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 CFR 1910.1200 OSHA Hazard Communication
Standard
 This program was established so that employee’s
will be informed of the contents of the Hazard
Communication
Standard, the
hazardous
properties of the chemicals with which they
work, safe handling procedures and the measure
to take to protect themselves from hazardous
chemicals.
 This standard was revised. The changes have
been made to labeling requirements, MSDSs are
now referred to as SDSs with added sections, and
training requirements have been revised to align
with the UN Globally Harmonized System of
Classification and Labeling of Chemicals.
Use the following checklist to help you
comply with OSHA HCS 2012:
•Audit your chemicals: conduct a physical
audit of all chemicals in the workplace
•Confirm the use of workplace labels: as you
conduct your inventory, ensure all containers
are properly labeled
•Obtain updated supplier SDSs: contact the
manufacturer for a current SDS for each
chemical in the workplace
•Distribute your supplier SDSs: ensure your
chemical users have FREE, unlimited access to
the updated SDSs
•Train your employees: update your existing
hazardous chemical training program to
include the GHS data elements and format of
the SDS
 A representative from each clinic/lab will
maintain up a list of all products that contain
hazardous chemicals used in their clinic or
laboratory
 This will be referred to as the hazardous
chemicals inventory list (HCI)
 This list will be kept in front of the SDS book
for reference
 This list will be updated as new chemicals
are introduced into or removed from the
clinic
 SDSs are detailed information bulletins prepared
by the manufacturer or supplier of any product
that contains a chemical deemed to be hazardous
 The SDS has 16 sections:
Identification, Hazard(s) Identification,
Composition/Information on Ingredients, First-Aid
Measures, Fire-fighting Measures, Accidental
Release Measures, Handling and Storage,
Exposure Controls/PPE, Physical and Chemical
Properties, Stability and Reactivity, Toxicological
Info, Ecological Info, Disposal Considerations,
Transport Information, Regulatory Information,
and Other Information
 If an SDS is not available refer to the
online SDS Public Service Library at
http://www.chemquik.com/scripts/
main.asap
• Labels will list the chemical identity of the material,
appropriate hazard warnings and the name of the
manufacturer
• The manufacturer is responsible for labeling the
original container, however, it is the ultimate
responsibility of the PM or lab supervisor
• Professional products that are regulated by the FDA
are exempt from labeling except when transferred to
a secondary label
 Labels for hazardous chemical must contain:
 Name, address, and telephone number
 Product identifier
 Signal word
 Hazard statement(s)
 Precautionary statement(s)
 Pictogram(s)
OSHA HCS 2012 Labels
Under OSHA HCS 2012, chemical manufacturers
and importers must label their chemical
containers with the applicable GHS elements. In
turn, employers must convey these GHS elements
on the workplace label for each hazardous
chemical. These GHS elements include:
•Signal Word: “Danger” or “Warning” indicates
the severity of the hazard.
•GHS Pictograms: convey the health, physical and
environmental hazard information assigned to a
specified GHS hazard class and category.
•Health and Physical Hazard Statements:
describe the nature and degree of the stated
hazard.
•Precautionary Statements: describe measures
to minimize or prevent effects from exposure or
improper storage of the hazardous chemical.
 https://www.youtube.com/watch?v=RvQNf1Y7E84&noredirect
=1
 Chemicals transferred to a secondary
container need to be labeled
 Examples of secondary containers include:
alcohol, bleach, disinfectant, radiographic
chemicals
 Every container that you place a chemical in
needs to be labeled…including, ultrasonic
cleaners and radiographic processors
 Hazard Communication training must be updated to include the
new label and SDS formats and how to implement these
changes
 Hazardous waste storage containers must be in good condition,
free of leaks and compatible with the material stored in them
 The container should remain capped when not in use
 If the container should begin to leak, place in a larger non-
leaking container, transfer to another container and call the
safety office at 433-7556 is needed
 All containers must be marked with the words “waste” or
“spent”
 Kept near the site of generation and under control of the
generator
 Compatible with contents (no acids in metal cans)
 Kept closed at all times except when in use
 Properly identified with waste tags before pickup
 Transported with a non-leaking screw on cap
 Filled to a safe level (not beyond the bottom of the neck of the
container or a 2 inch head space for 55 gallon drums)
 Do NOT use red bags or sharps containers for storage
 A generator of potentially hazardous waste may accumulate up
to a total of 55 gallons of waste which may be determined to be
hazardous or one quart of acutely hazardous waste
 In the event more than this volume will be generated, contact
Safety for a special pick-up
 Hazardous waste in excess pf 55 gallons may not be stored at
your site for more than 3 days
 Refer to the Department of Safety Procedures for Disposal of
Hazardous Waste Manual for details on which chemicals are
compatible and incompatible
 Prior to pick-up a waste tag is required (refer to the Laboratory
Safety Manual for details)
 This should be filled out by the waste generator and attached to
each container
 When ready for disposal contact the Safety department.
 A hazardous waste disposal request form will need to be filled
out (refer to the Laboratory Safety manual)
 An SDS should accompany the container
 The Safety department conducts regular safety inspections of
all labs
 Failure to comply may result in disciplinary action
 At no time will any chemical be disposed of by pouring it down
the drain regardless of what is recommended by the SDS or
manufacturer
 Dental developer and fixer chemicals shall be stored in
containers provided by the chemical transporter and disposed
of as hazardous chemicals
 Dental amalgam is a potential source of
mercury vapor
 Dental amalgam waste & teeth containing
amalgam will be placed in the designated
containers placed in each operatory
 Each container will be labeled appropriately
 A designated vendor will pick up used
amalgam
 Lead foils will be collected in a plastic
container
 The container will be labeled appropriately
 The container will be picked up monthly by a
designated vendor.
 All unused, unneeded, or expired
prescription drugs must be removed
from their original containers and
mixed with used coffee grounds, kitty
litter, or other undesirable
substances.
 The litter or coffee grounds must be
placed in impermeable containers
such as zip-loc baggies and then in
the trash to prevent diversion.
Disposition of medications must
include the medication name,
strength, prescription number (if
applicable along with patient's
name), quantity, date of
disposition, and disposing staff or
students.
Medications should NOT
be placed into sharps
containers.
Syringes containing
medications should be
emptied into kitty litter
which will then be
enclosed in zip-lock bags,
and disposed of in the
trash unless on the
previous list.
Syringes will then be
disposed of in the correct
manner.
The Board of Pharmacy
recommends that any
expired bottles (used or
unused) of injectable
controlled substances be
sent for reverse distribution
to:
Return Logistics
International Corporation,
22 Artley Road, Savannah,
GA 31408.
 You are responsible for the safety of your clinic or lab
 If you do not know the chemicals properties ask for help
 Proper PPE is required to include lab coats, and safety glasses
when handling chemicals, biohazards, and radioisotopes
 No shorts, sandals, or open toe shoes
 No children or pets
 Never pipette by mouth
 Be aware of dangling jewelry, hair, and loose clothing
 No food in designated refrigerators
 Never work alone. If not avoidable let someone know where
you are
 Wash hands frequently and always before leaving the lab
 Do not wear PPE outside of the lab
 Contact lenses should not be worn in lab
 Work areas should be kept clean and free of unnecessary
chemicals
 Clean equipment after use to avoid cross contamination
 Do not block emergency exits or equipment
 Do not eat, drink, apply make-up or chew gum
 Emergency phone
numbers should be
posted near entrances
to each lab, storeroom
and beside every phone
in the lab or clinic
 Include Emergency
Medical Services, The
RSO, and the Office of
Safety
 Fire-Pull the nearest fire alarm. If you are unable to control or
extinguish a fire follow building evacuation plan
 Accidents-attend to person who may have been contaminated
if it is safe to reach them. Use safety showers and/or eye washes
as appropriate. Flush eyes for a minimum of 15 minutes and
seek medical attention immediately.
 Ingestion of substance- call Poison Control Center at 1-800-
POISON
 Skin Contact-wash skin with water and remove clothing or
jewelry. If symptoms persist seek medical attention.
 Spill- notify persons in the immediate area. Evacuate all non-
essential personnel
 Flammable spill- Turn off all ignition sources. Avoid breathing
vapors. Be aware some chemicals have no odor or create
olfactory fatigue(you stop smelling the odor quickly)
 Leave on or establish all exhaust ventilation and close doors to
prevent spread of the odors
 Call Emergency Services1-911in case of fire, if there is
immediate threat to life, or any other emergency situation
 Be aware of marked exits
 To activate the fire alarm, pull the handle on one of the red
boxes located in the hall
 In the event of a fire, call 1-911
 If the fire alarm sounds, exit through the nearest exit
 Proceed to designated assembly area and check in with
designated personnel
 Do not return to the building unless instructed by Security
 Refer to the Emergency manual for detailed instructions for
building evacuation and other emergencies
 Be aware of which products contain
hazardous chemicals
 Know what hazards are associated with
these products
 Know the proper hygiene for working with
dental products
 Know what to do in case of a spill
 Know the location of your spill kit
 Have the necessary supplies on hand
 In the event of a MINOR spill utilize the spill response equipment.
Specific contents of the spill kit may be found in the Laboratory
Safety Manual.
 Refer to SDS to determine cleanup method
 Use appropriate PPE
 Cover liquid spills with absorbent material (check compatibility)
 Cover powdered materials with wet paper towels
 Neutralize corrosive if appropriate materials available
 Clean from the outer area towards the center
 Place spilled material in impervious container, seal, and contact
Safety Department for disposal
 Wash/mop up area
 A solvent (xylene) may be necessary to clean surfaces
contaminated with a non-water soluble chemical
The Spill-Kit container should include:
 Chemical spill instructions
 Utility gloves and protective eyewear
 Kitty litter, vermiculite or a 50.50 mixture
of the two
 Sodium bicarbonate (Baking soda)
 Plastic non-sparking scoop
 Plastic bags
 Dust pan
 Paper towels
 Fresh 1:10 bleach solution
 Respond only if you have been trained…otherwise summon
assistance
 Attend to anyone contaminated or injured if safe to reach them
 Call Emergency Services (1-911)
 If room equipped with UV lights, turn them on
 Evacuate non-essential personnel. Leave the lab and close
doors
 Remove contaminated clothing and place in impervious
container, seal and label, avoid contact with others, take a
shower
 Put on PPE
 Wait 30 minutes for aerosol to settle before entering
 Turn off UV lights and check for visible mists before entering
 Apply appropriate disinfectant to spill with gentle flooding
action to avoid secondary aerosols
 Cover excess liquid with absorbent material and dry material
with wet paper towels
 Place spill clean-up material into a container and autoclave or
call Safety Department for disposal
 Wash affected surface with strong disinfectant
 Procurement
 Before a substance is received information on proper handling,
storage and disposal must be known. Refer to SDS
 All chemicals must be properly labeled
 Stockrooms/Storerooms
 Chemicals must be segregated and stored properly depending on
their properties
 Stored chemicals should be examine periodically (at least
annually)for leakage and to make sure labels are secure
 Distribution
 When moving chemicals place in an outside secondary container
 Use freight elevators whenever possible when transporting
chemicals
 Laboratory Chemical Storage
 Read labels carefully before storing
 Store according to the Chemical Storage Segregation Scheme
in the Laboratory Safety Manual
 Store all chemicals by their hazard class not in alphabetical
order
 Do not store near heat sources or in direct sunlight
 Date chemicals when received and first opened
 Do not use lab benches as permanent storage for chemicals
 Inspect chemicals routinely
 Do not store chemicals in glass containers on the floor
 Do not use fume hoods as permanent storage areas
 Contact Safety Department for disposal of old, outdated or
unused chemicals
 Do not store chemicals above eye level
 Do not store excessive amounts of chemicals in the lab
 Store in proper storage cabinets(Refer to safety manual for
specific requirements for storing in these cabinets)
• Flammable storage cabinets
• Acid storage cabinets
• Compressed gas cylinder cabinets
 Laboratory inventory posters including emergency contacts must
be posted outside of each work area
 Labels must be placed on all chemical containers
 Secondary containers must be labeled
 Waste disposal tags must be used to identify waste
 Employee notification posters must be current and posted-The
Right To Know (can be obtained from Safety Department)
 Florida Hazard Communication Act rights for employees
 Lab supervisor must keep this poster up to date
 Safety signs for safety equipment, first aid equipment & exits
 Warning signs where special or unusual hazards exist
 Food and beverage consumption and storage permit signs
 Follow laboratory procedures for assembly of lab apparatus (refer
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to Lab Safety Manual)
Follow laboratory procedures for use of lasers(refer to Lab Safety
Manual)
Follow laboratory procedures for safe use of cooling baths and
cold traps(refer to Lab Safety Manual)
Follow laboratory procedures for safe use of vacuum pumps (refer
to Lab Safety Manual)
Examine electrical cords periodically
Make sure all electrical equipment is grounded
Do no run cords along the floor where they create a tripping
hazard or above the ceiling
Do not plug too many cords into one outlet
 Equipment and other materials should be placed at least 6
inches behind the sash
 When hood not in use pull the sash all the way down
 Do not keep loose paper or towels in the hood
 Do not use as a storage cabinet
 When using large equipment keep it raised 1.5 inches off the
work surface to allow ventilation
 Do not block fume hood
do not modify the fume hood
 Minimize the foot traffic in front of a hood
 Reference the Laboratory Safety Manual for specific details for
working with:
 Embryotoxins
 Chemicals with chronic or high acute toxicity
 Substances of high chronic toxicity
 Flammable solvents
 Oxidizers
 Corrosives
 Reactives
 Refer to laboratory Safety Manual for specific details for
working in the different biosafety level areas.
• OSHA requires that all gas cylinders
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be secured to prevent tipping
Always use appropriate regulator on
cylinder
Be legibly labeled and marked to
clearly identify the department and
gas
Be stored to protect against external
heat sources
Do not use oil or grease on any
cylinder
Be stored as not to be damaged by
passing or falling items
Valve protectors must also be in place
when cylinder not in use
Valves must be closed if cylinder is
being moved
 Never use cylinder if it cannot be positively identified
 Place all cylinders so the main valve is accessible
 Remove regulators from all unused cylinders and place
protective safety cap
 Store oxygen at least 20 feet from a flammable material
 Never roll a cylinder
 Never drop or strike a cylinder
 use designated wrenches or tools to open valve
 Store compatible gases together
 Lab supervisor or program manager or designee will be
responsible to assure that Incident Reports are filed with
Security
 Medical records associated with an exposure will be
maintained by the facility in accordance with State and Federal
regulations
 If a medical consultation is performed HR will obtain a written
opinion from the examining physician to include:
 Follow-up recommendations
 Results of the exam
 Statement that the lab personnel has been informed of the
results and any follow-up treatment needed
 SDSs will be available in each lab for all hazardous chemicals
 Every lab worker must be trained to know the location and proper use of
PPE (refer to the Laboratory Safety manual-”Basic Rules and Procedures
for Working with Chemicals”)
 Training must be provided at the time of initial employment and then
annually or as needed when a new chemical is introduced
 Training must include at minimum:
 Location of the Laboratory Safety Manual
 Locations of SDSs
 The permissible exposure limits (PEL) for OSHA regulated substances or
the exposure limits for other chemicals where there is no OSHA standard
(refer to appendix for PEL’s in Laboratory Safety manual)
 Signs and symptoms of exposures
 Methods to detect the presence or release of a hazardous chemical
 The physical and health hazards of the chemicals in their work area
 The measures lab personnel can take to protect themselves from the
hazards
 The applicable details of the Laboratory Safety manual
 Hazard Communication training is required when the employee
is hired and then annually or as needed to include:
 Chemical labeling (new CHS requirements)
 SDSs
 Spill clean-up and chemical disposal
 Chemical storage guidelines
 Hazards specific to different chemical groups
 Implementing new formats
 Lab safety training must take place at the time of hire and then annually or
as needed and must include:
 Safety equipment and practices
 Emergency procedures
 Emergency equipment
 Waste disposal
 Fire Extinguisher training is required for all lab personnel
 What to do in the event of a fire
 The behavior of fires
 The classes of fires and proper selection and use of a fire extinguisher
 Waste Management Training and Bloodborne Pathogen Training must take
place at the time of hire and then annually or as needed. (the requirements
covered previously in BBP section)