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1. Given the balanced equation: 2Na + S → Na2S What is the total number of moles of S that reacted when 4.0 moles of Na were completely consumed? 1) 1.0 mole 3) 0.5 mole 2) 2.0 moles 4) 4.0 moles 2. Given the reaction: N2(g) + 3H2(g) → 2NH3(g) What is the total number of moles of NH3(g) produced when 10. moles of H2(g) reacts completely with N2(g)? 9. Given the equation: 2 C2H2(g) + 5 O2(g) - 4 CO2(g) + 2 H2O(g) 10. 1) 6.7 3) 3.0 2) 2.0 4) 15 3. Given the balanced equation: 11. 2 C4H10(g) + 13 O2(g) → 8 CO2(g) + 10 H2O(g) What is the total number of moles of O2(g) that must react completely with 5.00 moles of C4H10(g)? 1) 10.0 3) 26.5 2) 20.0 4) 32.5 4. Given the reaction: Ca + 2H2O → Ca(OH)2 + H2 How many moles of H2O are needed to exactly react with 2.0 moles of Ca? 1) 1.0 3) 0.50 2) 2.0 4) 4.0 5. Given the reaction: 12. 13. PbCl2(aq) + Na2CrO4(aq) → PbCrO4(s) + 2 NaCl(aq) What is the total number of moles of NaCl formed when 2 moles of Na2CrO4 react completely? 1) 1 mole 3) 3 moles 2) 2 moles 4) 4 moles 6. Given the equation: Zn + 2HCl → ZnCl2 + H2 How many moles of HCl would be required to produce a total of 2 moles of H2? 1) 0.5 3) 3 2) 2 4) 4 7. Given the reaction: 2Na + 2H2O → 2NaOH + H2 What is the total number of moles of hydrogen produced when 4 moles of sodium react completely? 1) 1 3) 3 2) 2 4) 4 8. Given the reaction: 6 CO2 + 6 H2O →C6H12O6 + 6 O2 What is the total number of moles of water needed to make 2.5 moles of C6H12O6 ? 1) 2.5 3) 12 2) 6.0 4) 15 14. 15. 16. How many moles of oxygen are required to react completely with 1.0 mole of C2H2? 1) 2.5 3) 5.0 2) 2.0 4) 10 Given the equation: 2C4H10 + 13O2 → 8CO2 + 10H2O How many moles of carbon dioxide are produced for each mole of butane consumed? 1) 1 3) 8 2) 2 4) 4 Given the reaction: 4Al(s) + 3O2(g) → 2Al2O3(s) What is the minimum number of grams of oxygen gas required to produce 1.00 mole of aluminum oxide? 1) 32.0 g 3) 96.0 g 2) 48.0 g 4) 192 g In the reaction Fe2O3 + 3CO → 2Fe + 3CO2, what is the total number of moles of CO used to produce 112 grams of iron? 1) 1.0 3) 3.0 2) 2.0 4) 4.0 Given the balanced equation: Fe(s) + CuSO4(aq) - FeSO4(aq) + Cu(s) What total mass of iron is necessary to produce 1.00 mole of copper? 1) 26.0 g 3) 112 g 2) 55.8 g 4) 192 g According to the reaction H2 + Cl2 → 2HCl, the production of 2.0 moles of HCl would require 70. grams of Cl2 and 1) 1.0 g of H2 2) 2.0 g of H2 3) 3.0 g of H2 4) 4.0 g of H2 Given the balanced equation: NaOH + HCl → NaCl + H2O What is the total number of grams of H2O produced when 116 grams of the product, NaCl, is formed? 1) 9.0 g 3) 36 g 2) 18 g 4) 54 g Given the reaction: 4Al + 3O2 → 2Al2O3 How many moles of Al2O3 will be formed when 27 grams of Al reacts completely with O2? 1) 1.0 3) 0.50 2) 2.0 4) 4.0 17. Given the reaction: 2C2H6 + 7O2 → 4CO2 + 6H2O What is the total number of CO2 molecules produced when one mole of C2H6 is consumed? 1) 6.02 × 1023 3) 3(6.02 × 1023) 23 2) 2(6.02 × 10 ) 4) 4(6.02 × 1023) 18. In a laboratory experiment, a student reacted 2.8 grams of Fe(s) (steel wool) in excess CuSO4(aq), according to the following balanced equation: Fe(s) + CuSO4(aq) → FeSO4(aq) + Cu(s) When the Fe(s) was completely consumed, the precipitated Cu(s) had a mass of 3.2 grams. Did the student's result in this experiment verify the mole ratio of Fe(s) to Cu(s) as predicted by the equation? 1) Yes, because the experimental result was 2:1. 2) No, because the experimental result was 2:1. 3) Yes, because the experimental result was 1:1. 4) No, because the experimental result was 1:1. 19. Given the reaction: Cu + 4HNO3 → Cu(NO3)2 + 2H2O + 2NO2 What is the total mass of H2O produced when 32 grams of Cu is completely consumed? 1) 9.0 g 3) 36 g 2) 18 g 4) 72 g 20. Given the reaction: N2 + 3H2 → 2NH3 How many grams of ammonia are produced when 1.0 mole of nitrogen reacts? 1) 8.5 3) 34 2) 17 4) 68 21. Magnesium was reacted with an excess of dilute hydrochloric acid and the hydrogen gas produced collected in a eudiometer. The volume of hydrogen in the eudiometer was corrected to conditions of STP. If 94.1 milliliters of hydrogen was produced, how much magnesium reacted in this experiment? 1) 0.01 g 3) 0.05 g 2) 0.10 g 4) 0.50 g 22. Given the equation: 6CO2(g) + 6H2O(l) → C6H12O6(s) + 6O2(g) What is the minimum number of liters of CO2(g), measured at STP, needed to produce 32.0 grams of oxygen? 1) 264 L 3) 192 L 2) 32.0 L 4) 22.4 L 23. Given the reaction: Mg + H2SO4 → MgSO4 + H2 How many grams of H2SO4 are needed to produce exactly 11.2 liters of H2, measured at STP? 1) 24.5 3) 98.0 2) 49.0 4) 196 24. Given the reaction N2(g) + 3H2(g) → 2NH3(g) How many liters of ammonia, measured at STP, are produced when 28.0 grams of nitrogen is completely consumed? 1) 5.60 3) 22.4 2) 11.2 4) 44.8 25. In a laboratory experiment, a student determined the mass of the product, KClO3(s), to be 45.7 grams. a. Calculate the gram formula mass of KClO3(s). Round atomic masses from the Periodic Table to the nearest tenth. [Show all work. Indicate the correct answer in proper significant figures and include an appropriate unit.] b. Calculate the number of moles of KClO3(s) produced. [Show all work. Indicate the correct answer in proper significant figures.] 26. Given the unbalanced equation: __Al2(SO4)3 + __Ca(OH)2 → __Al(OH)3 + __CaSO4 Balance the equation using smallest whole number coefficients. 27. Base your answer to the following question on the unbalanced equation provided: ___ C5H12(g) + ___ O2(g) → ___ CO2(g) + ___ H2O(g) Balance the equation using the smallest whole-number coefficients. 28. Given the compound C4H10O8, a Calculate the molar masss of the compound. b Calculate the number of moles in 17.7 grams of the compound. c What is the empirical formula for this compound? 29. Base your answer to the following question on the information and equation below. Antacids can be used to neutralize excess stomach acid. Brand Aantacid contains the acid-neutralizing agent magnesium hydroxide, Mg(OH)2. It reacts with HCl(aq) in the stomach, according to the following balanced equation: 2 HCl(aq) + Mg(OH)2(s) → MgCl2(aq) + 2 H2O(…) If a person produces 0.050 mole of excess HCl in the stomach, how many moles of Mg(OH)2 are needed to neutralize this excess hydrochloric acid? 30. Base your answer to the following question on the balanced chemical equation below. 2 H 2O → 2 H 2 + O 2 How does the balanced chemical equation show the Law of Conservation of Mass? 31. A student heats a 243 gram sample of BaCl2 • 2H2O hydrated crystals? a What was the percentage by mass of water in the hydrated crystals?[Show all work] b If all the water was driven out of the crystal, what would be the expected weight of the BaCl2 sample remaining?[Show all work] 32. Base your answer to the following question on the information below, which describes the smelting of iron ore, and on your knowledge of chemistry. In the smelting of iron ore, Fe2O3 is reduced in a blast furnace at high temperature by a reaction with carbon monoxide. Crushed limestone, CaCO3, is also added to the mixture to remove impurities in the ore. The carbon monoxide is formed by the oxidation of carbon(coke), as shown in the reaction below: 2 C + O2 - 2 CO + energy Liquid iron flows from the bottom of the blast furnace and is processed into different alloys of iron. Balance the equation for the reaction of Fe2O3 and CO using the smallest whole-number coefficients. Base your answers to questions 33 and 34 on the particle diagrams below, which show atoms and/or molecules in three different samples of matter at STP. 33. Which sample represents a pure substance? 34. Explain why (x)(x) does not represent a compound. 35. The following procedures are carried out during a laboratory activity to determine the mass in grams of CuSO4 in a hydrated sample of CuSO4•5H2O. Step 1 Determine the mass in grams of the crucible and CuSO4•5H2O. Step 2 Determine the mass in grams of the crucible and CuSO4 Step 3 Determine the mass in grams of CuSO4•5H2O. Step 4 Determine the mass in grams of the empty crucible. Step 5 Determine the mass in grams of CuSO4 Arrange the steps above in the order that the student should use to determine the mass of CuSO4 in the sample. _______, _______, _______, _______, ________ 36. Base your answers to the following questions on the information below. For health reasons, the element chlorine is added to the drinking water because it will kill disease-causing organisms. Typically 0.50 ppm of chlorine is added to drinking water to make it safe. In 2.0 liters of drinking water (2000.g), how many grams of chlorine is present?[Show all work. Include in your answer proper units and significant figures.] 37. In a laboratory experiment, a student determined the mass of the product, CaSO4(s), to be 31.9 grams. a Calculate the gram formula mass of CaSO4(s). Round atomic masses from the Periodic Table to the nearest tenth. [Show all work. Indicate the correct answer in proper significant figures and include an appropriate unit.] b Calculate the number of moles of CaSO4(s) produced. [Show all work. Indicate the correct answer in proper significant figures.] 38. In a laboratory experiment, a student determined the mass of the product, NaCl(s), to be 1.84 grams. a Calculate the gram formula mass of NaCl(s). Round atomic masses from the Periodic Table to the nearest tenth. [Show all work. Indicate the correct answer, including an appropriate unit.] b Calculate the number of moles of NaCl(s) produced. Show all work. Indicate the correct answer. 39. Given the unbalanced equation: __NH3 + __O2 → __HNO3 + __ H2O balance the equation using the smallest whole number coefficients. 40. In a laboratory experiment, a student determined the mass of the product, HgBr(s), to be 98.7 grams. a Calculate the gram formula mass of HgBr(s). Round atomic masses from the Periodic Table to the nearest tenth. [Show all work. Indicate the correct answer in proper significant figures and include an appropriate unit.] b Calculate the number of moles of HgBr(s) produced. [ Show all work. Indicate the correct answer in proper significant figures.] 41. Given the unbalanced equation: __Li + __N2 → __Li3N balance the equation using smallest whole number coefficients. 42. Base your answers to the following questions on the information below. Rockets use as fuel, liquid hydrogen, H2(l) and liquid oxygen , O2(l) , which react together forming hot gaseous water. This reaction provides the energy to lift the the shuttle and it's crew. Write a balanced equation for the reaction of liquid hydrogen with liquid oxygen to produce gaseous water. Include the energy term ( " + energy" ) in your equation. 43. In a laboratory experiment, a student determined the mass of the product, LiCl(s), to be 0.333 grams. a Calculate the gram formula mass of LiCl(s). Round atomic masses from the Periodic Table to the nearest tenth. [Show all work. Indicate the correct answer in proper significant figures and include an appropriate unit.] b Calculate the number of moles of LiCl(s) produced. [Show all work. Indicate the correct answer in proper significant figures.] 44. In a laboratory experiment, a student determined the mass of the product, NaNO3(s), to be 0.105 grams. a. Calculate the gram formula mass of NaNO3(s). Round atomic masses from the Periodic Table to the nearest tenth. [ Show all work. Indicate the correct answer in proper significant figures and include an appropriate unit.] b. Calculate the number of moles of NaNO3(s) produced. [Show all work. Indicate the correct answer in proper significant figures.] Reference Tables Answer Key 1. 2 2. 1 3. 4 30. Acceptable responses: 4 H and 2 O on both sides; 4 H = 4 H and 2 O = 2 O; same number of each element on both sides. 4. 4 31. a) 36/ (137 + 71 + 36) × 100 = 15% b) 207 grams 5. 4 32. 1 Fe2O3 + 3 CO - 2 Fe + 3 CO2 6. 4 33. Allow credit for 3. 7. 2 34. Acceptable responses: A compound must contain two or more different elements, only 1 kind of atom present. 8. 4 9. 1 29. 0.025 35. 4,1,3,2,5 36. 0.0010 g 10. 4 11. 2 12. 3 13. 2 14. 2 15. 3 40. a) 200.6 + 79.9 = 280.5g 0.352 mole 16. 3 41. _6_Li + _1_N2 → _2_Li3N 17. 2 42. 2 H2(l) + O2(l) → 2 H2O(g) + energy 18. 3 19. 2 43. a) 6.9 + 35.5 = 42.4g 0.00785 mole 20. 3 21. 2 22. 4 23. 2 24. 4 25. a) 39.1 + 35.5 + 3(16.0) = 122.6 g mole/122.6g = .373 mole 37. a) 40.1 + 32.1 + 4(16.0) = 136.2 g mole/136.2g = 0.234 mole 38. a) 23.0 + 35.5 = 58.5 g 0.0315 mole b) 31.9g x 1.00 b) 1.84 g × 1.00 mole/58.5 g = 39. 1 NH3 + 2 O2 → 1 HNO3 + 1 H2O b) 98.7g × 1.00 mole/280.5g = b) 0.333g × 1.00 mole/42.4g = 44. a) 23.0 + 14.0 + 3(16.0) = 85.0 g mole/85.0g = 0.00124 mole b) 45.7g x 1.00 26. _1_Al2(SO4)3 + _3_Ca(OH)2 → _2_Al(OH)3 + _3_CaSO4 27. Allow credit for C5H12(g) + 8 O2(g) → 5 CO2(g) + 6 H2O(g). Allow credit even if the coefficient “1” is written in front of C5H12 (g) 28. a) 186 grams b) .095 moles c) C2H5O4 b) 0.105g x 1.00