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Essential Chemistry for Biology Matter: Elements and Compounds All biologists have to have a basic understanding of chemistry There are 92 naturally-occurring elements All living organisms are made of atoms of basic naturally-occurring elements ~25 are essential for life Matter is anything that occupies space and has mass Matter on Earth is found in three physical states solid, liquid, and gas Mass is a measure of the amount of material in an object An element is a substance that cannot be broken down into other substances by chemical reactions All matter is composed of chemical elements All biologists have to have a basic understanding of chemistry There are 92 naturally-occurring elements All living organisms are made of atoms of basic naturally-occurring elements ~25 are essential for life Atoms Each element consists of one kind of atom The atom is the fundamental unit of matter Atomic structure All atoms are composed of three subatomic particles Protons - positively charged particles Neutons - neutral particles Electrons - negatively charged particles Protons and neutrons are found in the nucleus of the atom Electrons orbit the nucleus Number of protons = atomic number This determines the chemical properties of the element Number of protons + neutrons = mass number Atoms are electrically neutral Isotopes All atoms of a particular element have the same atomic number However, they can vary in the number of neutrons Atoms of the same element with different numbers of neutrons are called isotopes They have the same chemical properties but different physical properties Many elements can combine to form compounds This is due to the interactions of atoms of the elements It all has to do with the electrons The chemical reactivity of an atom is determined by its electron configuration Atoms whose outer shells are not full tend to interact with other atoms They readily participate in chemical reactions They are reactive! The electron configuration follows specific rules 2, 8, 8, 18 Chemical bonding and molecules Chemical bonds hold atoms together These form when atoms share or after they transfer electrons Ionic bond Covalent bond Occurs when two atoms share electrons Water molecules H atoms exert a weak pull on the shared electrons and the O atom exerts a strong pull The water molecule exhibits polarity; it is polar Water The properties of water are due to the properties of the water molecule The major contributing factor is the polarity of the water molecule Hydrogen Bonds The polarity of water results in weak electrical attractions between neighboring water molecules These weak attractions are called hydrogen bonds Cohesion Responsible for surface tension It also allows the transport of water from the roots to the leaves of tall trees Water resists changes in temperature Temperature is a measure of the average speed of molecules Water is an excellent solvent for other charged or polar substances When something is dissolved in water, we have an aqueous solution Consider sugar or salt dissolved in water The substance dissolved is the solute But by the same token, water is not a good solvent for nonpolar molecules Hydrophilic compounds interact well with water Hydrophobic compounds do not Chemical Reactions Cells constantly rearrange molecules by breaking existing chemical bonds and forming new ones Such changes in the chemical composition of matter are called chemical reactions Chemical reactions include reactants or starting materials products or end materials Chemical reactions can rearrange matter but cannot create or destroy matter Acids, bases, pH In aqueous solutions, some water molecules dissociate into ions (H+ and OH-) Organisms need the correct balance of these H+ and OHAcids (more H+), bases (less H+) pH scale Even slight changes in pH can be harmful to organisms Because of this many biological fluids contain buffers to maintain correct pH ranges When CO2 dissolves in seawater, it reacts with the water to form an acid lowering ocean pH and greatly affecting marine environments