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Magnesium Cycle Click on green circle to return to main cycle Crop removal Plant uptake as Mg2+ at root tip Plant residue and Microbial population Chelates in solution Leaching MgSO4 Mg fertilizer PPT Soil Solution Erosion Secondary clay and humus Weathering Authors: Jeffrey Ball, Mark Everett, Rick Kochenower, and Heather Qualls Where you can go Where you have been CEC More Info. Plant uptake as Mg2+ at root tip Dolomite, MgSO4, MgO, Mangesite,Magnesia, Kainite, Langbeinite, Epsom salts Mg fertilizer Soil Solution Secondary clay and humus Oxides Silicates Sulfides Etc Where you can go Where you have been More Info. Crop removal Plant uptake as Mg2+ at root tip Plant residue and Microbial population Chelates in solution Mg fertilizer Dolomite, MgSO4, MgO, Mangesite,Magnesia, Kainite, Langbeinite, Epsom salts Soil Solution Where you can go Where you have been More Info. Crop removal Plant uptake as Mg2+ at root tip Where you can go Where you have been More Info. Plant uptake as Mg2+ at root tip Plant residue and Microbial population Chelates in solution Soil Solution Erosion Where you can go Where you have been More Info. Plant residue and Microbial population Soil Solution Erosion Where you can go Where you have been More Info. Chelates in solution Leaching MgSO4 Soil Solution Where you can go Where you have been More Info. Plant uptake as Mg2+ at root tip Plant residue and Microbial population Chelates in solution Leaching MgSO4 Soil Solution Secondary clay and humus Oxides Silicates Sulfides Etc Where you can go Where you have been More Info. Parent material non-exchangeable 2% of all rock Dolomite Magnesite Serpentine Biotite Olivine Fosterite Pyrope Iolite Diopside Augite Enstatite Actinolite Hornblende Talc Phlogopite Clinochlore Soil Solution Secondary clay and humus Where you can go Where you have been Weathering Oxides Silicates Sulfides Etc More Info. Dolomite, MgSO4, MgO, Mangesite,Magnesia, Kainite, Langbeinite, Epsom salts Parent material non-exchangeable 2% of all rock Dolomite Magnesite Serpentine Biotite Olivine Fosterite Pyrope Iolite Diopside Augite Enstatite Actinolite Hornblende Talc Phlogopite Clinochlore Mg fertilizer Soil Solution PPT Secondary clay and humus Where you can go Where you have been Weathering Oxides Silicates Sulfides Etc More Info. Plant uptake as Mg2+ at root tip Plant residue and Microbial population Dolomite, MgSO4, MgO, Mangesite,Magnesia, Kainite, Langbeinite, Epsom salts Chelates in solution Leaching MgSO4 Mg fertilizer Soil Solution PPT Erosion Secondary clay and humus Where you can go Where you have been Parent material non-exchangeable 2% of all rock Dolomite Magnesite Serpentine Biotite Olivine Fosterite Pyrope Iolite Diopside Augite Enstatite Actinolite Hornblende Talc Phlogopite Clinochlore Weathering Oxides Silicates Sulfides Etc CEC More Info. Soil Solution Where you can go Where you have been CEC More Info. Deficiencies: pH 5.0 is best for Mg availability. A higher or lower pH depresses Mg uptake. High K and Ca levels also interfere with uptake. Where deficiencies occur: Highly leached humus acid soils or on sandy soils which have been limed heavily (due to Ca2+ competition). Deep sandy soils. Soils with high forage production (8 -10ton/ac/yr) removal. Sometimes on soils high in K, Mg deficiencies are indicated by soil test index values less than 100lbs/acre. Toxicity Symptoms: none Toxicities: Grass Tetany when K/(Ca+Mg)> 2.2 Back to cycle More Info. Form taken up by plant: Mg2+ Mobility in Soil: yes/no Mobility in Plant: yes as Mg2+ or Mg Citrate Deficiency Symptoms: Interveinal chlorosis, necrosis, and General withered appearance. Leaves are stiff and brittle and intercostal veins are twisted. Observed in lower leaves first. Between veins striping, mottling, and blotching. Back to cycle More Info. Role of Mg in Plant Growth: Responsible for electron transfer in photosynthesis. Central element of chlorophyll molecule (6-25% of total plant Mg). Required for starch degradation in the chloroplast. Involved in regulating cellular pH. Required for protein synthesis. Required to form RNA in the nucleus, Mg pectate in the middle lamella. Role of Nutrient in Microbial Growth: Important for phosphorus metabolism. Helps to regulate colloidal condition of the cytoplasm. Concentration in plants: 0.15% - 0.35% (1500-3500 ppm) Back to cycle More Info. Effect of pH on Availability: Highest Mg availability at pH 5.0. Precipitated forms at low pH: MgCl2 , MgSO4 , Mg(NO3)2 Precipitated forms at high pH: MgO, MgCO3, Mg(OH)2, MgCa(CO3)2 Interactions with other nutrients: Uptake of K+, NH4+, Ca 2+, Mn2+ by plant limits Mg2+ uptake. H+ (low pH) can limit Mg2+ uptake. Mg salts increase phosphorus adsorption. Back to cycle More Info. Fertilizer Sources: Dolomite (MgCa(CO3)2) (most common); Magnesium sulfate (MgSO4 x H2O) (Kieserite); Magnesium oxide (Mg(OH)2) (Brucite); Magnesite (MgCO3); Magnesia (MgO); Kainite (MgSO4 x KCl x 3H2O); Langbeinite (2MgSO4K2SO4); Epsom Salts (MgSO4 x 7H2O) Location in Plants: In corn, 34% of total Mg is in grain. Radioactive Isotopes: 23 Mg t 1/2 = 11.6 sec 27 Mg t 1/2 = 9.6 min 28 Mg t 1/2 = 21.3 hr Back to cycle More Info. Enzymes that require Mg2+: Magnesium is a co-factor for many enzymes. This includes enzymes involved in glycolysis, carbohydrate transformations related to glycolysis, Krebs cycle, the monophosphate shunt, lipid metabolism, nitrogen metabolism, “phosphate pool” reactions, photosynthesis, and other miscellaneous reactions. Examples: ATPase (phosphorylation), phosphokinases;RuBP carboxylase (photosynthesis); Fructose 1,6 phosphatase (starch synthesis in chloroplasts); Glutamate synthase (ammonia assimilation in the chloroplasts); Glutathione synthase; PEP carboxylase Back to cycle More Info. Ionic Radius: 0.78 Angstroms Hydration Energy: 1908 J mol-1 Toxicity Symptoms: none Toxicities: Grass Tetany when K/(Ca+Mg)> 2.2 Back to cycle More Info. References: Ball, Jeffrey. 1994. Magnesium Cycle. As presented to SOIL 5813. Brady, Nyle C. and Ray R. Weil. 1996. The Nature and Properties of Soils. 11th Edition. Prentice Hall, Upper Saddle River, N.J. Jacob, A. 1958. Magnesium - the fifth major plant nutrient. Staples Press Limited, London. Johnson, G.V., W.R. Raun, and E.R. Allen. 1995. Oklahoma Soil Fertility Handbook. 3rd ed. Okla. Plant Food Educational Society and Okla. State Univ. Dept. of Agronomy, Stillwater, OK. Johnson, G.V., W.R. Raun, Hailin Zhang, and Jeffrey A. Hattey. 1997. Oklahoma Soil Fertility Handbook. 4th Edition. Oklahoma State University Department of Agronomy, Oklahoma Agricultural Experiment Station, Oklahoma Cooperative Extension Service, And Oklahoma State University Division of Agricultural Sciences and Natural Resources, Stillwater, OK. Lauchli, A. and R.L. Bieleski (editors). 1983. Inorganic Plant Nutrition. SpringerVerlag, Berlin. Marschner, H. 1986. Mineral Nutrition of Higher Plants. 2nd ed. Academic Press, London. Mengel, K. and E.A. Kirkby. 1978. Principles of Plant Nutrition. International Potash Institute, Bern. West Virginia Univ. 1959. Magnesium and agriculture symposium. Morgantown, WV. Authors: Jeffrey Ball, Mark Everett and Rick Kochenower, and Heather Qualls Back to cycle More Info. More Information Form taken up by plant Effect of pH on availability Mobility in soil Precipitated forms at pH Mobility in plant Interactions with other nutrients Deficiency symptoms Fertilizer sources Deficiencies Location in plants Where deficiencies occur Radioactive isotopes Toxicity symptoms/Toxicities Enzymes that require Mg2+ Concentration in plants Ionic radius/Hydration energy Role of nutrient in microbial and plant growth Back to cycle References Deficiencies: pH 5.0 is best for Mg availability. A higher or lower pH depresses Mg uptake. High K and Ca levels also interfere with uptake. Where deficiencies occur: Highly leached humus acid soils or on sandy soils which have been limes heavily (due to Ca2+ competition). Deep sandy soils. Soils with high forage production (8 –10ton/ac/yr) removal. Sometimes on soils high in K, Mg deficiencies are indicated by soil test index values less than 100lbs/ac. Back to cycle More Info.