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... for the reaction is 4 x 1018. 1. Calculate the free energy change at 200°C 2. Calculate the free energy change if the partial pressure of HBr is 1.50 atm and hydrogen is 0.500 atm at 298 K. The standard free energy change is ...
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... connected the wrong electrode as cathode. This is equivalent to reversing equation (1). When equation (1) is reversed, the measured cell potential difference becomes Eocell = - 1.10 V. The absolute value of ∆Eocell is the same in both cases, but the sign is different. The sign of ∆Eocell is positive ...
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1 8. Entropy (Hiroshi Matsuoka) Why do we need entropy? There

... which implies that when dividing ! Qq s, which is not a change of a state variable, by T, which is a state variable, we get a change of the entropy, which we claim to be a state variable. Clearly, this is a claim that needs to be justified. It turns out that to justify this relation we need the seco ...
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... spontaneous reaction - we can also calculate )U and )H for the reverse reaction, which we know does not occur spontaneously (thankfully!!) What about gases? We know that gases expand spontaneously to fill a container - we know that the opposite does not happen - unless some sort of work is done to b ...
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Maximum entropy thermodynamics

In physics, maximum entropy thermodynamics (colloquially, MaxEnt thermodynamics) views equilibrium thermodynamics and statistical mechanics as inference processes. More specifically, MaxEnt applies inference techniques rooted in Shannon information theory, Bayesian probability, and the principle of maximum entropy. These techniques are relevant to any situation requiring prediction from incomplete or insufficient data (e.g., image reconstruction, signal processing, spectral analysis, and inverse problems). MaxEnt thermodynamics began with two papers by Edwin T. Jaynes published in the 1957 Physical Review.
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