Introduction to Organic Chemistry Notes Sheet
... What happens if the alkane has more than one substituent? In this case, the rules above are followed, and the carbons on the longest chain are numbered to give the lowest number possible to one of the substituent. The substituents are then all named in the prefix (e.g. 2-ethyl,3-methyl). If more tha ...
... What happens if the alkane has more than one substituent? In this case, the rules above are followed, and the carbons on the longest chain are numbered to give the lowest number possible to one of the substituent. The substituents are then all named in the prefix (e.g. 2-ethyl,3-methyl). If more tha ...
Chapter 4 Functional Group Transformations: Oxidation and
... 4.1 - Oxidation of Alcohols to Aldehydes and Ketones Reagent ...
... 4.1 - Oxidation of Alcohols to Aldehydes and Ketones Reagent ...
+ 2 KI + 2 H3P04 + 2 RI + 2 KHzPOI + H2O
... Since the procedures for the reactions of potassium iodide and orthophosphoric acid with various ethers, alcohols, and olefins are essentially the same, a detailed procedure is described for only a single member of each class of compounds. Characterization of all compounds was based on their densiti ...
... Since the procedures for the reactions of potassium iodide and orthophosphoric acid with various ethers, alcohols, and olefins are essentially the same, a detailed procedure is described for only a single member of each class of compounds. Characterization of all compounds was based on their densiti ...
apchem - practice midterm_shs
... mark completely, and then record your new answer. Mark only one answer for each question. Many candidates wonder whether or not to guess the answers to questions about which they are uncertain. In this section of the examination, as a correction for haphazard guessing, one-fourth of the number of qu ...
... mark completely, and then record your new answer. Mark only one answer for each question. Many candidates wonder whether or not to guess the answers to questions about which they are uncertain. In this section of the examination, as a correction for haphazard guessing, one-fourth of the number of qu ...
Complete the following equations
... (d) A compound composed of lithium boron and hydrogen that is used as a reducing agent in organic synthesis: _LiBH4__________ (e) An aluminum compound used for the treatment of municipal water: __Al2(SO4)3__________ ...
... (d) A compound composed of lithium boron and hydrogen that is used as a reducing agent in organic synthesis: _LiBH4__________ (e) An aluminum compound used for the treatment of municipal water: __Al2(SO4)3__________ ...
Chapter 1--Title - Chemistry Workshop
... The acyl azide is obtained from an acid chloride Rearrangement of the acyl azide occurs with loss of N2, a very stable leaving group In the last step, the isocyanate is hydrolyzed by adding water ...
... The acyl azide is obtained from an acid chloride Rearrangement of the acyl azide occurs with loss of N2, a very stable leaving group In the last step, the isocyanate is hydrolyzed by adding water ...
odd - WWW2
... The reaction is highly exothermic due primarily to the strength of the nitrogen-nitrogen triple bond. 15.69 Only two hydrogens are replaced because the structure contains only two hydroxyl groups. The hydrogen bonded to the phosphorus is not labile and cannot be replaced. (HO)2HPO2(D2O) + 2 D2O(l) ( ...
... The reaction is highly exothermic due primarily to the strength of the nitrogen-nitrogen triple bond. 15.69 Only two hydrogens are replaced because the structure contains only two hydroxyl groups. The hydrogen bonded to the phosphorus is not labile and cannot be replaced. (HO)2HPO2(D2O) + 2 D2O(l) ( ...
SCH 4C - mscucinato
... 2. What does the term qualitative analysis refer to? Give an example of a time where you carried out a qualitative analysis in class. 3. Distinguish between physical properties and chemical properties. Give an example of each. 4. Distinguish between physical changes and chemical changes. Give an exa ...
... 2. What does the term qualitative analysis refer to? Give an example of a time where you carried out a qualitative analysis in class. 3. Distinguish between physical properties and chemical properties. Give an example of each. 4. Distinguish between physical changes and chemical changes. Give an exa ...
Chapter 1--Title
... The acyl azide is obtained from an acid chloride Rearrangement of the acyl azide occurs with loss of N2, a very stable leaving group In the last step, the isocyanate is hydrolyzed by adding water ...
... The acyl azide is obtained from an acid chloride Rearrangement of the acyl azide occurs with loss of N2, a very stable leaving group In the last step, the isocyanate is hydrolyzed by adding water ...
Equilibrium Review Problems N2(g) + H2(g) NH3(g) 1. When 3.29
... (d) At 27ºC the concentration of Mg2+ in a saturated solution of MgF2 is 1.1710-3 molar. Is the dissolving of MgF2 in water an endothermic or an exothermic process? Give an explanation to support your conclusion. ...
... (d) At 27ºC the concentration of Mg2+ in a saturated solution of MgF2 is 1.1710-3 molar. Is the dissolving of MgF2 in water an endothermic or an exothermic process? Give an explanation to support your conclusion. ...
Conversion of Alcohols into Alkyl Halides
... 1o and 2o Alcohols: best to use SOCl2, PBr3, or P/I2 All are SN2 Reactions SOCl2 pyridine OH ...
... 1o and 2o Alcohols: best to use SOCl2, PBr3, or P/I2 All are SN2 Reactions SOCl2 pyridine OH ...
POLYMER END-GROUP ANALYSIS: THE DETERMINATION OF
... chloride), abbreviated PVC, and polystyrene), and elastomers. See Fig. 1. Like PVC and polystyrene, the compound involved in this experiment is synthesized from only one kind of monomer molecule, ethylene glycol. The monomers are joined by elimination of a molecule of water to form a series of ether ...
... chloride), abbreviated PVC, and polystyrene), and elastomers. See Fig. 1. Like PVC and polystyrene, the compound involved in this experiment is synthesized from only one kind of monomer molecule, ethylene glycol. The monomers are joined by elimination of a molecule of water to form a series of ether ...
8.2-Organic Nomenclature packet
... Hydrocarbons that contain multiple bonds are called unsaturated hydrocarbons. If the hydrocarbon has one double bond, its general formula will be CnH2n, where n is the number of carbon atoms in the compound. The alkene family uses the -ene ending. The double bond is stronger than a single bond, and ...
... Hydrocarbons that contain multiple bonds are called unsaturated hydrocarbons. If the hydrocarbon has one double bond, its general formula will be CnH2n, where n is the number of carbon atoms in the compound. The alkene family uses the -ene ending. The double bond is stronger than a single bond, and ...
Review for Ch. 20 21
... amine incapable of doing the reaction. If you use equal amounts of acid chloride and amine, the reaction will only go halfway because half the amine gets acidified. There are two ways around this: either use twice as much amine, or throw in one equivalent of some sacrificial amine, usually pyridine, ...
... amine incapable of doing the reaction. If you use equal amounts of acid chloride and amine, the reaction will only go halfway because half the amine gets acidified. There are two ways around this: either use twice as much amine, or throw in one equivalent of some sacrificial amine, usually pyridine, ...
Word - Chemistry and More
... precipitate forms, give the name and formula of the precipitate. a) sodium sulfate and barium chloride b) ammonium sulfide and strontium nitrate c) lithium carbonate and cobalt(III) chloride d) potassium phosphate and sodium hydroxide 10. (Chapter 8) For each case where there was a net reaction in Q ...
... precipitate forms, give the name and formula of the precipitate. a) sodium sulfate and barium chloride b) ammonium sulfide and strontium nitrate c) lithium carbonate and cobalt(III) chloride d) potassium phosphate and sodium hydroxide 10. (Chapter 8) For each case where there was a net reaction in Q ...
Gas Stoichiometry
... decomposition of sodium azide (NaN3) to sodium metal and nitrogen gas. 2. Because sodium is toxic and very reactive, it reacts with the potassium nitrate to produce potassium oxide and sodium oxide, and (additional) nitrogen gas. 3. The metal oxides are removed by reacting with the silicon dioxide t ...
... decomposition of sodium azide (NaN3) to sodium metal and nitrogen gas. 2. Because sodium is toxic and very reactive, it reacts with the potassium nitrate to produce potassium oxide and sodium oxide, and (additional) nitrogen gas. 3. The metal oxides are removed by reacting with the silicon dioxide t ...
1 SECONDARY SCHOOL IMPROVEMENT PROGRAMME (SSIP
... bonded together in the molecule but it does not show all the bonds e.g. CH 3CH2CH2 CH2CH3 Hydrocarbon – organic compounds that consist of only hydrogen and carbon atoms. Homologous series – a series of organic compounds that have the same functional group and that obey the same general formula or in ...
... bonded together in the molecule but it does not show all the bonds e.g. CH 3CH2CH2 CH2CH3 Hydrocarbon – organic compounds that consist of only hydrogen and carbon atoms. Homologous series – a series of organic compounds that have the same functional group and that obey the same general formula or in ...
AP Chemistry Summer Assignment
... i. NH3 60. Which of the following reactions are redox reactions? a. HCl + NaHCO3 _____> CO2 + H2O + NaCl ...
... i. NH3 60. Which of the following reactions are redox reactions? a. HCl + NaHCO3 _____> CO2 + H2O + NaCl ...
Chapter 4 Carbon
... • Isomers are compounds with the same molecular formula but different structures and properties – Structural isomers have different covalent arrangements of their atoms – Cis-trans isomers have the same covalent bonds but differ in spatial arrangements – Enantiomers are isomers that are mirror image ...
... • Isomers are compounds with the same molecular formula but different structures and properties – Structural isomers have different covalent arrangements of their atoms – Cis-trans isomers have the same covalent bonds but differ in spatial arrangements – Enantiomers are isomers that are mirror image ...
Types of Chemical Reactions
... 5. What is the net ionic equation for the reaction between aqueous calcium hydroxide and nitric acid? The products of this reaction are aqueous calcium nitrate and water. How does this net ionic equation compare to the net ionic equation shown at the top of this page? Hint: you may want to begin wit ...
... 5. What is the net ionic equation for the reaction between aqueous calcium hydroxide and nitric acid? The products of this reaction are aqueous calcium nitrate and water. How does this net ionic equation compare to the net ionic equation shown at the top of this page? Hint: you may want to begin wit ...
Unit 6 Study Guide - Dorman High School
... have the gases A, B, C, and D at equilibrium. Upon adding gas A, the value of K A) increases because when A is added, more products are made, increasing the product-to-reactant ratio B) decreases because A is a reactant, so the product-toreactant ratio decreases C) does not change because A does not ...
... have the gases A, B, C, and D at equilibrium. Upon adding gas A, the value of K A) increases because when A is added, more products are made, increasing the product-to-reactant ratio B) decreases because A is a reactant, so the product-toreactant ratio decreases C) does not change because A does not ...
Camp 1 - drjosephryan.com Home Page
... In general, ions in solution react with each other when one of the following can happen – two of them form a compound that is insoluble in water – two of them react to form a gas that escapes from the ...
... In general, ions in solution react with each other when one of the following can happen – two of them form a compound that is insoluble in water – two of them react to form a gas that escapes from the ...
Strychnine total synthesis
Strychnine total synthesis in chemistry describes the total synthesis of the complex biomolecule strychnine. The first reported method by the group of Robert Burns Woodward in 1954 is considered a classic in this research field. At the time it formed the natural conclusion to an elaborate process of molecular structure elucidation that started with the isolation of strychnine from the beans of Strychnos ignatii by Pierre Joseph Pelletier and Joseph Bienaimé Caventou in 1818. Major contributors to the entire effort were Sir Robert Robinson with over 250 publications and Hermann Leuchs with another 125 papers in a time span of 40 years. Robinson was awarded the Nobel Prize in Chemistry in 1947 for his work on alkaloids, strychnine included. The process of chemical identification was completed with publications in 1946 by Robinson and later confirmed by Woodward in 1947. X-ray structures establishing the absolute configuration became available between 1947 and 1951 with publications from J. M. Bijvoet and J.H. Robertson .Woodward published a very brief account on the strychnine synthesis in 1954 (just 3 pages) and a lengthy one (42 pages) in 1963.Many more methods exist and reported by the research groups of Magnus, Overman, Kuehne, Rawal, Bosch, Vollhardt, Mori, Shibasaki, Li, Fukuyama Vanderwal and MacMillan. Synthetic (+)-strychnine is also known. Racemic synthesises were published by Padwa in 2007 and in 2010 by Andrade and by Reissig.In his 1963 publication Woodward quoted Sir Robert Robinson who said for its molecular size it is the most complex substance known.