tripling [B] D) quadr ...
Thermodynamics
Thermodynamics

... From knowing the value of ∆G, you may predict whether a process/reaction will be spontaneous at a certain temperature. A process is spontaneous if ∆G is negative (∆G < 0), nonspontaneous if ∆G is positive (∆G > 0), and at equilibrium if ∆G = 0. The enthalpy change, ∆Hrxn, is the heat gained or lost ...
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Thermomechanical analysis

Thermomechanical analysis (TMA) is a technique used in thermal analysis, a branch of materials science which studies the properties of materials as they change with temperature.Thermomechanical analysis is a subdiscipline of the thermomechanometry (TM) technique.
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