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Introduction to Chemistry Mrs. Ferry www.unit5.org/chemistry Job Skills for the Future Evaluate and Analyze Think Critically Solve Math Problems Organize and Use References Synthesize Ideas Apply Ideas to New Areas Be Creative Make Decisions with Incomplete Information Communicate in Many Modes Chemistry will develop ALL of these skills in YOU! Unit 1 – Chemistry Basics Here we go! Chemistry is the study of matter and the transformations it can undergo… Chemistry with a Purpose Areas of Chemistry Organic The study of most carbon-containing compounds Inorganic The study of all substances not classified as organic, mainly those compounds that do not contain carbon Analytical The identification of the components and composition of materials Physical The study of the properties, changes, and relationships between energy and matter Biochemistry The study of substances and processes occurring in living things The Scientific Method 1- OBSERVE a phenomenon/ Ask a question 2- Form a HYPOTHESIS about it 3- EXPERIMENT to test hypothesis 4- Collect DATA and OBSERVATIONS 5- Draw a CONCLUSION Using the scientific method requires that one be a good observer. observation uses the five senses inference involves a judgment or assumption “My mother the eye doctor” Observation or Inference? The Names The piece player players adult mother of are player theof iswritten holding teams isin the holding of paper holding awearing the the catcher. umpire. ispicture batter ison the called aaapiece note bat bat. isare uniforms. the isan from oftalking. on “Reds.” paper. optometrist opposite the mother teams. orofopthalmologist the batter. (an eye doctor). One athe catcher’s mask. Hypotheses A tentative explanation for the observations May not be correct, but it puts the scientist’s understanding of the system being studied into a form that can be tested Copyright © 2007 Pearson Benjamin Cummings. All rights reserved. 1.2 Scientific Method Experiment Set of controlled observations Independent variable – the variable that will be changed. Dependant variable – the value that changes when the independent variable changes. Constants – the other factors that are not allowed to change. Control – standard used for comparison 1.2 Scientific Method Experiment continued An experiment is designed to test the hypothesis that table salt will dissolve faster in hot water than in room temperature water. Independent variable: temperature Dependant variable: rate of dissolving Constants: amount of salt, water, and stirring Control: rate room temp water dissolves Data Observations are also called data. There are two types of data. qualitative data descriptions; no numbers quantitative data measurements; must have numbers and UNITS Scientific Law vs. Scientific Theory A law states what happens. Law of Gravity A theory tries to explain why or how something happens. Theory of Evolution Atomic Theory States of Matter: Solid, Liquid, Gas (a) Particles in solid Def. Shape & Vol. (b) Particles in liquid (c) Particles in gas Indef. Shape, Def. Vol. Indef. Shape & Vol. Some Properties of Solids, Liquids, and Gases Property Solid Liquid Gas Shape Has definite shape Takes the shape of the container Volume Has a definite volume Has a definite volume Arrangement of Particles Fixed, very close Random, close Random, far apart Strong Essentially none Interactions between particles Very strong Takes the shape of its container Fills the volume of the container Properties of Matter Physical property – quality of a substance that can be observed without changing the substances composition Name some physical properties! Properties of Matter Two Types of Physical Properties – Extensive properties – dependent upon the amount of substance present. • Mass, volume, and length – Intensive properties – independent of the amount of substance present. • density Properties of Matter Chemical property – The ability of a substance to undergo chemical reactions and to form a new substance Ex. Rusting is a chemical properties of iron Other ex: rotting, decomposing, fermenting, corroding, growing, decaying. Physical and Chemical Properties Examples of Physical Properties Boiling point Color Slipperiness Electrical conductivity Melting point Taste Odor Dissolves in water Shininess (luster) Softness Ductility Viscosity (resistance to flow) Volatility HardnessMalleability Density (mass / volume ratio) Examples of Chemical Properties Burns in air Reacts with certain acids Decomposes when heated Explodes Reacts with certain metals Reacts with certain nonmetals Tarnishes Reacts with water Is toxic Ralph A. Burns, Fundamentals of Chemistry 1999, page 23 Chemical properties can ONLY be observed during a chemical reaction! Changes in Matter Physical change – change that results in a dramatically different appearance yet leave the composition of the substance unchanged. Crumpling of a sheet of aluminum foil. Changes in state Changes in Matter Chemical change – of a process where one or more other substances change into new substances. Starting Substances = Reactants New Substances = Products How do you know if it’s a chemical change has occurred? 1.Color change • Solid or liquid precipitate 2.Odor or gas produced. 3.Light or energy involved. Physical & Chemical Changes CO2 crushing heating Pyrex PHYSICAL CHANGE Limestone, CaCO3 CHEMICAL CHANGE CaO Crushed limestone, CaCO3 Lime and carbon dioxide, CaO + CO2 The formation of a compound The formation of a mixture Sunlight energy O2 Pyrex H2O2 Pyrex H2O Light hastens the decomposition of hydrogen peroxide, H2O2. The dark bottle in which hydrogen peroxide is usually stored keeps out the light, thus protecting the H2O2 from decomposition. H H O O Chemistry Basics Chemical vs. Physical Change Memory Tool… Vs. Elements & Compounds ELEMENTS: the simplest forms of matter that can exist under normal laboratory conditions Cannot be separated into simpler substances Building blocks for all other substances COMPOUNDS: Substances that can be separated into simpler substances only by chemical reactions. Elements are always present in specific proportions Every element and compounds has its own unique set of properties. Chemical Symbols Each element is represented by a chemical symbol. The first letter is always capitalized If a second letter is used, it must be lowercase. Groups of Elements 1A 1 H 1 2 3 Be 3 4 7 2A Alkaline earth metals 6A Oxygen group Transition metals 7A Halogens 3A Boron group 8A Noble gases 4A Carbon group 8A He 3A 4A B C 5A 6A 7A 2 N O F Ne Hydrogen Inner transition metals 5 6 7 8 9 10 Al Si P S Cl Ar 8B K 3B 4B 5B 6B 7B 1B 2B 13 14 15 16 17 Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br 12 20 21 22 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In 39 40 41 42 49 Hf Ta W 72 73 74 37 6 Nitrogen group Na Mg 19 5 5A 2A Li 11 4 1A Alkali metals 38 Cs Ba 55 56 Fr Ra 87 88 * W La 57 W 24 25 43 26 44 Re Os 75 76 27 28 29 47 30 45 46 Ir Pt Au Hg Tl 77 78 81 79 48 31 80 32 33 34 Sn Sb Te 50 51 Pb Bi 82 83 52 Kr 35 36 I Xe 53 54 Po At Rn 84 85 86 Rf Db Sg Bh Hs Mt 104 * 23 18 Ac 89 105 106 107 108 109 Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 58 59 60 Th Pa U 90 92 91 61 62 63 64 65 66 Np Pu Am Cm Bk Cf 93 94 95 96 97 98 67 68 69 70 71 Es Fm Md No Lr 99 100 101 102 103 Mixtures of Matter Classifying Mixtures Mixture – physical blend of two or more substances. Can be separated Substances are not present in specific ratios 1. Heterogeneous mixture – nonuniform composition. 2. Homogeneous mixture (solution) – uniform composition. Mixtures of Matter Separating Mixtures Distillation – uses differences in boiling points to separate liquid-solid or liquid-liquid mixtures. Mixtures of Matter Separating Mixtures Filtration – separate by passing through a barrier Changes in Matter Conservation of Mass Law of conservation of mass – in an ordinary chemical or physical reaction, mass can’t be created or destroyed. mass reactants = mass products Changes in Matter Changes in Matter A reaction between sodium hydroxide and hydrogen chloride gas produces sodium chloride and water. A reaction of 22.85 g of sodium hydroxide22.85 with 20.82 g of hydrogen g 20.82ggof water. What mass of sodium chloride gives off 10.29 10.29 gin the reaction? chloride is formed sodium hydroxide + hydrogen chloride sodium chloride + water 22.85 g + 20.82 g = sodium chloride + 10.29 g 43.67 g = sodium chloride + 10.29 g 33.38 g sodium chloride Changes in Matter A reaction between sodium hydroxide and 19.87 g hydrochloric acid produces water and sodium chloride. If I end up with 7.54 g of water and 35.29g of sodium chloride, how much sodium hydroxide did I start with?