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Chemicals of the Natural Environment. Lesson 9 Learning objective: To calculate how much metal can be extracted from its mineral. • Must: Be able to calculate the relative formula mass for any compound. • Should: Be able to calculate the mass of a metal that can be extracted form its mineral. • Should: Be able to write balanced symbol equations. • Keywords: Atomic mass, relative formula mass, percentage composition, reactants and products. • Starter: What do these numbers mean CONNECT What is the total number of atoms in the following formulae? NaOH H2O CaCO3 H2SO4 Ca(OH)2 A small number just talks about the element it is behind. E.g. O2 = 2 x O Small numbers outside the bracket mean multiply everything inside the bracket by that number E.g. (CO3)3 = 3 x C, 9 x O Relative atomic mass Relative atomic masses 1. Atoms of different elements have different masses 2. The relative atomic mass (Ar) is the mass of the elements compared to the mass of a hydrogen atom Relative Formula Mass 1. The relative formula mass (Mr) is the relative mass of a molecule compared to the mass of a hydrogen atom Calculating relative formula mass. • Top Tips. • 1. The relative atomic mass is usually at the top – it is always the highest number. • 2. When calculating the relative formula mass, • a) Write out all the different atoms (Capital letter). • b) Write down the number of each atom. • c) Multiply the number of each type of atom by its atomic mass. • d) Add all the masses together. An example. • • • • • • • Calculate the RFM – for calcium carbonate. Formula CaCO3 Type, number and atomic mass of each atom; Ca x 1 x 40 = 40 C x 1 x 12 = 12 O x 3 x 16 = 48 Total = 100 – Relative formula mass of CaCO3. Relative formula mass Relative formula mass, Mr 12/05/2017 The relative formula mass of a compound is blatantly the relative atomic masses of all the elements in the compound added together. E.g. water H2O: Relative atomic mass of O = 16 Relative atomic mass of H = 1 Therefore Mr for water = 16 + (2x1) = 18 Work out Mr for the following compounds: 1) HCl H=1, Cl=35 so Mr = 36 2) NaOH Na=23, O=16, H=1 so Mr = 40 3) MgCl2 Mg=24, Cl=35 so Mr = 24+(2x35) = 94 4) H2SO4 H=1, S=32, O=16 so Mr = (2x1)+32+(4x16) = 98 5) K2CO3 K=39, C=12, O=16 so Mr = (2x39)+12+(3x16) = 138 More examples CaCO3 40 + 12 + 3x16 HNO3 1 + 14 + 3x16 2MgO 2 x (24 + 16) 3H2O 3 x ((2x1) + 16) 4NH3 2KMnO4 3C2H5OH 4Ca(OH)2 12/05/2017 100 80 PROGRESS CHECK Mr of CO2 ADD Mr of NaCl ADD Mr of MgO 142.5 PROGRESS CHECK Mr of CuSO4 SUBTRACT Mr of Al2O3 58 PROGRESS CHECK Mr of H2O 35 ADD Mr of ammonia Calculating percentage mass 12/05/2017 If you can work out Mr then this bit is easy… Percentage mass (%) = Mass of element Ar Relative formula mass Mr x100% Calculate the percentage mass of magnesium in magnesium oxide, MgO: Ar for magnesium = 24 Ar for oxygen = 16 Mr for magnesium oxide = 24 + 16 = 40 Therefore percentage mass = 24/40 x 100% = 60% Calculate the percentage mass of the following: 1) Hydrogen in hydrochloric acid, HCl 2) Potassium in potassium chloride, KCl 3) Calcium in calcium chloride, CaCl2 4) Oxygen in water, H2O Calculating the mass of a metal that can be extracted from its mineral. • How much Fe could you get from 100kg of Fe2O3? • There are 2 steps; • 1. Calculate the percentage mass (composition) for the element in this case Fe. • 2. Multiply the percentage mass (from step 1) by the mass of the mineral An example. • • • • Percentage composition of Fe in Fe2O3 Mass of Fe in Fe2O3 = 2 x 56 =112 Mass of Fe2O3 = 2 x 56 + 3 x 16 = 160 Percentage Fe in Fe2O3 = 112 x 100 = 70% 160 • Mass of Fe in 100 kg of Fe2O3 = 70 x 100 • = 70 kg • Click here for more examples of percentage composition problems. DEMONSTRATE How much gold is in your mobile phone? Use the procedure to calculate the percentage composition of gold in a mobile phone More problems. • 1. What mass of Al could be made from 1 tonne of Al2O3? • 2. What mass of Na could be made from 2 tonnes of NaCl? • 3. The main ore of chromium is FeCr2O4. What is the percentage mass of Cr in FeCr2O4? • 4. 1000 tonnes of copper ore are dug out of the ground. Only 1% of this is the pure mineral, CuFeS2. What mass of the Cu could be made from 1000 tonnes of the ore? Conservation of Mass Show that mass is conserved in this reaction. ZnCO3 ZnO + CO2 You need to use the ideas of Mr Simple chemical reactions H Mg Cl O H Magnesium + oxide MgO Cl Cl Mg H Cl Magnesium chloride + Water 2HCl MgCl2 + H2O + Cu O O S O Cu Mg Mg + Copper sulphate CuSO4 O S O O Magnesium + H Hydrochloric acid O Mg O Copper + Magnesium sulphate Cu + MgSO4 O Balancing reaction equations This sequence of slides includes two approaches to balancing reaction equations. Individual slides may be copied elsewhere or used as templates. 1 Using symbols and no text click here 2 Using text prompts to explain each step of the process click here To return to this page, click the button to the top right of any slide. Original slide prepared for the 2Mg + O2 2 MgO Symbols Mg + O2 Original slide prepared for the 2 Al + 1½ I23 23 AlI Symbols Al + I2 Original slide prepared for the Write a balanced equation sodium + water sodium hydroxide + hydrogen formula each substance Checkthe thein equation balanced: Add Write numbers front of ofis the ringed formula asofitreactant is ringedof above countsothe number and productsymbols elements that the total number reactant = total number of product symbols sodium hydroxide is ionic: Reactants: 2Na 4H 2O what are the formulae of its ions? Products:+ 2Na 4H- 2O Na and OH It’s balanced! 2 Na + 2 H2O 2 NaOH + H2 Original slide prepared for the References First example, with symbols only: Frank Harriss of Malvern College Second example, with text prompts: Steve Lewis Original slide prepared for the Some examples 2Mg O2 2 MgO Zn + 2 HCl ZnCl2 2 Fe + 3Cl2 2 FeCl3 NaOH CH4 Ca + + HCl + 2 O2 NaCl CO2 + + H2 H 2O + 2H2O + 2 H2O Ca(OH)2 + + H2SO4 Na2SO4 + 2H2O 2 CH3OH + 3 O2 2 NaOH 2 CO2 + 4H2O H2 Balancing equations