2.2.1 Exercise 3 - oxidation reactions of alcohols - A
... Write an equation to show how the further oxidation of the product in 1 (a). Name the organic product and state the reagents and conditions required for this reaction. ...
... Write an equation to show how the further oxidation of the product in 1 (a). Name the organic product and state the reagents and conditions required for this reaction. ...
Zumd22
... Alcohols, R–OH The –OH makes alcohol polar enough to hydrogen bond. water soluble Fermentation product but vulnerable to oxidation to aldehyde and acid. ...
... Alcohols, R–OH The –OH makes alcohol polar enough to hydrogen bond. water soluble Fermentation product but vulnerable to oxidation to aldehyde and acid. ...
Synthesis of n-Butyl Acetate via Esterification
... In a 5-mL short-necked round-bottomed flask, place 0.2 g of Dowex 50X2-l00 ion-exchange resin [Note: The Dowex resin as received should be washed with water by decantation to remove much of the yellow color. It is then collected by vacuum filtration on a Buchner funnel before use], 0.61 g (0.58 mL) ...
... In a 5-mL short-necked round-bottomed flask, place 0.2 g of Dowex 50X2-l00 ion-exchange resin [Note: The Dowex resin as received should be washed with water by decantation to remove much of the yellow color. It is then collected by vacuum filtration on a Buchner funnel before use], 0.61 g (0.58 mL) ...
Year 13 Organic Chemistry Test
... Fill in the gaps with the correct reactants, products or catalysts in the reactions below. You may draw graphical (structural) formulae or constitutional formulae. If there is more than one organic product, (e.g. due to Markovnikov’s rule), give the major product only. (a) ...
... Fill in the gaps with the correct reactants, products or catalysts in the reactions below. You may draw graphical (structural) formulae or constitutional formulae. If there is more than one organic product, (e.g. due to Markovnikov’s rule), give the major product only. (a) ...
Chem 263 April 11, 2006 Reductive Amination Amines can be
... plant (Erythroxylum coca). This is not in the Solanaceae family, but rather is in family Erythroxylaceae. It is a stimulant of the central nervous system and an appetite suppressant, creating what has been described as a euphoric sense of happiness and increased energy. Though most often used recrea ...
... plant (Erythroxylum coca). This is not in the Solanaceae family, but rather is in family Erythroxylaceae. It is a stimulant of the central nervous system and an appetite suppressant, creating what has been described as a euphoric sense of happiness and increased energy. Though most often used recrea ...
Brønsted-Lowry Acids and Bases
... 3. Some acids react with active metals and release hydrogen gas, H2. 4. Acids react with bases to produce salts and water. 5. Acids conduct electric current. ...
... 3. Some acids react with active metals and release hydrogen gas, H2. 4. Acids react with bases to produce salts and water. 5. Acids conduct electric current. ...
CHAPTER 1: ORGANIC COMPOUNDS
... - C-O-C bond is v-shaped and polar, so molecule is more polar than an alkane with the same number of C’s but not as polar as alcohols with the O-H bond - see table 2 p 46 - can dissolve both polar and non-polar substances - C-O bond stable so they are unrreactive Naming Ethers: - use “-oxy” on end o ...
... - C-O-C bond is v-shaped and polar, so molecule is more polar than an alkane with the same number of C’s but not as polar as alcohols with the O-H bond - see table 2 p 46 - can dissolve both polar and non-polar substances - C-O bond stable so they are unrreactive Naming Ethers: - use “-oxy” on end o ...
Dr. Baxley`s Thermodynamics Worksheet
... 6. (from Brady, Russell and Holum) Considering the fact that the formation of a bond between two atoms is exothermic and is accompanied by an entropy decrease, explain why all chemical compounds decompose into individual atoms if heated to a high enough temperature. ...
... 6. (from Brady, Russell and Holum) Considering the fact that the formation of a bond between two atoms is exothermic and is accompanied by an entropy decrease, explain why all chemical compounds decompose into individual atoms if heated to a high enough temperature. ...
Demonstrate understanding of the properties of organic compounds
... Amines are derived from ammonia If the N is attached to one carbon chain it is a primary amine Secondary amines have 2 alkyl groups and tertiary have 3 Name the parent chain, position of the amino group and if there are other groups attached to the N then prefix with ‘N’ rather than the number eg. N ...
... Amines are derived from ammonia If the N is attached to one carbon chain it is a primary amine Secondary amines have 2 alkyl groups and tertiary have 3 Name the parent chain, position of the amino group and if there are other groups attached to the N then prefix with ‘N’ rather than the number eg. N ...
Chemistry 199 - Department of Chemistry | Oregon State University
... What is chiral? Sketch a molecule that contains three chiral carbons. A molecule is chiral if it cannot be superimposed on its mirror image. A carbon in a molecule is chiral if it has four different groups attached to it. CH2BrF is not chiral. CHBrClF is. ...
... What is chiral? Sketch a molecule that contains three chiral carbons. A molecule is chiral if it cannot be superimposed on its mirror image. A carbon in a molecule is chiral if it has four different groups attached to it. CH2BrF is not chiral. CHBrClF is. ...
CH 3 Br + Nu
... B) it involves the formation of the carbocation from elimination of a good leaving group C) a common competing reaction is rearrangement of a less stable carbocation to a more stable carbocation D) the loss of a proton by the carbocation is a fast step E) all of the above ...
... B) it involves the formation of the carbocation from elimination of a good leaving group C) a common competing reaction is rearrangement of a less stable carbocation to a more stable carbocation D) the loss of a proton by the carbocation is a fast step E) all of the above ...
Organic-IB-Short-Exam Questions-Answers
... curly arrow showing attack by – OH on end H; curly arrow showing C–Br bond fission; curly arrow showing formation of double bond; H2O and Br– shown as products; ...
... curly arrow showing attack by – OH on end H; curly arrow showing C–Br bond fission; curly arrow showing formation of double bond; H2O and Br– shown as products; ...
Amino Acids and Their Polymers
... Fats, oils, and other water-insoluble compounds are called lipids. ...
... Fats, oils, and other water-insoluble compounds are called lipids. ...
Make Your Own Summary 1. single displacement reaction 2
... h. synthesis, since the only reaction elements can perform is to join together to make a compound i. single displacement, since an element and a compound are the reactants required for such a reaction j. synthesis, since the only reaction elements can perform is to join together to make a compound ...
... h. synthesis, since the only reaction elements can perform is to join together to make a compound i. single displacement, since an element and a compound are the reactants required for such a reaction j. synthesis, since the only reaction elements can perform is to join together to make a compound ...
Lecture6-Organometallic Chemistry
... more specific) than an uncatalyzed version of the same reaction because the catalyst provide a different reaction pathway with a lower activation energy Catalyst efficiency • Turnover frequency : Commonly called the turnover number, N, and defined as molecules reacting per active site in unit time. ...
... more specific) than an uncatalyzed version of the same reaction because the catalyst provide a different reaction pathway with a lower activation energy Catalyst efficiency • Turnover frequency : Commonly called the turnover number, N, and defined as molecules reacting per active site in unit time. ...
슬라이드 1
... Conjugate addition to a,b-unsaturated esters can often be effected by copper catalyzed reaction with Grignard reagent. Other reactions, such as epoxide ring opening, can also be carried out under catalytic conditions. (Scheme 8.5) ...
... Conjugate addition to a,b-unsaturated esters can often be effected by copper catalyzed reaction with Grignard reagent. Other reactions, such as epoxide ring opening, can also be carried out under catalytic conditions. (Scheme 8.5) ...
Bulent Terem - CH324 - Syllabus | Chaminade
... + .15 (average of the quizzes/presentations –including clicker quizzes) + .05 (grade from tutorial sessions/homework assignments) + .36 (final) Make-up exams will be given only under exceptional circumstances and on the basis of a written request submitted before the exam day or within 24 hours of t ...
... + .15 (average of the quizzes/presentations –including clicker quizzes) + .05 (grade from tutorial sessions/homework assignments) + .36 (final) Make-up exams will be given only under exceptional circumstances and on the basis of a written request submitted before the exam day or within 24 hours of t ...
Unit 2 Content Statements
... The structure of a section of protein is based on the constituent amino acids. Condensation of amino acids produces the peptide (amide) link. The peptide link is formed by the reaction of an amine group with a carboxyl group. Proteins specific to the body’s needs are built up within the body. The bo ...
... The structure of a section of protein is based on the constituent amino acids. Condensation of amino acids produces the peptide (amide) link. The peptide link is formed by the reaction of an amine group with a carboxyl group. Proteins specific to the body’s needs are built up within the body. The bo ...
Organic Chemistry I Mario Lintz 1st Year MD/PhD Candidate Mario
... nucleophilic substitution of the displaced halide ion. Does not require strong acids (HCl, HBr) ...
... nucleophilic substitution of the displaced halide ion. Does not require strong acids (HCl, HBr) ...
Chapter 11 Introduction to Organic Chemistry Part 2
... 5. Determine whether the following isomers are enantiomers or diastereomers. What characteristic feature of the molecule can be used to make the decision? ...
... 5. Determine whether the following isomers are enantiomers or diastereomers. What characteristic feature of the molecule can be used to make the decision? ...
www.xtremepapers.net
... effective if electronegative elements such as chlorine are present. Thus the chloroethanoic acids become increasingly more acidic as more chlorine atoms are present in the molecule. The reagent of preference is SOCl2, since both by-products are gases. Other possibilities are PCl3 and PCl5. The react ...
... effective if electronegative elements such as chlorine are present. Thus the chloroethanoic acids become increasingly more acidic as more chlorine atoms are present in the molecule. The reagent of preference is SOCl2, since both by-products are gases. Other possibilities are PCl3 and PCl5. The react ...
Petasis reaction
The Petasis reaction (alternatively called the Petasis borono–Mannich (PBM) reaction) is the chemical reaction of an amine, aldehyde, and vinyl- or aryl-boronic acid to form substituted amines.Reported in 1993 by Nicos Petasis as a practical method towards the synthesis of a geometrically pure antifungal agent, naftifine, the Petasis reaction can be described as a variation of the Mannich reaction. Rather than generating an enolate to form the substituted amine product, in the Petasis reaction, the vinyl group of the organoboronic acid serves as the nucleophile. In comparison to other methods of generating allyl amines, the Petasis reaction tolerates a multifunctional scaffold, with a variety of amines and organoboronic acids as potential starting materials. Additionally, the reaction does not require anhydrous or inert conditions. As a mild, selective synthesis, the Petasis reaction is useful in generating α-amino acids, and is utilized in combinatorial chemistry and drug discovery.