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Name (LAST, First) ________________, ____________ Date ___ / ___ / ______ Block 1 2 3 4 5 6 7 8 Experiment #4: The Density of Metal Shot Introduction Archimedes, a Greek physicist and mathematician who lived in the third century B.C., was said to have discovered the principle of water displacement while bathing, and subsequently ran through the streets naked, shouting "Eureka!" which is Greek for "I have found it!" This method may be used by clothed scientists as well to determine the volume of irregularly-shaped objects that will completely submerge in water. Obtain and weigh a small weighing dish. Place approximately 1.5 x 102 g of dry metal shot into the dish and weigh. Record the masses to the nearest 0.01 g. With this technique, the density of metal shot will be simple to determine, but can the density of an unknown metal provide enough information to identify it and distinguish it from other metals? Tilt the graduated cylinder to a 45° angle and slowly pour the shot into the cylinder. Set the cylinder upright and record the volume. Obtain, from the supply shelf, a 100 mL graduated cylinder. Fill approximately half-full with tap water. Record this volume to correct number of significant digits (estimate the last digit, ±0.1mL). When reading volume, read the level at the bottom of the meniscus. Pour the shot into the recovery bucket and rinse the cylinder 1. 2. 3. 4. Prelab Assignment Read about Density: a. Use the index in your text to find appropriate pages. b. See web resources below for Water Displacement and Reading Volume. 152.3 g of shot is placed into a graduated cylinder. The volume of water in the cylinder is initially 55.4 mL, which rises to 68.6 mL with the addition of the shot. The sample consisted of 123 spherical shot. a. Calculate the density of the shot. b. Determine the average mass, volume, and diameter for an individual shot. In your Work Record, create a blank table for data. The column headings should be “Description” and “Value”. Create a separate, blank table for calculations. kg with tap water. Calculate density place your value in the class data table. 1. 2. 3. Experimental Question Can density be used to identify a particular type of metal? Experiment Overview You will collect mass and volume data for a sample of metal shot and then calculate the density of this unknown metal. You will then attempt to determine the identity of the metal. Procedure 4. 5. Calculations Calculate the specific gravity for your sample. Data Analysis For the class density data calculate the mean, standard deviation, 95% range, and percent sigma. Results Using a table of metal densities as a reference, find all metals that have a density within the 95% range. These are the metals, with 95% surety, that your sample could be. This also means that there is a 5% chance that the actual density is outside of the 95% range. Record the identity and correct density for each metal within this range. Determine the percent error between your experimental value and the correct density for each possibility. Repeat, using average class density in place of your experimental density. Comment on accuracy and precision. Support each answer with appropriate numerical evidence. Web resources: (Extra credit if you find a web resource that I will plan on using next year.) Water Displacement Method: http://ch185.semo.edu/comp2obj/comp2obj.html Meniscus and Reading Volume: http://www.uwplatt.edu/chemep/chem/chemscape/labdocs/catofp/measurea/scales/scales.htm Density Information: You are going to have to search. http://www.chemicalelements.com/index.html http://micronmetals.com/ http://www.atlanticmetals.com http://en.wikipedia.org/wiki/Periodic_table http://www.mcelwee.net/#%5B%5BDensities%20of%20Various%20Materials%5D%5D 769794165 4/30/2017 2:27:00 AM for the shot and m3 Page 1 of 2 Name (LAST, First) ________________, ____________ Date ___ / ___ / ______ Block 1 2 3 4 5 6 7 8 TI-83 Skills Entering the data, 1 dimension, Statistics: Buttons to press: STAT / EDIT Notes: Enter your data in the appropriate lists. For this I will assume that L1 contains the data to be analyzed. To clear a list, do NOT use the DEL button. Position the cursor on the L1 symbol, press CLEAR, then press ENTER. The list should be emptied but remain. Statistics, One Variable Buttons to press: STAT / CALC / 1: 1-Var Stats / L1 / ENTER The command you should see on the screen: 1-Var Stats L1 The results should look like this (I have included a definition and description): Symbol Pronounced x x-bar x x Sx σx n minX Q1 Med Q3 maxX sigma x 2 Definition arithmetic mean Description center of the data summation of all x values sigma x squared summation of all x2 values sigma x minimum x que one median que three maximum x standard deviation of a sample standard deviation of a population number of x values minimum x value 1st quartile score middle score 3rd quartile score maximum x value spread middle value Laboratory Statistical Calculations Simple Statistics: x is the arithmetic mean, a measure of central tendency. σ is standard deviation, a measure of data spread. 95% Range: Acceptable range within Spread of Data: 95% Range Upper bound of acceptable values: x + 2 σ Lower bound of acceptable values: x – 2 σ The range within which 95% of the data values lie. The 95% that falls within the range is usually assumed to be good data. The 5% that falls outside of the range is usually assumed to be in error. The correct, or accepted, value has a 95% chance of falling within this range. There is a 5% chance that the correct value is outside of this range. Accuracy: Relative Error and Percent Error Measured = experimentally measured value, either an individual value or the mean of the measured values. Accepted = value accepted as correct Relative Error = Measured – Accepted Percent Error = %e = Relative Error / Accepted * 100 In first-year physics a percent error value between – 5% and +5% inclusive is usually considered to be acceptable. This indicates data points that are close to the accepted value. A value greater than 5% usually indicates sloppy lab technique and/or failure to follow instructions. |%e| ≤ 5% implies accurate measurement(s). Precision: Percent Sigma Percent Sigma = %σ = x x 100 In first-year physics a percent sigma value less than or equal to 5% is usually considered to be acceptable. This indicates data points that are grouped close to each other. |%σ| ≤ 5% implies precise measurements. 769794165 4/30/2017 2:27:00 AM Page 2 of 2