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APPLICATION OF IONIC LIQUIDS IN ORGANIC SYNTHESIS
APPLICATION OF IONIC LIQUIDS IN ORGANIC SYNTHESIS

... methodologies. These activities may provide more information on the understanding of mechanisms of organic reactions using ionic liquids as reaction media, which have been traditionally conducted in molecular solvents. It may also provide improved methodologies for product separations, particularly ...
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Chapter 4 Aqueous Reactions and Solution Stoichiometry
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... 28.Al(OH)3 +3HCl-->AlCl3+3H2O, If 14g of Al(OH)3 is present, determine the theoretical yield of AlCl3 produced when the tablet reacts with HCl. 29. Zn+I2-->ZnI2 (a).Determine the theoretical yield if 1.912 mol of zinc is used. (b).Determine the percent yield is 515.6g of product is recovered. 30. Wh ...
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... 3. Chlorine gas can be formed in the laboratory by adding concentrated hydrochloric acid to potassium permanganate. The gas is bubbled through water, to remove any unreacted hydrochloric acid, and then concentrated sulphuric acid to dry it. The chlorine gas is then collected in a gas jar. (a) La ...
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Click chemistry

In chemical synthesis, click chemistry is generating substances quickly and reliably by joining small units together. Click chemistry is not a single specific reaction, but describes a way of generating products that follows examples in nature, which also generates substances by joining small modular units. The term was coined by K. Barry Sharpless in 1998, and was first fully described by Sharpless, Hartmuth Kolb, and M.G. Finn of The Scripps Research Institute in 2001.A desirable click chemistry reaction would: be modular be wide in scope give very high chemical yields generate only inoffensive byproducts be stereospecific be physiologically stable exhibit a large thermodynamic driving force (> 84 kJ/mol) to favor a reaction with a single reaction product. A distinct exothermic reaction makes a reactant ""spring-loaded"". have high atom economy.The process would preferably: have simple reaction conditions use readily available starting materials and reagents use no solvent or use a solvent that is benign or easily removed (preferably water) provide simple product isolation by non-chromatographic methods (crystallisation or distillation)↑ 1.0 1.1 ↑
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