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Periodic Table The Basics Chemistry Mrs. Sousa & Mr. Pickin 5/24/2017 1 Introduction 5/24/2017 This presentation will give you all the information you need to know about the basic organization of the periodic table 2 Origin 5/24/2017 The periodic table was first devised by Dmitiri Mendeleev in Russia in 1869 Based on the “Periodic Law” which states that the properties of the elements repeat periodically 3 Basics 5/24/2017 Elements listed by increasing atomic number (Unique for each element) (thus properties) Atomic number is the number of protons contained in the nucleus of an atom of an element 4 Major Divisions in Table 5/24/2017 Metals (<4 valence electrons) form + ions (cations). Ionic bonds Non-metals (>4 valence electrons) form - ions (anions). Covalent bonds Metalloids (semi-metals) Separated by zig-zag line Image 5 Periods 5/24/2017 Horizontal (across) rows are called periods. Properties of elements change across the period. 7 periods (maximum) Period number is the number of energy levels each element contains in that row (quantum # n value as well) 6 Groups/Families Either term acceptable 5/24/2017 Vertical columns 18 families Numbered from left to right Members of the same family have very similar chemical and physical properties. Atoms increase in size as you get lower in a group. 7 Representative Families. Representative families are 1,2,13, 14,15,16,17,18 Ones place is the number of valence electrons In other words- for 13-18 put your finger over the #1! Ex. Family 16 has 6 valence electrons Valence electrons are those in the outer energy level – they are used for bonding and come from the s & p orbital space Noble Gases (group #18) all have 8 valence electrons. Exception to the octet rule: He (helium) has 2 valence electrons 5/24/2017 8 Common Names 1-Alkali metals (most active metals) 2-Alkaline earth metals 16-Chalcogens 5/24/2017 17-Halogens (most active non-metals) 18- Noble gases (not reactive) 3-12 Transition metals (1 or 2 valence electrons) Lanthanide series (AN 57-71) Actinide series (AN 89-103) 9 Regions of the Periodic Table 5/24/2017 10 Group 1: Alkali Metals Reaction of potassium + H2O Cutting sodium metal 5/24/2017 11 Group 2: Alkaline Earth Metals Magnesium Magnesium oxide 5/24/2017 12 Group 17: The Halogens (salt makers) F, Cl, Br, I, At 5/24/2017 13 Group 18: The Noble (Inert) Gases He, Ne, Ar, Kr, Xe, Rn Lighter than air balloons “Neon” signs Very Unreactive because they have full electron levels 5/24/2017 XeOF4 14 Transition Metals (elements) Families 3-12 Lanthanide series click Actinide series Multivalent – can have 1, 2, 3 valence electrons – depending on what other atoms they are bonding with. 5/24/2017 15 Transition Elements Lanthanides and actinides Iron in air gives iron(III) oxide 5/24/2017 16 s, p, d, f blocks 5/24/2017 17 Atomic Radius (size) • The trend is that: •Atoms get smaller going across a period (Noble gases are the exception) •Atoms get larger going down a family 5/24/2017 18 Atomic Radius (cont.) 5/24/2017 19 Atomic Radius (cont) 5/24/2017 20 Ionization Energy (IE) The amount of energy necessary to remove one or more electrons from an atom in its gaseous state Generally: Metals have low IE Non-metals have high IE 5/24/2017 21 Ionization Energy (IE) 5/24/2017 IE increases across a period IE decreases down a family 22 Electronegativity (EN) The tendency of an atom to attract electrons (affinity for electrons) An atom's electronegativity is affected by both the positive charge in the nucleus and the distance that its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. Range of EN’s for the elements is 0.7 (Fr) to 4.0 (F) Trend: EN increases across a period and decreases down a family 5/24/2017 23 Electronegativity (EN) Trend 5/24/2017 24 Electronegativity (cont.) 5/24/2017 25 Electron Affinity 5/24/2017 The energy released when an electron is added to a neutral atom. (exothermic process) for the first added electron the process is exothermic 26