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Chapter 4.3 Distinguishing Among Atoms Atomic Number number of protons in the nucleus is what defines different atoms. ► Atomic Number—the number of protons in the nucleus of an atom of that element. ► For atoms (which are electrically neutral), the number of protons is equal to the number of electrons. ► Different Mass Number ► The total number of protons and neutrons in the nucleus of an atom is called the mass number. ► The number of neutrons in an atom can be calculated if you know the atomic number and the mass number. ► Number of neutrons = mass number minus atomic number. ► Shorthand notation uses: ► Superscript—mass number ► Subscript—atomic number ► Both to the left of the chemical symbol. ► Also may be written as the chemical name followed by the mass number. Example: Gold-197 Isotopes ► Atoms of an element with different numbers of neutrons are known as isotopes. Because they have different number of neutrons, they also have different mass numbers. Atomic Mass ► Using grams to indicate masses of individual atoms results in numbers that are inconveniently small. ► Instead, the carbon-12 isotope is used as a reference standard. ► An atomic mass unit (amu) is defined as one twelfth the mass of a carbon-12 atom. ► The masses of the electrons are insignificant when calculating atomic mass. ► The atomic mass of an element is usually not a whole number. ► Because of an element’s isotopes, the element’s atomic mass is a weighted average of the relative abundance of the isotopes as they occur in nature. ► To calculate atomic mass, multiply the mass of each isotope by its natural abundance, expressed as a decimal, and then add the products.