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Atomic Theory • Atom – smallest part of an element with that element’s properties • 2 parts – Nucleus • Protons (positive charge, weigh 1 amu*) • Neutrons (neutral charge, weigh 1 amu*) – Orbitals (inside electron cloud) • Electrons (negative charge, negligible mass) • (* amu = atomic mass unit) A note about electrons • They don’t all have the same amount of energy. • The farther away from the nucleus they are, the more energy they have. • We don’t know exactly where they are, we just have an idea. They move fast, like the blades of a fan. We know they’re there somewhere. • Outermost ones are called valence electrons. They are responsible for how elements react with each other and the physical and chemical properties. Electrons • Electron cloud is split into energy levels that hold different amounts of electrons. – 1st one holds 2 (maximum) – 2nd one holds 8 – 3rd one holds 18 – 4th one holds 32 • Electrons fill the lowest one first • The energy levels are split into orbitals, called s, p, d and f. So it gets complicated •Really the 8 electrons in the second energy level are 2 in the s orbital and 6 in the p orbital •And the 18 in the third energy level are 2 in s, 6 in p and 10 in d orbital… s, p, d, f orbitals • You can see this pattern on the table! Do we have to know this? • But you’ll hear more about that in chemistry. For now realize that each energy level is made up of sublevels that hold specific amounts of electrons. • The sublevels are called orbitals and are named s, p, d, f • You can see these patterns in the periodic table. The Periodic Table • Was organized according to the chemical & physical properties of the known elements • Protons, neutrons and electrons had not yet been discovered • Dmitri Mendeleev noticed that when the elements were put into order by their atomic mass, some of their properties repeated periodically (at regular intervals) • This is because the pattern of valence electrons repeats as orbitals are filled What it tells you • Atomic number = the number of protons • Atomic mass = average mass for all the forms of that element • Name of the element • Symbol (first letter always capital) Ions • Atoms aren’t always neutral (no charge) • Lose electrons – More protons, positive ion • Gain electrons – More electrons, negative ion • Has 1 charge for each electron lost or gained • Written above the symbol, e.g. Na+, O2- Isotopes • Some forms of the atom naturally have more or less neutrons • Because it has the same number of protons it’s still the same atom, but called an isotope. • That’s why atomic mass is not a whole number, it averages all the isotopes • Write the mass number and atomic number to left of symbol 14 • 6 C is carbon-14, used to carbon date Patterns on the table • Rows are called periods • As you go across a period: – Atomic number (#p+) increases by 1 – So does #e- for neutral atoms – So does # valence electrons • Columns are called families or groups – Similar properties (density, melt pt, etc.) – React chemically the same way – Because have same valence electrons How you use it • #p+ = to Atomic Number (by definition) • #e- = # protons (in a neutral atom) • #n0 = atomic mass, rounded off – atomic number Bohr Model • Shows protons and neutrons in nucleus • Shows electrons in the cloud in layers called energy levels Lewis Diagram • Also called dot diagrams • Only shows valence electrons (outer most) • Valence are only ones involved in chemical reactions