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chemistry 232 elementary organic chemistry ii
chemistry 232 elementary organic chemistry ii

Chapter 9: Aldehydes and Ketones
Chapter 9: Aldehydes and Ketones

... Aldehydes and ketones are characterized by the presence of the carbonyl group, which is perhaps the most important functional group in organic chemistry. Aldehydes have at least one hydrogen atom attached to the carbonyl carbon atom. The remaining group may be another hydrogen atom or any aliphatic ...
Physical Properties of Hydrocarbons
Physical Properties of Hydrocarbons

... • bigger the molecule greater the intermolecular force • ... more viscous as the intermolecular attractive forces between molecules increases. • ... higher melting point as more vibrational kinetic energy is needed to overcome the intermolecular attractive forces holding the molecules together to fo ...
Oxidation Reactions
Oxidation Reactions

Chapter 1 Structure and Bonding
Chapter 1 Structure and Bonding

... 3) Number and name any other substituents 4) Carboxylic acids have priority over any other functional group studied 5) Cyclic (cycloalkanecarboxylic acids) and aromatic (benzoic acids) ...
Addition reactions
Addition reactions

... substituted carbon, creates the most stable carbocation. Sometimes the substituted carbocation is also stabilized by resonance. v ...
Document
Document

... Convenor : Dr. Fawaz Aldabbagh ...
Separation of alcohol/ether/hydrocarbon mixtures in
Separation of alcohol/ether/hydrocarbon mixtures in

... Oxygenated compounds like alcohols or ethers have high octane numbers, as can be seen from table 1. Furthermore the incorporation of oxygenated compounds in gasoline reduces the emissions of CO and of unburned hydrocarbons in engines exhaust gases. But ethers have specific advantages over alcohols w ...
Oxidation of alcohol to carboxylic acid under mild acidic condition
Oxidation of alcohol to carboxylic acid under mild acidic condition

... material for synthesis of prostaglandins [2] and prostaglandin possess a diverse range of biological activities including the treatment of glaucoma and ocular hypertension[3], chronic constipation and irritable bowel syndrome[4]. In this paper, we report the Oxidation of Corey lactone, which is sens ...
11 - DR CLEM KUEK
11 - DR CLEM KUEK

INFRARED SPECTROSCOPY PURDUE UNIVERSITY
INFRARED SPECTROSCOPY PURDUE UNIVERSITY

... The emphasis in this experiment is on the methods of organic qualitative analysis. Nevertheless, a brief discussion of the properties and molecular structures of the substances to be tested should prove useful. Organic compounds are often defined as those substances containing carbon; most contain h ...
Topic checklist
Topic checklist

... These factors, together with reaction rates, are important when determining the optimum conditions in industrial processes, including the Haber process. ...
The Chemicals of Life Properties of Organic Compounds Organic
The Chemicals of Life Properties of Organic Compounds Organic

... It has a high electronegativity, so it pulls electrons away from the carbon atom It is important in carbohydrates, pyruvic acid (used in respiration), glycerol (a component of fats), and alcohols Alcohols are compounds that contain a hydroxyl group (OH-) attached to the carbon, and can easily dissol ...
Dehydration notes-1
Dehydration notes-1

... Elimination Reactions 1. E1 – unimolecular transition state – formation of carbocation intermediate – Preferred for tertiary carbons ...
ppt
ppt

... Wittig Reaction (sec. 16.17) Ph3P is good at taking up O to form strong Ph3P=O bond. ...
A Floral Fragrance, Methyl Benzoate
A Floral Fragrance, Methyl Benzoate

... Cool the solution to room temperature, then decant it into a separatory funnel containing 25 mL of water, and rinse the flask with 25 mL of diethyl ether (use wet ether found in a supply bottle in each hood). Add this ether to the separatory funnel, shake thoroughly, and drain off the water layer, w ...
  Spring 2015 CH 421  Name ________________________________________    1.  Consider the structures of vanillin and vanillyl alcohol.  
  Spring 2015 CH 421  Name ________________________________________    1. Consider the structures of vanillin and vanillyl alcohol.  

... 8. Which  peak  from  the  1H  NMR  of  vanillin  will  disappear  upon  its  conversion  to  vanillyl alcohol?  Indicate the chemical shift rounded to the tenths digit.  (Note the  other peaks may be shifted, but they are still present in the product.)  ...
pptx
pptx

... A. The most widely employed transition metal oxidants for alcohols are based on Cr(VI). Chromium trioxide = CrO3 Dichromate = Cr2O72Chromium trioxide will oxidize 2o alcohols to ketones. A specific cocktail of CrO3 and H2SO4 in acetone is called the Jones reagent, and is particularly effective for t ...
CH19 Aldehydes and Ketones
CH19 Aldehydes and Ketones

... (basic): ...
Chapter 22 Organic Chemistry
Chapter 22 Organic Chemistry

... Chapter 22–Assignment C: Organic Compounds with Oxygen or Nitrogen The major organic functional groups include oxygen or nitrogen atoms. When these electronegative atoms are bonded to carbon, polar bonds are formed. These polar bonds may then be sites of chemical reactions. The main ideas are: ...
Oxidation and Reduction
Oxidation and Reduction

NCEA Level 1 Chemistry (90932) 2015
NCEA Level 1 Chemistry (90932) 2015

106KB - NZQA
106KB - NZQA

... molecular mass, particularly the number of carbon atoms. The lower / higher its molecular mass is, the lower / higher the temperature (boiling point) at which it will condense. This determines whereabouts on the tower the particular fraction is collected. Products formed during Process 1 may include ...
Relative Reactivity of Aldehydes and Ketones: Generally
Relative Reactivity of Aldehydes and Ketones: Generally

... Acidic conditions use neutral water, H2O, as the nucleophile… Neutral carbonyl and neutral water aren’t so very attracted to each other… The oxygen atom in water is electronegative and less willing to share its electron density to form a bond to the carbonyl. We must tweak the system to make them mo ...
Aldehid dan Keton
Aldehid dan Keton

... Preparation of Aldehydes and Ketones • Aldehydes from oxidation of primary alcohols using pyridinium chlorochromate (PCC) ...
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Alcohol



In chemistry, an alcohol is any organic compound in which the hydroxyl functional group (–OH) is bound to a saturated carbon atom. The term alcohol originally referred to the primary alcohol ethyl alcohol (ethanol), the predominant alcohol in alcoholic beverages.The suffix -ol appears in the IUPAC chemical name of all substances where the hydroxyl group is the functional group with the highest priority; in substances where a higher priority group is present the prefix hydroxy- will appear in the IUPAC name. The suffix -ol in non-systematic names (such as paracetamol or cholesterol) also typically indicates that the substance includes a hydroxyl functional group and, so, can be termed an alcohol. But many substances, particularly sugars (examples glucose and sucrose) contain hydroxyl functional groups without using the suffix. An important class of alcohols, of which methanol and ethanol are the simplest members is the saturated straight chain alcohols, the general formula for which is CnH2n+1OH.
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