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Krystal Klear R Chelated Micronutrient Solutions The Performance Edge: Patented Dual Chelation What is a chelate? The word chelate (pronounced: “key-late”) is derived from the Greek word “chele” which literally means “claw”. Hence, chelate refers to the pincer-like manner in which a metal nutrient ion is encircled by the larger organic molecule (the claw), usually called a ligand or chelator. Chelated micronutrients are protected from oxidation, precipitation, and immobilization in certain conditions because the organic molecule (the ligand) can combine and form a ring encircling the micronutrient. The pincer-like manner in which the micronutrient is bonded to the ligand changes the micronutrient’s surface property and favors the uptake efficiency of foliarly applied micronutrients. Why are Krystal Klear® micronutrient solutions so effective? Dual Chelation: Utilizes patented, biodegradable IDS in conjunction with EDTA to maximize the benefits of both chelating agents. Stability Constant, which refers to the equilibrium state of a metal cation and a ligand to form a chelating complex: A good stability constant is one in which the bond is strong enough to hold the metal in solution but not so strong that it doesn’t release the metal when applied. Number of ligands: This refers to the ligands or “legs” that bond the metal to the chelating agents. For example, EDTA has 6 and Baypure® has 5 ligands while citric acid has 3 carboxylic ligands and glucoheptonate has 1. The higher the number of legs means more cation surface area is covered. That is why both EDTA and Baypure chelated metals are stable in orthophosphate solutions for an extended period while others fall apart and precipitate over time. Chelation occurs when certain large molecules form multiple bonds with a micronutrient, protecting it from reacting with other elements in the nutrient solution and increasing its availability to the plant. Chelated metal being protected from attraction to other materials. 20-20-20 A good chelating agent protects the metal from all sides. 20-20-20 with Krystal Klear Fe 20-20-20 with Fe citrate Performance Nutrition® Field Performance - Krystal Klear Zinc Products Tomato Plant Uptake of Foliar Applied Zinc Pepper Plant Uptake of Soil Applied Zinc Zn EDTA versus Krystal Klear® Zn Zn EDTA versus Krystal Klear® Zn 990 920 830 100 800 600 600 400 65 80 60 25 40 200 0 105 120 Zn ppm Uptake per plant (ppm X Dry Wt) 1000 32 20 0 No Fertilizer 15-30-15 no micros 15-30-15 plus KK Zn 15-30-15 plus Zn EDTA No Fertilizer Only Krystal Klear with Baypure (IDS) says Yes! to all your chelated micronutrients needs! 15-30-15 plus KK Zn 15-30-15 plus Zn EDTA Krystal Klear patented chelated micronutrient solutions for Agriculture Krystal Klear Agra Mix 2% Cu, 2% Mn, 2% Zn and 0.5% B Baypure vs. Other Chelating Agents Baypure EDTA DTPA • HeEDTA EDDHA Citric Acid Glucoheptonate Stable at pH =/< 6 Yes Yes Yes Yes Yes Effective at pH > 6 Yes No Yes No No Can be soil applied Yes Yes Yes Yes Yes Can be foliar applied Yes Yes No Yes Yes Biodegradable Yes No No Yes Yes Ortho-Phosphate Compatible Yes Yes Yes No No Economical Yes Yes No Yes Yes Options 15-30-15 no micros Krystal Klear Agra Mix II 2% B, 2% Mn, 2% Zn and 0.5% Cu Krystal Klear Agra Mix III 2% B, 0.5% Cu, 0.25% Fe, 2% Mn and 2% Zn Krystal Klear Crop Mix 4% Zn, 1% Mn, 0.5% Cu and 0.1% B Krystal Klear Crop Mix II 0.1% B, 0.5% Cu, 0.25% Fe, 1% Mn and 4% Zn Krystal Klear B 5% B Krystal Klear Cu 5% Cu Krystal Klear Fe 4% Fe Krystal Klear Mn 5% Mn Krystal Klear Zn 9% Zn Performance Nutrition® A division of LidoChem, Inc. 20 Village Court, Hazlet NJ 07730 Phone: (732) 888-8000 Email: [email protected] www.pnfertilizers.com Performance Nutrition and Krystal Klear are registered trademarks of LidoChem, Inc. Baypure is a registed trademark of Lanxess © 20145 LidoChem, Inc.