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Chemistry 10/14 The History of the Atom ChemSaver p 17 • (400 B.C.) Democritus of Adbera (northern Greece) asserted that all material things are composed of extremely small irreducible particles called atoms. • The atomic theory was roundly rejected by Aristotle, and, thus, by almost everybody else for the next two millennia. Democritus’ Atomic Model Dalton’s Atomic Theory (1808) John Dalton 1. All matter is composed of extremely small particles called atoms 2. Atoms of a given element are identical in size, mass, and other properties; atoms of different elements differ in size, mass, and other properties Dalton’s Atomic Theory Continued (1808) John Dalton 3. Atoms cannot be subdivided, created, or destroyed 4. Atoms of different elements combine in simple whole-number ratios to form chemical compounds 5. In chemical reactions, atoms are combined, separated, or rearranged Dalton’s Atomic Model Cathode Ray Experiment 1. What will the particles in the tube do when the current is turned on? 2. What evidence did this experiment provide that electrons are negatively charged? 3. How do you think this experiment would be different if more powerful magnets were used? Click here for demonstration Chem Saver page 17 • JJ Thomson • The Cathode ray tube experiment showed: • That atoms are divisible. • That negatively charged particles can be easily ejected from an atom. • Thomson developed the “plum pudding model” of the atom (chocolate chip cookie dough from my point of view!) JJ Thomson’s Atomic Model Rutherford’s Gold Foil Experiment 1. Why did most of the alpha particles pass through the gold foil undeflected? 2. Why were a few of the alpha particles deflected at wide angles when they passed through the gold foil? 3. Why did some alpha particles appear to bounce off the gold foil at very large angles, some even back toward their source? Click here for demonstration Chem Saver page 17 • Ernest Rutherford • Since some alpha particles “bounced” back Rutherford concluded: • Atoms are mostly empty space (99+%) • Atoms have a small, dense, and very positive nuclei • Most of the mass of an atom is in its nucleus Rutherford’s Atomic Model The size of a nucleus to the electron cloud of an atom is similar to the size of one blade of turf in reliant stadium