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... D. Venting some CO2 gas from the flask 111. In a sealed bottle that is half full of water, equilibrium will be attained when water molecules A. Cease to evaporate B. Begin to condense C. Are equal in number for both the liquid and the gas phase D. Evaporate and condense at equal rates 112. At equili ...
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... a) Write the chemical reaction for the Haber process and write a K equation to describe it. (2) b) Why was this reaction so important when it was developed back in 1909? (2) c) How did Haber manage to keep this reaction moving forward to produce ammonia? (4) ...
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full text - pdf 452 kB

... not change significantly with temperature and the AC, values are small for reactions (6) and (7). The AC,, AH, and AS values for the association of K+, Ba2+, and Sr2+ with 18-crown-6 (18C6) are large and negative (16), as shown in Figs. 6 and 7. The AS values for these reactions are negative, except ...
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Click chemistry

In chemical synthesis, click chemistry is generating substances quickly and reliably by joining small units together. Click chemistry is not a single specific reaction, but describes a way of generating products that follows examples in nature, which also generates substances by joining small modular units. The term was coined by K. Barry Sharpless in 1998, and was first fully described by Sharpless, Hartmuth Kolb, and M.G. Finn of The Scripps Research Institute in 2001.A desirable click chemistry reaction would: be modular be wide in scope give very high chemical yields generate only inoffensive byproducts be stereospecific be physiologically stable exhibit a large thermodynamic driving force (> 84 kJ/mol) to favor a reaction with a single reaction product. A distinct exothermic reaction makes a reactant ""spring-loaded"". have high atom economy.The process would preferably: have simple reaction conditions use readily available starting materials and reagents use no solvent or use a solvent that is benign or easily removed (preferably water) provide simple product isolation by non-chromatographic methods (crystallisation or distillation)↑ 1.0 1.1 ↑
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