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No Slide Title
No Slide Title

... of heat is added to the gas under conditions of constant applied pressure. The final volume occupied by the gas is 6.000 L. What are q, w, and U for the process? From the first law, U = q + w. Heat is added to the system, so q = + 8000. J For constant pressure w = - p V = - (1.00 atm) (6.000 L – ...
Surface chemistry and Catalysis
Surface chemistry and Catalysis

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CHAPTER-8 NCERT SOLUTIONS
CHAPTER-8 NCERT SOLUTIONS

... get colourless pungent smelling gas HCl, but if the mixture contains bromide then we get red vapour of bromine. Why? Answer: (a) In the manufacture of benzoic acid from toluene, alcoholic potassium permanganate is used as an oxidant because of the following reasons. (i) In a neutral medium, OH– ions ...
ch17
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... (a) In which direction will the reaction proceed to reach equilibrium? (b) If [CH4] = 5.56 M at equilibrium, what are the equilibrium concentrations of the other substances? PLAN: (a) To find the direction of reaction we determine the initial concentrations from the given amounts and volume, calcula ...
U3 Student Workbook - The Connected Chemistry Curriculum
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... reactions (combination, decomposition, single displacement, double displacement, and combustion reactions). In the Connecting Activity, students apply the Law of Conservation of Mass to chemical equations by learning how to balance them. Following a teacher demonstration of the simulation and proced ...
Exam 2
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... SECTION B – Short answer questions Instructions for Section B Answer all questions in the spaces provided. To obtain full marks for your responses you should • give simpliÞed answers with an appropriate number of signiÞcant Þgures to all numerical questions; unsimpliÞed answers will not be given ful ...
Worksheet
Worksheet

... Answer the following questions that relate to the analysis of chemical compounds. (a) A compound containing the elements C, H, N, and O is analyzed. When a 3.5560 g sample is burned in excess oxygen, 6.0838 g of CO2(g) is formed. (i) Determine the mass, in grams, of C in the 3.5560 g sample of the c ...
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chapter 6: chemical reactions: an introduction
chapter 6: chemical reactions: an introduction

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Final Exam Review 2010 UbD
Final Exam Review 2010 UbD

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Downloaded from www.studiestoday.com Downloaded from www
Downloaded from www.studiestoday.com Downloaded from www

... Vapour phase refining : Vapour phase refining is the process of refining metal by converting it into its volatile compound and then, decomposing it to obtain a pure metal. The basic principle involved in this process are: (a) The metal should form a volatile compound with an available reagent, and ( ...
Class XII Chemistry IMPORTANT QUESTIONS and COMMON
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Advanced Higher Chemistry Resource Guide
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... A similar experiment using zinc amalgam is also shown in a oneminute video produced by the Open University. Can also do similar experiment with oxidation states of Mn. ...
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... This is known as the Lucas reagent. The use of aqueous hydrochloric acid, however, is less suitable because of the poor yield and the large amount of zinc chloride required. To overcome this difficulty, phase-transfer catalysts in a heterogeneous system have been used.5 Tertiary alcohols react readi ...
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... (NH2CH2COOH)H+ +CH3COOH(CH3CONHCH2COOH)H++H2O protonated N-acetyl-glycine (CH3CONHCH2COOH)H+ + NH2OH  no (clusters) (NH2CH2CONHCH2COOH)H+ + H2O Fe+CH3CONHCH2COOH + NH2OH  ? (too complicated) Fe+NH2CH2CONHCH2COOH + H2O diglycine, a dipeptide M+(Gly)n + CH3COOH + NH2OH  M+(Gly)n+1 + H2O (M+ assemb ...
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... particle of matter. It translates to mean something that is indivisible. In the eighteenth century, chemist, John Dalton, revived the term when he suggested that each element was made up of unique atoms and the atoms of an element are all the same. At that time, there were about 35 known elements. T ...
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... The ashes left over from a wood fire contain less mass than the wood. In many other chemical reactions, mass also appears to decrease. That is, the mass of the products appears to be less than the mass of the reactants. In other reactions, the products appear to gain mass. For example, plants grow t ...
Electrochemistry Lecture
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N5 Chemistry 2014
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... The redox equation for the overall reaction is A H2O(ℓ) + SO32—(aq) + Fe3+(aq) SO42—(aq) + 2H+(aq) + Fe2+(aq) + e— B H2O(ℓ) + SO32—(aq) + 2Fe3+(aq) SO42—(aq) + 2H+(aq) + 2Fe2+(aq) C SO42—(aq) + 2H+(aq) + Fe2+(aq) + e— H2O(ℓ) + SO32—(aq) + Fe3+(aq) D SO42—(aq) + 2H+(aq) + 2Fe2+(aq) H2O(ℓ) + SO32—(aq) ...
E:\My Documents\sch4u\SCH4U review McKay answers.wpd
E:\My Documents\sch4u\SCH4U review McKay answers.wpd

... Q = [Ag+]2[CO32-] = (0.0005)2 x 2.95x10 -5 = 7.4 x 10 -12 Ksp = 8.5x10 -12 Q
Grade 11 Unit 6 - Amazon Web Services
Grade 11 Unit 6 - Amazon Web Services

Chemistry in Society - Cathkin High School
Chemistry in Society - Cathkin High School

... Crude oil is a raw material from which naphtha is obtained by fractional distillation. Naphtha is a feedstock that can be cracked to produce ethene. Batch and Continuous Processes In a batch process the chemicals are loaded into the reaction vessel. The reaction is monitored and at the end of the re ...
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Lewis acid catalysis



In Lewis acid catalysis of organic reactions, a metal-based Lewis acid acts as an electron pair acceptor to increase the reactivity of a substrate. Common Lewis acid catalysts are based on main group metals such as aluminum, boron, silicon, and tin, as well as many early (titanium, zirconium) and late (iron, copper, zinc) d-block metals. The metal atom forms an adduct with a lone-pair bearing electronegative atom in the substrate, such as oxygen (both sp2 or sp3), nitrogen, sulfur, and halogens. The complexation has partial charge-transfer character and makes the lone-pair donor effectively more electronegative, activating the substrate toward nucleophilic attack, heterolytic bond cleavage, or cycloaddition with 1,3-dienes and 1,3-dipoles.Many classical reactions involving carbon–carbon or carbon–heteroatom bond formation can be catalyzed by Lewis acids. Examples include the Friedel-Crafts reaction, the aldol reaction, and various pericyclic processes that proceed slowly at room temperature, such as the Diels-Alder reaction and the ene reaction. In addition to accelerating the reactions, Lewis acid catalysts are able to impose regioselectivity and stereoselectivity in many cases.Early developments in Lewis acid reagents focused on easily available compounds such as TiCl4, BF3, SnCl4, and AlCl3. The relative strengths of these (and other) Lewis acids may be estimated from NMR spectroscopy by the Childs method or the Gutmann-Beckett method. Over the years, versatile catalysts bearing ligands designed for specific applications have facilitated improvement in both reactivity and selectivity of Lewis acid-catalyzed reactions. More recently, Lewis acid catalysts with chiral ligands have become an important class of tools for asymmetric catalysis.Challenges in the development of Lewis acid catalysis include inefficient catalyst turnover (caused by catalyst affinity for the product) and the frequent requirement of two-point binding for stereoselectivity, which often necessitates the use of auxiliary groups.
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