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Carbohydrates-sugars Made of C, H,O Carb = Carbon hydr = water Carbohydrate = carbon + water general formula = CH2O 2-1 ratio of hydrogen to oxygen like water H2O ribose C5H10O5 glucose C6H12O6 sucrose C12H22O11 many carbohydrate names end in -ose More carbohydrate basics Monomer: monosaccharide – one sugar Functions of carbohydrates: Energy for metabolism (glucose) Short term energy storage (glycogen/starch) Structure: plants – cell wall animals – exoskeleton Source of carbon for other molecules Cell surface markers – cell identification Monosaccharide: Simple Sugars Monosaccharides like glucose are the main source of energy in living things Disaccharides - 2 sugars 2 monosaccharides linked together by dehydration synthesis - form a glycosidic bond Examples: Sucrose – Table Sugar glucose + fructose Lactose – Milk Sugar glucose + galactose Maltose – glucose + glucose Polysaccharides-Many Sugars Polysaccharides are polymers composed of large numbers of monosaccharides. - the monosaccharides are joined by dehydration synthesis - form glycosidic bonds Used for short term energy storage and structure Energy Storage Polysaccharides Starch Chloroplast Starch polymer made up of glucose monomers Stores glucose in plants 1 m Starch: a plant polysaccharide Glycogen Polymer of glucose monomers Is the major storage form of glucose in animals Stored in liver and muscle More highly branched than Mitochondria Glycogen granules starch – contains more stored energy 0.5 m Glycogen Glycogen: an animal polysaccharide Starch and Glycogen are Easily Broken Apart by Hydrolysis Allows the stored glucose to be easily used Structural Polysaccharides Cellulose Is a polymer of glucose – connected in a straight unbranched chain Multiple strands of cellulose are held together by hydrogen bonds – makes a rigid structure Is a major component of the tough walls that enclose plant cells Cell walls Cellulose microfibrils in a plant cell wall Microfibril About 80 cellulose molecules associate to form a microfibril, the main architectural unit of the plant cell wall. 0.5 m Plant cells Parallel cellulose molecules are held together by hydrogen bonds between hydroxyl groups attached to carbon atoms 3 and 6. Figure 5.8 OH CH2OH OH CH2OH O O O O OH OH OH OH O O O O O O CH OH OH CH 2 2OH H CH2OH OH CH2OH OH O O O O OH OH OH OH O O O O O O CH OH OH CH 2 2OH H CH2OH OH OH CH2OH O O O O OH OH OH O O OH O O O O CH OH OH CH2OH 2 H Glucose monomer Cellulose molecules A cellulose molecule is an unbranched glucose polymer. Cellulose is difficult to digest Animals can’t break the bonds between the glucose molecules –dietary fiber Animals that eat plants have bacteria in their stomachs that can break the bonds of cellulose- allow their hosts to digest plants Figure 5.9 Chitin, another important structural polysaccharide Is a polymer of a form of glucose with an attached functional group Is found in the exoskeleton of arthropods CH2O H O OH H H OH H OH H H NH C O CH3 (a) The structure of the chitin monomer. Figure 5.10 A–C (b) Chitin forms the exoskeleton (c) Chitin is used to make a of arthropods. This cicada strong and flexible surgical is molting, shedding its old thread that decomposes after exoskeleton and emerging the wound or incision heals. in adult form. Other Uses for Carbohydrates Cell surface markers – carbohydrates attached to parts on the cell membrane where they act to identify the cell ABO blood groups are identified by carbohydrates on their surface Vocabulary to Know and Love Carbohydrate Monosaccharide Glucose Disaccharide - examples of disaccharides Polysaccharide Starch Glycogen cellulose Chitin - 5 functions of carbohydrates - 3 elements found in carbohydrates - Iodine test- positive test and what molecule it indicates - Bendict’s test –positive test and what molecule it indicates