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Sedimentation & Stratigraphy (89.352) http://faculty.uml.edu/lweeden/SedStrat.htm Kinds of Sedimentary Rocks Siliciclastic: sedimentary rocks that are composed of dominantly silicate materials, such as quartz, feldspar, and rock fragments. (i.e.: Conglomerates, sandstones & shales.) Volcaniclastic: Siliciclastic sedimentary rocks that are formed mainly from the products of explosive volcanism. (i.e.: conglomerate composed primarily of fragment of volcanic glass and rocks – Breccia & Tuff.) Chemical/Biological: sedimentary rocks that are composed of minerals precipitated mainly from ocean or lake water by inorganic and or organic processes. (i.e.: limestone, chert, gypsum and ironrich sedimentary rocks.) Carbonaceous: sedimentary rocks that contain (>~15%) highly altered remains of the soft tissue of plants and/or animals. (i.e.: coal & oil shale.) Sedimentology: The scientific study of the classification, origin and interpretation of sediments and sedimentary rocks. Stratigraphy: The science of rock strata. It is concerned more with processes and establishment. Diagenesis: Any chemical, physical, or biological change undergone by a sediment after its initial deposition and during and after its lithification, exclusive of surface alteration (weathering) and metamorphism. These changes happen at relatively low temperatures and pressures and result in changes to the rock's original mineralogy and/or texture. Weathering: Physical disintegration and chemical decomposition of older rock to produce solid particulate residues. Brief History of Sedimentation and Stratigraphy Nicolas Steno (1638 – 1686) Principles of Superposition and Original Horizontality. James Hutton (1727 – 1797) Principle of Uniformitarianism (aka. Actualism) William “Strata” Smith (1769 – 1839) Law of Faunal Succession. Johannes Walther (1860 – 1937) Walther’s Law of succession of facies Chapter 1: Weathering and Soils I. Physical Weathering A. Freeze – Thaw (Frost Wedging) B. Insolation Weathering C. Salt Weathering D. Wetting & Drying Weathering E. Stress Release Weathering F. Other Physical Process How does surface area contribute to weathering processes? Frost Wedging Insolation Weathering (Spalling) Salt Weathering Wetting and Drying Weathering Stress – Release Weathering II. Chemical Weathering (Table 1.1) A. Simple Solution B. Hydrolysis C. Oxidation / Reduction D. Hydration / Dehydration E. Ion Exchange F. Chelation III. Weathering Rates There is no mathematical solution to precise weathering rates. It is all relative…. A. Climate (physical - cold and dry; chemical – hot and wet.) B. Stability of Minerals “Happiness Principle” Table 1.2 C. Subaerial Weathering (Table 1.3) D. Submarine Weathering 1.Halmyrolysis 2.Magnitude of Circulation and effects. Physical weathering dominates in cold and dry climates. Chemical weathering dominates in warm and wet climates. Stability of Minerals and “The Happiness Principle” Order of increasing “weatherability” Table 1.2 Sand and Silt-size minerals Mafic Minerals Olivine Felsic Minerals Ca plagioclase Pyroxene Amphibole Ca-Na plagioclase Na-Ca plagioclase Na plagioclase Biotite K-feldspar Muscovite,quartz (increasing stability) Clay-size minerals 1. Gypsum, halite 2. Calcite, dolomite, apatite 3. Olivine, amphiboles, pyroxenes 4. Biotite 5. Na plagioclase, Ca plagioclase, Kfeldspar, volcanic glass 6. Quartz 7. Muscovite 8. Vermiculite (clay mineral) 9. Smectite (clay mineral) 10.Pedogenic (soil) chlorite 11.Allophane (clay mineral) 12.Kaolinite, halloysite (clay mineral) 13.Gibbsite, boehmite (clay mineral) 14.Hematite, goethite, magnetite 15.Anatase, titanite, rutile, ilmenite (all titanium-bearing minerals), zircon Subaerial Weathering (Table 1.3) Weathering process Type of Weathering product Physical weathering Particulate residues Example Ultimate depositional product Silicate minerals such as quartz and feldspar; all types of rock fragments Sandstones, conglomerates, mudrocks Chemical weathering Hydrolysis Soluble constituents Secondary minerals Simple solution Oxidation Soluble constituents Secondary minerals Soluble constituents + Silicic acid (H4SiO4); K , + 2+ 2+ Na , Mg , Ca , etc. Clay minerals + + Silicic acid; K , Na , 2+ 2+ Mg , Ca , HCO3 , 2SO4 , etc. Ferric oxides (Fe2OOH); manganese oxides (MnO2) 2Silicic acid; SO4 Cherts, limestones, etc. Mudrocks (shales) Limestones, evaporites, chert, etc. Minor constituent in Siliciclastic rocks Chert, evaporites, etc. Submarine Weathering and Halmyrolysis IV. Soils A. Soil is a product of bedrock weathering. B. The thickness and characteristics of a soil is a function of: 1. Bedrock lithology 2. Slope of bedrock surface 3. Climate 4. Biological activity 5. Additions to ground surface C. Transformation D. Transfers E. Removals F. Bioturbation of Soils Soil-Forming Processes 1. Additions to the ground surface—Precipitation of dissolved ions in rainwater; influx of solid particles (dust, etc.); addition of organic matter from surface vegetation (leaf litter, etc .) 2. Transformations a. Decomposition of organic matter with soils to produce organic compounds. b. Weathering of primary minerals; formation of secondary minerals, including iron oxides. 3. Transfers a. Movement of solid or suspended material downward from one soil horizon to a lower horizon by groundwater percolation (eluviation) b. Accumulation of soluble or suspended material in a lower horizon (illuviation) c. Transfer of ions upward by capillary movement of water and precipitation of ions in the soil profile Soil forming processes continued… 4. Removals—Removal of substances still in solution to become part of the dissolved constituents in groundwater or surface water 5. Bioturbation of soil—Soil disrupted by animals (i.e. ants and termites) and plants. G. Soil Profile Bedrock Water enters system Minerals leached Altered minerals accumulated with different chemistry than original material H. Soil Classification (Taxonomy) 1. 2. 3. 4. 5. 6. Gelisols Histosols Spodosols Andisols Oxisols Vertisols 7. Aridisols 8. Ultisols 9. Mollisols 10. Alfisols 11. Inceptisols 12. Entisols Review climatic effects of soil formation. I. Paleosols—ancient soils, fossil soils or soils that escaped the effects of erosion to become part of the sedimentary record. Recognition of Paleosoils – Glaebules, Mottles & Burrows…Oh my! See Figure 1.6 of Text