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Lipids Include substances commonly called fats, oils and waxes. Made up of C, H and O but relatively less oxygen than in carbohydrates. Dissolve in organic solvents but not in water (hydrophobic) Formed from the combination of fatty acids and glycerol. Functions of Lipids Reserve Energy Supply - Fats yield more than twice as much energy as carbohydrates when broken down. Component of cell structure, especially cell membrane Act as cushion for delicate organs Help to retain body heat (insulation) Serve as carriers for vitamins A, D, E, K Act as the raw material for the synthesis of hormones. A fatty acid molecule consists of a chain of carbon atoms to which hydrogen atoms are bonded. At one end of the chain there is a carboxyl group COOH. Carboxyl group Glycerol – is an alcohol that has three OH groups in its molecule. A molecule of fat (triglyceride) is produced by the combination of three fatty acid molecules with one glycerol molecule. A condensation reaction takes place between a hydroxyl group of the glycerol and the carboxyl group of a fatty acid. The bond is called an ester linkage. Saturated Fats – A fat formed from fatty acids in which all carbon-to-carbon bonds are single bonds. Unsaturated Fats – A fat formed from a fatty acid in which there are one or more double or triple carbon-to-carbon bonds. Waxes – Fatty acids combined with either alcohols or other hydrocarbons that form a hard, water-repellent covering. Waxes coat leaves, fruit, fur, and feathers making them water repellent. Steroids (sterols) – Lipids that have four interconnected carbon rings with various side chains. Cholesterol is an important steroid component of cell membranes. It is used to produce bile salts and vitamin D. Forms the sex hormones e.g. estrogen and testosterone. Cortisone Phospholipids – Consists of glycerol attached to 2 (not 3) fatty acids chains. A phosphate group attaches to the third hydroxyl group of glycerol. Forms a major part of cell membranes. Micelles – spheres formed when phospholipids are added to water Questions p. 40 #11, 12 & 16 Questions on handout