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The CAALM approach to USES OF ALKENES A Self Study guide NAME:___________________________________ THE A-LEVEL GRADE YOU WANT TO ACHIEVE: _________________ (A motivating factor!) __________________________________________ WRITTEN TASK GRADE: SELF ASSESSED:___________ PEER ASSESSED:______________ YOU COULD IMPROVE BY (PEER ASSESSED): ____________________________________________________________________________ ____________________________________________________________________________ ____________________________________________________________________________ I CAN IMPROVE BY (SELF ASSESSED): ____________________________________________________________________________ ____________________________________________________________________________ ____________________________________________________________________________ 1 Introduction This self-study guide will lead you through the process of learning about the uses of alkenes. Complete every task to a high standard. You will be peer assessed and given feedback on the report you write. This is an Independent Learning guide and has been designed with a CAALM outlook. CAALM stands for the five areas that together will improve your Independent Learning ability. You will cover all the five areas as part of this study guide which will improve your self-study of catalysis and help you learn the subject more effectively. The five areas are: Cognition, Affective Skills, Access to Resources, Learnt Skills & Tools, Meta-Cognition In this booklet you will specifically be developing the following parts for each area. Cognition – Processing skills in order to learn about Alkenes Affective Skills – Developing your Motivation Access to Resources – Looking at texts that impart information Learnt Skills & Tools – Reading for Understanding Meta-Cognition – Reflecting on your ability to read, understand and use texts Start the self-study guide at the beginning and complete all the tasks in the order they are given. Keep all your work together and be prepared to hand in all work. Objectives The objectives of this Self-study guide are: To improve your knowledge of Alkenes according to the exam board specification To improve your Reading for Understanding.. To improve your Independent Learning ability using a 2 CAALM outlook. 3.2.9 Alkenes – AQA Exam Board Alkenes Specification Specification statement – Candidates should…. I think I know this… I can use this information when answering questions…. know that alkenes are unsaturated hydrocarbons know that bonding in alkenes involves a double covalent bond know that the arrangement >C=C< is planar know that the alkenes can exhibit E-Z stereoisomerism be able to draw the structures of E and Z isomers understand that E-Z isomers exist due to restricted rotation about the C=C bond understand that the double bond in an alkene is a centre of high electron density understand the mechanism of electrophilic addition of alkenes with HBr, H2SO4 and Br2 know that bromine can be used to test for unsaturation be able to predict the products of addition to unsymmetrical alkenes by reference to the relative stabilities of primary, secondary and tertiary carbocation intermediates understand that alcohols are produced industrially by hydration of alkenes in the presence of an acid catalyst. know the typical conditions for the industrial production of ethanol from ethene know how addition polymers are formed from alkenes recognise that poly(alkenes) like alkanes are unreactive be able to recognise the repeating unit in a poly(alkene) know some typical uses of poly(ethene) and poly(propene) and know that poly(propene) is recycled 3.2.10 Alcohols – AQA Exam Board Alcohols Specification (only relevant part shown) Specification statement – Candidates should…. know how ethanol is produced industrially by fermentation know the conditions for this reaction and understand the economic and environmental advantages and disadvantages of this process compared with the industrial production from ethene 3 I think I know this… I can use this information when answering questions…. Alkenes – Reading for Understanding Resource: AS AQA Chemistry text book p206 to 208 P205 p214 to 215 p152 to 153 Task 1: Read the above pages from the text book. Do not make notes. Task 2: Read the above pages from the text book again making a list of all the words or ideas that you do not fully understand (be honest with yourself). Task 3: Look up the items on your list from Task 3 and make notes so that you understand them. For definition of words then look them up in the glossary. For work then look them up in other parts of the text book, your notes or on web pages (e.g. web pages outlined in the Chemistry Handbook p16). Task 4: Do not do this task before doing Tasks 1, 2 & 3. Just using your notes from Task 4 answer the following questions on paper. 1. How are alcohols produced industrially? 2. Write an equation for the fermentation of glucose to produce ethanol. What conditions are needed? 3. What are the advantages and disadvantages of the two ways of producing ethanol? 4. Write an equation showing the polymerisation of ethene to poly(ethene). 5. What is the repeating unit of poly(propene)? 6. What homologous group does poly(ethene) belong to? 7. How can we dispose of polymers made by addition polymerisation? 8. What can poly(ethene) and poly(propene) be used for? If you cannot complete this task with just your notes then repeat Task 1, 2 & 3. Task 5: Re-read the above pages of the text book with a renewed understanding. 4 Alkenes - Written Task Task 6: Write a report on ‘The uses of Alkenes’. The following is how you should structure the report. Scenario: You are a government advisor and have been asked to write a report to the Science Minister and the House of Parliament Science Sub Committee about alkenes and what they are used for. This also needs to lead onto what the products are useful for and about any environmental issues there may be. Task: To prepare a report on the uses of alkenes in the production of polymers and alcohols. Your report must include information that illustrates the following objectives you are trying to get across to the Sub Committee. Objectives: 1) To understand that alcohols are produced industrially by hydration of alkenes in presence of an acid catalyst. 2) To know the typical conditions for the industrial production of ethanol from ethene. 3) To know how ethanol is produced industrially by fermentation. 4) To know the conditions for this reaction and understand the economic and environmental advantages and disadvantages of this process compared with the industrial production from ethene 5) To know how addition polymers are formed from alkenes. 6) To recognise that poly(alkenes) like alkanes are unreactive. 7) To be able to recognise the repeating unit in a poly(alkene). 8) To know some typical uses of poly(ethene) and poly(propene) and know that poly(propene) is recycled. Hint: Polymers: a) Explain addition polymerisation using diagrams / equations. b) Show repeating units of some addition polymers. c) Explain properties of addition polymers. d) Describe uses of some addition polymers. e) Talk about the recycling of polymers. Alcohols: a) Explain how alcohols are produced and conditions needed for industrial production of ethanol from ethene and fermentation. b) Describe the advantages and disadvantages of each process. c) Include: Formula, name, what alcohol / ethanol is used for, how maximum yield is produced, what problems there are. Resources: For information use the text book, web pages found on p16 of the Chemistry Handbook, any other useful web pages and reference books. Reference all sources. 5 Self / Peer Assessment Task 7a: Self Assessment Now you must assess your work. Go through the following points on the mark grid and tick them off (in the self assessment column) if you have done them. Also record if you have done them to a high standard. Then give yourself a grade according to the statements underneath the mark grid. Mark Grid Polymers Self Assessment Present in the report Gives accurate equation describing addition polymerisation Gives correct conditions for polymerisation Shows repeating unit of suitable polymer Illustrates properties of addition polymers Describes some uses of addition polymers particularly polyethene and polypropene Describes the recycling of addition polymers particularly polypropene Highlights environmental issues Alcohols Explains production by fermentation Equation Conditions Other information Explains industrial production Equation Appropriate catalyst Conditions Explained process Explains maximum yield Describes possible problems with process Compares the two ways of producing ethanol Shows formula of appropriate alcohols Gives names of appropriate alcohols Describes uses of alcohols Highlights environmental issues Presentation Appropriate title Introduction to report Targeted at the correct audience 6 Peer Assessment Present in report GRADE ACIEVED Grading criteria Grade A: All parts are present in the report and have been completed to a high standard. The chemistry is correct and is described in a clear and logical way. All equations are correct and explanations are well thought out and understandable. Presentation is excellent and points have been illustrated using good, clear diagrams. It is easy to follow and adds to the readers knowledge and understanding. They have self-assessed the work. Grade B: All parts are present in the report and have been completed to a good standard. The chemistry is correct and is described in a logical way. All equations are correct and explanations are understandable. Presentation is good and points have been illustrated using clear diagrams. It is easy to follow and adds to the readers knowledge and understanding. They have self-assessed the work. Grade C: Most parts are present in the report and those parts that have been completed are done to a satisfactory standard. The chemistry is correct. All equations are correct and any explanations given are understandable. Presentation is satisfactory and some points have been illustrated using diagrams. It can be followed and adds to the readers knowledge. They have self-assessed the work. Grade D: An attempt has been made to carry out the task and the parts that have been attempted are chemical correct. There are very few if any diagrams. Presentation is not good but the report can be followed although with a little difficulty. A lot more effort should have been put in. They have sort of self-assessed the work. Grade F: No serious attempt has been made to complete the task described. There is some chemistry presented on paper but it looks like it has been done the night before. They have not self-assessed the work. Task 7b: Peer Assessment Assess this piece of work that has been given to you to mark. Go through the points on the mark grid and tick them off in the peer assessment column if they have been done. Also record if they have been done to a high standard. Then give a grade according to the statements underneath the mark grid. Peer Assessed by:__________________________________________ Write down here what they could have done to improve: _____________________________________________________________________ _____________________________________________________________________ _____________________________________________________________________ 7 Reflecting on Learning Task 8: In this self-study guide you have been asked to do a number of tasks. By answering the following questions you are reflecting on the learning that has taken place and consequently will improve your Independent Learning ability and your understanding of alkenes. 1. Did you use all the available resources allowed when completing the tasks set? What resources did you use? (reference them) ________________________________________________________________ ________________________________________________________________ ________________________________________________________________ 2. After completing the Reading for Understanding section did you have a better understanding of alkenes and their uses than when you just read through the text book once? Would you add any other steps in this section to improve your Reading for Understanding? If so what? ________________________________________________________________ ________________________________________________________________ ________________________________________________________________ 3. List the steps you took when writing your report. E.g. read texts, made notes, researched on web pages, read notes, thought up sub headings for sections, wrote introduction, etc…… Would you change the way you did it next time? If so how and why? ________________________________________________________________ ________________________________________________________________ ________________________________________________________________ ________________________________________________________________ ________________________________________________________________ 8