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Chapter13
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... thermodynamics. Spontaneous processes occur due to and increase in the total entropy (S), i.e. DS > 0 for the system plus the surrounding. For example, exothermic chemical reactions are often spontaneous because of increases in disorder of the surrounding caused by the release of heat. ...
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Maximum entropy thermodynamics

In physics, maximum entropy thermodynamics (colloquially, MaxEnt thermodynamics) views equilibrium thermodynamics and statistical mechanics as inference processes. More specifically, MaxEnt applies inference techniques rooted in Shannon information theory, Bayesian probability, and the principle of maximum entropy. These techniques are relevant to any situation requiring prediction from incomplete or insufficient data (e.g., image reconstruction, signal processing, spectral analysis, and inverse problems). MaxEnt thermodynamics began with two papers by Edwin T. Jaynes published in the 1957 Physical Review.
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