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4 slides per page() - Wayne State University Physics and
4 slides per page() - Wayne State University Physics and

... Atomic Transitions – Spontaneous Emission Once an atom is in an excited state, there is a constant probability that it will jump back to a lower state by emitting a photon This process is called spontaneous emission ...
Electrons and Photons
Electrons and Photons

... • Each energy level has electrons with a certain amount of energy in them that matches the level. • When the electrons change levels, they have to gain or lose energy to do so. • Each time they lose energy, they emit a bundle of energy. • We see that bundle as a photon! ...
State briefly the meaning of and
State briefly the meaning of and

HMWK 7
HMWK 7

... Assess: The emission spectra will include light of these three wavelengths. P29.36. Prepare: Figure P29.36 shows the ground state (with a large number of allowed states) and an excited state (with a large number of allowed states) for a molecule. Even though the ground state has a large number of al ...
Search for the Electron Electric Dipole Moment Using PbO
Search for the Electron Electric Dipole Moment Using PbO

7.1 Variational Principle
7.1 Variational Principle

... Suppose that you want to determine the ground-state energy Eg for a system described by H, but you are unable to solve the time-independent Schrödinger equation. It is possible to establish an upper bound for Eg by choosing any normalized ψ (whatsoever) and calculating hψ|H|ψi, which must be ≥ Eg . ...
IB HL Physics More Problems on Quantum and Nuclear Physics_
IB HL Physics More Problems on Quantum and Nuclear Physics_

fundamental_reality\Photons and Phonons
fundamental_reality\Photons and Phonons

Matter and Energy Identify a chemical physical change Identify a
Matter and Energy Identify a chemical physical change Identify a

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... why IP(Be)> IP(B) and I(O)< I(N)? 2p 2s ↑↓ ...
PerturbationTheory
PerturbationTheory

(3) Q =Z (3Z2 - r2 ) dV
(3) Q =Z (3Z2 - r2 ) dV

... spin for boron of 3. There is interest in checking this for the J = 0--)1 transition where only a simple triplet structure is to be observed. The spin in this case is determined from the fine-structure spacing and relative intensities. We have observed the J = 0-+1 transition for H3BCO but,as yet, h ...
Review - The University of Texas at Dallas
Review - The University of Texas at Dallas

... Nernst Equation  Work = Charge  Potential change  Mole of electrons worth F (96,450 C)  Workmax = ne F E° = – G° ...
PHY140Y 32 The Pauli Exclusion Principle
PHY140Y 32 The Pauli Exclusion Principle

... Our focus on the hydrogen atom should have given some insight into how one electron can interact with a proton. However, the behaviour of multi-electron systems was quite enigmatic. What was observed was that multi-electron atoms seemed to have periodic properties. As you added electrons to the atom ...
Lecture 8, Quantum Mechanical Harmonic Oscillator
Lecture 8, Quantum Mechanical Harmonic Oscillator

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Operating Principles

... There are three types of electron transitions, as shown in figure 2. The first type of transition, shown in figure 2 (a), is known as resonant absorption. An electron transits from the stable low energy level, E1, to the higher energy level, E2, by absorbing light. Figure 2 (b) shows spontaneous emi ...
Main Topic: T1 Density-Functional Theory beyond LDA
Main Topic: T1 Density-Functional Theory beyond LDA

Atomic Number and Mass Number
Atomic Number and Mass Number

2710 PS3 1 Problem Set #3 Comparing classical electromagnetic
2710 PS3 1 Problem Set #3 Comparing classical electromagnetic

Quantum Mechanical Model
Quantum Mechanical Model

... Chapter 5 Section 2 ...
A1980KM40500001
A1980KM40500001

... paper shows that the Hamiltonian can be transformed so that, for a completely unsymmetrical molecule, there are only (n+ 1) terms for each even degree n. [The SCI ® indicates that this paper has been cited over 305 times since 1967.] James K. G. Watson Department of Chemistry University of Southampt ...
Lecture 2014-12-07
Lecture 2014-12-07

Fluorescence
Fluorescence

... • higher energy radiation is absorbed by a species and stored for long enough that the molecules have collided and lost vibrational energy in collisions. When the excited molecule re-emits, the photon is of less energy depending on the species and is therefore of a lower frequency. • . Note that Flu ...
AS 713  Spectroscopy in Astrophysics Fall 2014
AS 713 Spectroscopy in Astrophysics Fall 2014

w/s dipole moments
w/s dipole moments

... 1. What is the relationship between the dipole moment and the bond moment? How is it possible for a molecule to have bond moments and yet be nonpolar? 2. The dipole moments of the hydrogen halides decrease from HF to HI. Explain this trend. 3. Sketch the bond moments for the following molecules, and ...
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Franck–Condon principle



The Franck–Condon principle is a rule in spectroscopy and quantum chemistry that explains the intensity of vibronic transitions. Vibronic transitions are the simultaneous changes in electronic and vibrational energy levels of a molecule due to the absorption or emission of a photon of the appropriate energy. The principle states that during an electronic transition, a change from one vibrational energy level to another will be more likely to happen if the two vibrational wave functions overlap more significantly.
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