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Chemistry 1 Revision: C5 Alkenes, cracking, making ethanol and polymers Task 1: Use the revision guide to produce a mini mind map or bullet point summary for the following key areas on this topic. Task 2: Practise past questions and assess using the mark scheme Cracking Polymers alkenes CnH2n bromine catalyst colourless double heated shorter smaller unsaturated cracking vaporised cooled deformed dental double ethene heated hydrogels join monomers original packaging poly(ethene) poly(propene) polymers propene small waterproof wound Long chain hydrocarbons are broken down into smaller more useful molecules by c……………………………..: In polymerisation the d………….… bonds in many s………………… molecules 1. long chain fraction is h…………………… and v………………………………. – called m………………….……. – open up so that the monomers can j…………. 2. vapours pass over a c……………………… together to form very large molecules called p……….……….….. e.g. 3. products have s……………….. chains / are s…………………. molecules containing fewer carbon atoms 4. products of cracking are a mixture of a…………………… and alkanes n → n Alkenes General formula ……………………… U………………………………………. hydrocarbons – have a d………………… carbon-carbon bond e....……………. p…………………………………………… Complete the diagram below to show how the monomer forms a polymer. What are the names of the monomer and the polymer? Alkenes react with b……………… water, turning it from orange to c…………………….. Ethanol carbon dioxide carbon neutral energy ethene fast few food habitat high impure land labour locked up low many non-renewable not oil other plants pure renewable slow sugar temperature waste water Hydration of ethene (from o…..…….) Fermentation of sugar (from p……………..) e……………… + w…………..…. → ethanol s……….… → ethanol + c………….. d……….….. disadvantages advantages • n...………………………….. resource • r………………..…………….. resource • higher t……………………………….. needed for process so uses • lower t……………………………………….. needed for process – so uses more e …………………… less e……………………… • h………. safety risk • n………….. carbon neutral – releases l………… u…… carbon • risk of major o…….. spillage • ethene could be used to make o……………… products advantages • continuous process – f……….. • f……….. steps in the process • ethanol is p…………. • ‘conserves’ f……………. break down p…….…………………………………………. Polymers have many uses e.g. p……………………….., w…………………………………… coatings for fabrics, d…………………… polymers, w………………… dressings, and h……………………………. Shape memory polymers can be d……………………. but return to their o………………………… shape when heated or cooled. Disposal of polymers biodegradeable carbon collected crude oil electricity energy expensive explosions fewer fuel heating landfill methane products split times toxic waste Advantages Re-use saves raw materials/c………… o…… Disadvantages • l…………. safety risk saves e………………. bags easily s…………… • c………………. n………….…………. carbon dioxide used by plants in photosynthesis f………………… bags needed reduces c…………… /CO2 emissions • can use w…………….. plant material disadvantages saves cost of new bags • batch process – s…………. • m………….. steps in the process saves e…………………. • ethanol is i………………… reduces c………….. /CO2 emissions • potential f……………. shortages reduces use of l……………….. • needs large areas of l…………. to grow crops and particular climates • potential h………………… loss • crops grow slowly can be used for new p………………… Burned • l……………………. intensive process e…………………………………. microbes polymers soil waste Many p………………………. are not b……………………………….., so they are not broken down by m…………………………… in the s…………... This can lead to problems with w…………………….. disposal. Biodegradable plastics made from corn starch have been developed; these b………………….. d…………………. more easily. unable to reuse many t……. reduces use of l………………… no w……………. Recycled saves raw materials/c………… o….. Biodegradeable polymers biodegradeable p……………………… e…………….. released can be used for h……………….. / generating reduces use of l………………………. Dumped can be c……………….. / transported with household w………………………… some plastics are b……………………….... - slow breakdown produces m……………………. which can be used as a f……………. non-b………………………………. plastics will not release CO2 / into the air has to be c…………………… / transported / washed / separated / melted – can be e………………………. has to be c…………………………. / transported w……………….. of resources releases t……… gases /CO2 w………………….. of resources plastic uses l……………………… produces m………………………. which is a greenhouse gas / could cause e………………………… not b…………………………………….