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Ionic radius is related to the valence of the ion - ions that have lost electrons (cations) are smaller than their neutral state, ions that have gained electrons (anions) are larger. If two cations are similar in ionic radius, one may substitute for another in a mineral structure. One of the more common substitutions is between Fe2+ (~0.63 angstrom) and Mg2+ (~0.57) and often a mineral contains a mixture of both Example is olivine - Fe2SiO4 = fayalite; Mg2SiO4 = forsterite; olivine = (Mg,Fe)2SiO4 Ca2+ and Na+ can also substitute for each other in plagioclase feldspar. Silicates (SiO4)4-: The largest mineral group due to the fact that silicates are made up of the two most abundant elements in the crust: silicon and oxygen. The basic building block is the silica tetrahedra As oxygen : silicon ratio decreases, more and more silicon ions must share oxygen atoms in order to complete their tetrahedra. Silicate mineralogy 1.Isolated tetrahedra (monomer). O:Si = 4, olivine is the most common example (Fe,Mg)2SiO4 no cleavage. Understand Solid solution of Fe-Mg 2.Single chain - silicate tetrahedra share oxygens with two other tetrahedra forming a long open ended chain. O:Si = 3 , pyroxenes, 2 cleavages at ~90, Si2O6 3.Double chain: two singles chains link together so each tetrahedra shares oxygens with three other tetrahedra. O:Si = 2.75, amphiboles, 2 cleavages at 60 and 120, Si8O22 4.Sheet silicates: silica tetrahedra form large sheets (link to three other tetrahedra) with all of the non-shared oxygens pointing in the same direction, Micas (biotite, muscovite):1 direction of cleavage. O:(Si+Al) = 2.5 5. Framework silicates: 3-d frameworks, all oxygens shared. O:Si+Al = 2. Common groups include quartz and feldspars (potassium feldspar/orthoclase, plagioclase). Most abundant minerals in the earth’s crust. (Solid solution in plagioclase) Can see increasing amount of SiO2 with increasing polymerization-also lower temperature. • Cabonates: calcite, dolomite • Oxides: magnetite, hematite • Sulfides, sulfates, halides, native elements How to ID minerals: Hardness: Moh’s scale Specific gravity Other properties (fizz, magnetic) Moh’s scale Color not always! streak Crystal habit Cleavage-feldspars Cleavage Concoidal fracture Carbonates fizz