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Learning Targets: 1. Compare wave and particle nature of light. 2. Define a quantum of energy, and explain how it is related to an energy change of matter. Main Idea • Light, a form of electromagnetic radiation, has characteristics of both wave and a particle. • Rutherford’s model: the atom’s mass is concentrated in the nucleus and electrons move around it. • Drawbacks: – Does not explain how the electrons were arranged around the nucleus. – Does not explain why negatively charged electrons aren’t pulled into the positively charged nucleus. • In the early 1900’s, scientists observed certain elements emitted visible light when heated in a flame. • Analysis of the emitted light revealed that an element’s chemical behavior is related to the arrangement of the electrons in its atoms. The wave nature of light • Visible light is a type of electromagnetic radiation, a form of energy that exhibits wave-like behavior as it travels through space. • All waves can be described by several characteristics: • The wavelength (λ) is the shortest distance between equivalent points on a continuous wave. • The frequency (v) is the number of waves that pass a given point per second. – Unit: Hz or sec-1 • The amplitude is the wave’s height from the origin to a crest. • The speed of light (3.00 x 108 m/s) is the product of it’s wavelength and frequency, c = λv • Sunlight contains a continuous range of wavelengths and frequencies. • A prism separates sunlight into a continuous spectrum of colors. • The electromagnetic spectrum includes all forms of electromagnetic radiation. Shortcomings of the wave model • Fails to explain why some objects emit only certain frequencies of light at a given temperature. • In other words, why some metals emit electrons when light of a specific frequency shines on them – emissions of different wavelengths. The Particle Nature of Light • Planck’s Conclusion: matter can gain or lose energy in small, specific amounts called quanta. – Quantum: the minimum amount of energy that can be gained or lost by an atom • Energy emitted by hot objects was quantized Photoelectric effect • The photoelectric effect is when electrons are emitted from a metal’s surface when light of a certain frequency shines on it. – For a given frequency, v, matter can emit or absorb energy only in whole number multiples. • Albert Einstein proposed in 1905 that light has a dual nature. • Light’s dual nature: a beam of light has a wavelike and particlelike properties. – Think of it as bundle of energy called photons. – Photon: massless particle that carries a quantum of energy Practice… • Identify the type of radiations for the following: 1. 6.32 x 1020 s-1 2. 9.50 x 1013 Hz 3. 7.230 x 1014 s-1 4. 8.72 x 10-2 m Ans: 1. gamma radiation 2. infrared radiation 3. Violet 4. microwave Atomic emission spectra • Light in a neon sign is produced when electricity is passed through a tube filled with neon gas and excites the neon atoms. • The excited atoms emit light to release energy. • The atomic emission spectrum of an element is the set of frequencies of the electromagnetic waves emitted by the atoms of the element. • Each element’s atomic spectrum is unique.