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thermodynamics - CHM152-SP10
thermodynamics - CHM152-SP10

... In thermodynamics, entropy is a measure of the degree of disorder. Entropy tends to increase. ...
Thermodynamic functions - Phase Transformations Group
Thermodynamic functions - Phase Transformations Group

... where q is the heat transferred into the system and w is the work done by the system. The historical sign convention is that heat added and work done by the system are positive, whereas heat given off and work done on the system are negative. Equation 1 may be written in differential form as dU = dq ...
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Set 3

... If the work done on a system is reverseable, we call it configuration work. This is because in almost all cases, reverseable processes do something to change the macroscopic configuration of the system. This in general can be undone. Consider the compression of an ideal gas by a piston. Of the syste ...
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... First Law and internal energy Properties of a reacting gas mixture, stoichiometry, equivalence ratio Enthalpy, enthalpy of formation, sensible enthalpy, enthalpy of reaction, enthalpy of combustion, fuel heating value §  Adiabatic flame temperature §  Second Law, entropy and Gibbs free energy §  ...
1 Thermodynamics All biochemical and cellular processes obey the
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... All biochemical and cellular processes obey the laws of chemistry and physics Biochemistry is not a special case. Therefore, in studying biochemistry, it is necessary to consider the relevant laws that control possible reactions. The three laws of thermodynamics First law: Energy is conserved The ov ...
Mr Alasdair Ross at Southpointe Academy: Math and Chemistry Pages
Mr Alasdair Ross at Southpointe Academy: Math and Chemistry Pages

... Heat (q) – A quantity of energy transferred between a system and its surroundings as a result of a temperature difference between them. Work (w) – In this section, we will consider the work done when gases expand or are compressed. ...
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Lecture 2: Adiabatic Flame Temperature and Chemical Equilibrium

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Chapter 4 - UniMAP Portal
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Lecture_3 - Department of Mathematics

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Unit 61: Engineering Thermodynamics
Unit 61: Engineering Thermodynamics

... • Using the specific enthalpy form of the steady flow energy equation (SFEE)… Q – W = (h2 – h1) + (1/2)(V22 –V12)+ g(z2 – z1) We note that g(z2 – z1) = 0 since there is no change in height between the fluid entry and exit (horizontal). Also there is negligible fluid kinetic energy at exit thus (1/2) ...
Chapter 3
Chapter 3

... For isothermal surroundings, the system can extract heat from the surroundings for free, so the work required to create the system from nothing is equal to the internal energy minus the heat received. And if we annihilate the system, we generally cannot recover all its energy as work since we have t ...
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... Enthalpy is a measure of the total energy of a thermodynamic system. It includes the internal energy, which is the energy required to create a system, and the amount of energy required to make room for it by displacing its environment and establishing its volume and pressure. Enthalpy is a thermodyn ...
LAW: The first law of thermodynamics states that the total energy in
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... Verify if the "cold water diet" would work. Some joker proposed that drinking 0.5kg of ice-cold water at each meal would be an effective diet method. Determine the internal energy change this would cause. What if you used ice cubes instead of water? DEFINITION: The latent heat is the specific enthal ...
LAW: The first law of thermodynamics states that the total energy in
LAW: The first law of thermodynamics states that the total energy in

... Verify if the "cold water diet" would work. Some joker proposed that drinking 0.5kg of ice-cold water at each meal would be an effective diet method. Determine the internal energy change this would cause. What if you used ice cubes instead of water? DEFINITION: The latent heat is the specific enthal ...
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... temperature while holding volume or pressure constant. • Then calculations can be made as to the work performed and/or heat generated. ...
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Chapter 12: Thermodynamic Property Relations
Chapter 12: Thermodynamic Property Relations

... Clapeyron-Clausius Equation For liquid-vapor and solid-vapor phase-change processes at low pressures, an approximation to the Clapeyron equation can be obtained by treating the vapor phase as an ideal gas and neglecting the specific volume of the saturated liquid or solid phase compared to that of t ...
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... Clapeyron-Clausius Equation For liquid-vapor and solid-vapor phase-change processes at low pressures, an approximation to the Clapeyron equation can be obtained by treating the vapor phase as an ideal gas and neglecting the specific volume of the saturated liquid or solid phase compared to that of t ...
Internal Energy, Heat, Enthalpy, and Calorimetry
Internal Energy, Heat, Enthalpy, and Calorimetry

...  However, we do know that the internal energy of a system is independent of the path by which the system achieved that state  Called a state function  A state function is formally defined as a property of the system that depends only on its present state  Does not depend in any way on the system ...
Enthalpy In A Box: Teaching Open Vs. Closed System Work Terms
Enthalpy In A Box: Teaching Open Vs. Closed System Work Terms

... Enthalpy, somewhat like entropy appears to be one of thermodynamic’s mysterious and abstract properties due primarily to difficulty in physical comprehension. Unlike entropy however, one could argue that enthalpy does not bring as much to the table. After all, it is defined, somewhat arbitrarily, fr ...
Chapter 5 Thermochemistry
Chapter 5 Thermochemistry

... fuel. The combustion of methylhydrazine with oxygen produces N2(g), CO2(g), and H2O(l): 2 CH6N2(l) + 5 O2(g) → 2 N2(g) + 2 CO2(g) + 6 H2O(l) When 4.00 g of methylhydrazine is combusted in a bomb calorimeter, the temperature of the calorimeter increases from 25.00 ˚C to 39.50 ˚C. In a separate experi ...
Thermochemistry - all things chemistry with dr. cody
Thermochemistry - all things chemistry with dr. cody

... the following thermochemical equations: C2H4(g) + H2(g) → C2H6(g) H = ? H2(g) + ½ O2(g) → H2O(l) C2H4(g) + 3 O2(g) → 2 CO2(g) + 2 H2O(l) C2H6(g) + 7/2 O2(g) → 2CO2(g) + 3 H2O(l) ...
HW # 5 - KFUPM Faculty List
HW # 5 - KFUPM Faculty List

... c) The rate of water added to the air in the dryer d) The rate of water condensed in the condenser e) The rate of heat removal in the condenser Q3) 196 grams of sulfuric acid at 250C are mixed with 360 grams of water at 250 C to form a solution at 250 C. Find the amount of heat which should be remov ...
Chapter 5
Chapter 5

... •Therefore, internal energy is a state function. •It depends only on the present state of the system, not on the path by which the system arrived at that state. •And so, ∆E depends only on Einitial and Efinal. ...
Lacture №1. Chemical thermodynamics. The first law of
Lacture №1. Chemical thermodynamics. The first law of

... If the gas expands, V2 › V1 and work is done by the system and W is negative (we will use sign positive) V2‹ V1 and the work is done on the system and W is positive Note. It may be noted that many books use the opposite sign convention for work!!! (according to the IUPAC recommendation) ...
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Enthalpy

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