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Design of Water Quality Monitoring Dragline in operation along FL 62 nr Ft Green Springs Horse Creek Stewardship Program Water Quality Monitoring Parameters and Trigger Levels Parameter pH Dissolved Oxygen Turbidity Color Total Nitrogen Total Ammonia Orthophosphate Chlorophyll-A Specific Conductance Total Alkalinity Dissolved Calcium Dissolved Iron Chloride Fluoride Radium 226 + 228 Sulfate Total Dissolved Solids Petroleum Range Organics Fatty Amido-amines Total Fatty Acids Reporting Units Trigger Level Std Units mg/l NTU PCU mg/l mg/l mg/l mg/m^3 uS/cm mg/l Ca CO3 mg/l mg/l mg/l mg/l pCi/L mg/l mg/l mg/l mg/l mg/l < 6.0 or > 8.5 < 5.0 > 29 < 25 > 3.0 > 0.3 > 2.5 > 15 > 1,275 > 100 > 100 > 0.3, > 1.0 > 250 > 1.5, > 4.0 > 5.0 > 250 > 500 > 5.0 > 0.2 > 0.5 Dunson's suggested changes Total P > 0.75 Total Kjehdahl Nitrogen and Nitrate/Nitrite are performed as part of the Total Nitrogen analysis. >250 >20 Sodium >11 >0.5 >20 >250 How do you find trends in water quality, without historic data? Assessment of Effects of Differing Watershed Land Uses on Water Quality based on Comparisons of Six Stream/River Systems: 1. St. Mary’s River- Control 2. Myakka River-Large Agricultural Impact 3. Horse Creek – Limited Impacts of Agriculture & Mining 4. Payne Creek- Large Phosphate Mining Impact 5. Peace River at Arcadia- Combined Agricultural & Mining Impacts 6. S. Prong Alafia River- 60-70% Mined Basin St Mary’s River- control No Trends in Water Quality over Time Myakka RiverAgricultural Pollution: Increasing sp. cond. & [K] Specific Conductance- Myakka River Potassium- Myakka River 95th 75th 50th 25th 5th Six Site Comparison of Mean Data for Seven Water Quality Parameters- Mined Watersheds Elevated in: 1. Specific Conductance 6. [F] 2. [Na] 7. [TP] 3. [Ca] 4. [Mg] 5. [SO4] Specific Conductance Sodium Calcium Magnesium Sulfate Fluoride Total Phosphorus Will such changes in water quality affect the fauna? Bishop Harbor Algal Bloom in Response to Piney Pt. Effluent Effluent Treatment & Discharge Water Quality in Reclaimed Wetland Streams 1. Hall’s Branch 2. Jamerson Jr. 3. Lizard Branch 4. Dogleg 5. Pickle 6. Tadpole The Normal Progression by Levels of Approximation in Field Toxicity Testing: 1. TIER 1- Is there toxicity by standard lab. bioassays? 2. TIER 2- Is there toxicity for native species in situ? Are species “missing” that should be present? 3. TIER 3- What is the toxicity due to? 4. TIER 4- What is the source of the toxin(s)? Chronic Toxicity in Reclaimed Wetlands (Charlotte Cty. Data: 10/25/03; 3/2/04) Sp. Cond. Crustacean FETAX Repr. Malfor. Growth Site pH Jam. 6.9 106,148 + + Lizard 7.6 290,296 + + Pickle 6.8 395,486 Halls 6.8 340,483 + Dog 7.5 309,328 + Tadpole 7.2 220,403 + + + WATER CHEMISTRY OF RECLAIMED STREAMS USED FOR BIOASSAYS BY CHARLOTTE COUNTY, Oct. 2003; March 2004 Parameter Dog Hall’s Jamerson Lizard pH 7.8 6.7 6.5 8.1 6.7 6.9 7.1 6.9 7.1 7.1 6.9 7.5 Sp Cond, uS/cm 328 483 148 290 486 403 309 340 106 296 395 220 6.8 1.5 7.0 12.6 0.8 2.8 8.6 2.1 8.0 7.1 1.2 2.1 325 117,000 583 547 4230 11,300 212 4025 195 352 786 1100 41 1880 136 71 127 166 22 392 21 30 72 20 Aluminum, ug/l 160 226 391 445 107 669 132 35 101 45 <5 95 Oxygen, mg/l Iron, ug/l Manganese,ug/l Pickle Tadpol e Acute (A) and Chronic (C) Toxicity in Horse Creek Tributaries (IMC- Marinco data;1/21/04) Site pH Sp. Cond. Ceriodaph. Shiner Fathead 8W 4.4 74 1W 5.1 122 C C 2E 5.6 88 C C 6W 5.9 97 C C Piez. 7.8 266 A,C A C HCSP Needs Changes • Water quality - re-set trigger levels; add sampling sites above and below points of discharge and increase number of samples • Bio-monitoring - use full 3 tier system of bioassays on field observations, lab tests and in-situ enclosures HCSP Needs Changes • The Bottom Line - Design rigorous plan for bio-monitoring prior to agreement - Convene outside panel free from conflicts of interest to design plan and oversee implementation A Physical Analogy for the Cumulative Adverse Ecological Impacts of Mining