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SCIENCE DEPARTMENT AP Chemistry Syllabus Teacher: Marilia Martinez Room 414 Email: [email protected] Text: Chemistry The central Science by Brown, Lemay, Bursten, and Murphy, 2009. ISBN-‐13: 978-‐0-‐13-‐601879-‐7 ISBN-‐10: 0-‐13-‐601879-‐3 Additional Resources Required: Multiple-‐ Choice & Free Response Questions In Preparation for the AP Chemistry Examination, Fifth Edition Multiple-‐ Choice & Free Response Questions In Preparation for the AP Chemistry Examination (Student’s Solution), Fifth Edition Mastering Chemistry account Composition notebook Scientific calculator Pens and pencils 2014-2015 Mastering Chemistry access instructions: The student must visit www.pearsonschool.com/access , and follow the onscreen instructions to locate and register for Brown/Lemay/Bursten, Chemistry The Central Science 11e, Mastering Chemistry. When prompted to do so enter the following access code into the space provided: SSNAST-TTBBO-MOUSY-PRIVY-TRAWL-TAXES Course Description: In this AP Chemistry Course the student shall cover all material outlined in the new AP Chemistry Course Outline as follows: Big Idea 1: The chemical elements are fundamental building materials of matter, and all matter can be understood in terms of arrangements of atoms. These atoms retain their identity in chemical reactions. Big Idea 2: Chemical and physical properties of materials can be explained by the structure and the arrangement of atoms, ions, or molecules and the forces between them. Big Idea 3: Changes in matter involve the rearrangement and/or reorganization of atoms and/or the transfer of electrons. SCIENCE DEPARTMENT AP Chemistry Syllabus Big Idea 4: Rates of chemical reactions are determined by details of the molecular collisions. Big Idea 5: The laws of thermodynamics describe the essential role of energy and explain and predict the direction of changes in matter. Big Idea 6: Any bond or intermolecular attraction that can be formed can be broken. These two processes are in a dynamic competition, sensitive to initial conditions and external perturbations. The science practices for AP Chemistry are designed to get the students to think and act like scientists. The science practices are: Science Practice 1: The student can use representations and models to communicate scientific phenomena and solve scientific problems. Science Practice 2: The student can use mathematics appropriately. Science Practice 3: The student can engage in scientific questioning to extend thinking or to guide investigations within the context of the AP course. Science Practice 4: The student can plan and implement data collection strategies in relation to a particular scientific question. Science Practice 5: The student can perform data analysis and evaluation of evidence. Science Practice 6: The student can work with scientific explanations and theories. Science Practice 7: The student is able to connect and relate knowledge across various scales, concepts, and representations in and across domains. Home Learning: Students will be responsible to complete assigned home learning assignments assigned from the supplementary workbook: Multiple-‐ Choice & Free Response Questions In Preparation for the AP Chemistry Examination, Fifth Edition, worksheets and online interactive assignments through the mastering chemistry website. The Home Learning assignments will be due and reviewed the following class. Laboratory: A minimum of 25% of class time will be dedicated to conduct laboratories. Students will also be required to complete 6 guided inquiry labs, where the student will design their own experiment/ procedures using knowledge from previous activities to solve a problem. Due to time constraints SCIENCE DEPARTMENT AP Chemistry Syllabus because of our 8 block schedule we will be conducting additional laboratory sessions after school on Tuesdays as per our tentative schedule. These lab sessions are Mandatory NOT OPTIONAL! Laboratory Notebook: Apart from the students class notebook the student will be given a laboratory notebook with carbon copies. This notebook will be dedicated solely to lab reports. Students will be expected to prepare a pre-‐lab prior to the day they will perform the lab (directions on how to prepare pre-‐lab will be reviewed in class.) The day of the laboratory experiment they will perform the procedures and collect their data. From the data collected they will finish their formal lab with their calculations and conclusions that will be turned in next class for a grade. Laboratory Report Requirements: Pre Labs are required before any student can begin any in class laboratory. Pre-lab requirements are below: • Name and Date. The students name and date should be printed in the upper left hand corner of your laboratory notebook. • Title: The Pre-lab must have a title in the top center of the lab report. The title must briefly describe what is being investigated. • Introduction/ Purpose: The introduction must summarize the purpose of the lab in 2 to 3 sentences. • Procedure: Students must re-write procedures in their own words and use exact measurements and equipment as the lab manual instructs. They may be written as steps (bulleted or numbered.) • Pre-Lab Questions: These questions will be provided to the student prior to the lab. Student must answer the questions before starting the lab. Students must use their resources available to answer the questions in its entirety. • Data Tables: Data tables must be pre-constructed in your lab reports to collect data during the lab. Students may not spend class/lab time drawing tables. Post Lab requirements • The final lab report should include all of the previous requirements and the additional following: • Calculations and graphs: All calculations including all the steps must be included as part of your lab report. When necessary one must create graphs to show relationships of variables tested. Graphs must be labeled accordingly(title, axis, units and keys.) SCIENCE DEPARTMENT AP Chemistry Syllabus • • Conclusion: Students must write a complete conclusion that includes analysis of the results. Discussion of results from other groups must be included when indicated to do so. They must be well written using correct terms and ideas accurately. Post lab questions: All labs have are accompanied by a post lab question section that must be completed when lab reports are to be turned in to class. Outline of topics Chapter Ch. One and Two Atoms, Molecules and Ions Topics Covered • Atomic structure • Average atomic mass • Isotopes Activities/ LABS LAB: Spectroscopy: What Is the Relationship Between the Concentration of a Solution andthe Amount of Transmitted Light Through the Solution? LO 1.15 The student can justify the selection of a particular type of spectroscopy to measure properties associated with vibrational or electronic motions of molecules. *Home Learning: Ch1 Atomic Structure from AP Exam manual. Complete Multiple choice and free response questions. Quiz on Ch 1 and Ch 2 Big Ideas 1 2 3 SCIENCE DEPARTMENT AP Chemistry Syllabus Ch. Three Chemical Reactions • Double Replacement, single replacement, combustion, decomposition, combination reactions, gas forming • Solubility rules • Precipitation reactions • Acid-base reactions • Redox reactions • Combustion analysis Guided Inquiry LAB: Spectrophotometry: How Can Color Be Used to Determine the Mass Percent of Copper in Brass? LO 1.16 The student can design and/or interpret the results of an experiment regarding the absorption of light to determine the concentration of an absorbing species in a solution. 1 2 3 5 6 Chemical reaction worksheet. Students will be given word equations and they must identify and write out the entire balanced chemical reaction. Quiz on Ch 3 Ch. Four Quantitative Information and Chemical Reactions • Nomenclature • Molar mass of compounds • Hydrated compounds • Balancing equations • Percent composition • Excess and limiting reagents • Percent yield LAB: Gravimetric Analysis: What Makes Hard Water Hard? LO 1.19 The student can design, and/or interpret data from, an experiment that uses gravimetric analysis to determine the concentration of an analyte in a solution. 1 3 Ch 4 problem set. Stoichiometry Word Problem Worksheet. Given balanced chemical equations students must determine limiting reactant and find unknown values of the product formed. Ch. Five Principles of Chemistry Reactivity: Energy and Chemical Reactions •Energy •Specific Heat •First Law of Thermodynamics •Enthalpy and calorimetry •Hess’s Law Quiz on Ch 4 Coffee Cup Calorimeter Lab Determine enthalpy change of a basic neutralization reaction. Ch 5 online problem set. Ch5 Quiz 3 5 SCIENCE DEPARTMENT AP Chemistry Syllabus Ch. Six The Structure of Atoms Seven The Structure of Atoms and Periodic Trends • • • • Ch. Eight Bonding and Molecular Sturcture Ch. Nine Bonding and Molecular Structure: Orbital Hybridization Different models Quantum view of atom o Electron Configuratio ns Aufbau o Hund’s Rule o Pauli Exclusion Principle Periodic Trends o Different trends o Coulomb’s Law Photoelectron Spectroscopy • • • • • • • Bonding Metallic Ionic Covalent Types of energy associated with different structures: bond dissociation energy lattice energy Types of covalent bonds, sigma, pi, resonance structures Lewis Dot Guided Inquiry LAB: Stoichiometry: Using the Principle That Each Substance Has Unique Properties to Purify a Mixture: An Experiment in Applying Green Chemistry to Purification LO 3.5 The student is ableto design a plan in order to collect data on the synthesis or decomposition of a compound to confirm the conservation of matter and the law of definite proportions. 1 5 Ch six problem Set (worksheet.) Home Learning: Students compare periodic trends for different elements by graphing the value for the trend to identify the trend for each one. Students will use atomic radius, electronegativity and ionization energy. Ch 6 Quiz The students are provided with Potential Energy Curves and 1 compare single, double, and triple bonds – looking for 2 patterns and investigating the strength of the different types of 5 bonds. (LO 2.17) [CR3b] LAB: Physical and Chemical Changes: Can the Individual Componentsof Quick Ache Relief Be Used to Resolve Consumer Complaints? LO 3.10 The student is ableto evaluate the classificationof a process as a physical change, chemical change, or ambiguous change based on both macroscopic observations and the distinction between rearrangement of covalent interactions and noncovalent interactions. SCIENCE DEPARTMENT AP Chemistry Syllabus • • • Ch. Ten Gases and their Properties • • • Diagrams Formal Charge VSEPR Theory Hybridization Ch 8 and Ch9 Quiz Ideal versus Real Chapter 10 Practice problems using ideal gas law PV=nRT Gas Laws Kinetic Mastering Chemistry Ideal Gas Tutorial Molecular Theory Temperature and particle motion simulation. Students will graph the average kinetic energy of a gas vs temperature to determine the relationship. 1 2 3 5 Ch 10 Quiz Ch. Eleven Intermolecular Forces and Liquids Ch. Twelve The Chemistry of Solids Ch. Thirteen Solutions and Their Behavior • • • • • • • • • • Intermolecular Forces London Induced dipole – induced dipole Dipole – dipole o Bond versus molecular polarity Properties of liquids Structures of solids Phase Change Diagrams Solution Chemistry Supersaturated solutions Saturated solutions Unsaturated solutions Guided Inquiry LAB: Chromatography: LO 2.10 The student can design and interpret the results of a separation Sticky Question: How Do experiment (filtration, You Separate Molecules paper chromatography, That Are Attracted to column chromatography, One Another? or distillation) in terms of the relative strength of Based on prior knowledge interactions among and of intra and intermolecular between the components. forces determine the best solvent to separate unknown dye mixture. Guided Inquiry LAB: Bonding in Solids: What’s in That Bottle? Using Chemical and physical properties of a substance design a procedure to determine whether it is ionic, molecular or metallic. LO 2.22 The student is able to design or evaluate a plan to collect and/or interpret data needed to deduce the type of bonding in a sample of a solid. Ch 11 and 12 Practice problems and Worksheet on identifying the intermolecular force and/ or intramolecular force. 1 2 5 6 SCIENCE DEPARTMENT AP Chemistry Syllabus Ch 13 Problem set Ch 11, 12, 13 Quiz Ch. Nineteen Principles of Chemical Reactivity: Entropy and Free Energy • • • • • Ch. Twenty Principles of Reactivity: Electron Transfer Reactions • • • • • • • • Spontaneous versus nonspontaneous (thermodynamic ally favored versus not favored) Entropy Free Energy Three laws of thermodynamics Concept of equilibrium Review redox reactions Oxidation versus reduction Oxidizing and Reducing agents Galvanic and voltaic cells Electrolysis Relationships Relating thermodynamics to electrochemistry Relating electrochemistry to equilibrium via thermodynamics Worksheet Ch 19: Given a set of conditions, the students determine if the situation is thermodynamically favored or not favored by looking at entropy, enthalpy, and Gibbs Free Energy (LO 5.13) 2 5 6 Ch 19 Quiz Worksheet: Students balance by the half-reaction method. Students balance by oxidation number change method LAB: Redox Titration: How Can We Determine the Actual Percentage of H2O2 in a Drugstore Bottle of Hydrogen Peroxide? Ch 20 Quiz LO 3.9 The student is able to design and/or interpret the results of an experiment involving a redox titration. 3 5 6 SCIENCE DEPARTMENT AP Chemistry Syllabus Ch. Fourteen Chemical Kinetics: The Rates of Chemcial Reactions • • • • • • Students complete the worksheets “Simple Rate Laws” and Reaction rates “Not So Simple Rate Laws” and use the given data to Relative rates Rate law, general determine the order of each reactant (LO 4.2) [CR3d] form Determination of Guided Inquiry LO 4.1 The student is ableto rate law LAB: Kinetics: Rate design and/or interpretthe Graphical of Reaction: How results of an experiment methods for zero, first, and Long Will That regarding the factors (i.e., second order rate Marble Statue Last? temperature, concentration, laws. surface area) that may Mechanisms influence the rate of a 4 reaction. LAB: Kinetics: Rate Laws: LO 4.2 The student is able to analyze concentration vs. time data to determine the rate law What Is the Rate for a zeroth-, first-, or secondLaw of the Fading of order reaction. In cases in Crystal Violet Using which the concentration of Beer’s Law? any other reactants remains essentially constant during the course of the reaction, the order of a reaction with respect to a reactant concentration can be inferred from plots of the concentration of reactant versus time. Ch. Fifteen Principles of Reactivity: Chemical • • Nature of equilibrium Equilibrium Ch 14 Quiz Problem Set to determine the type of equilibrium problem it is (i.e. given K or asked to find K) and then determine the missing values by using an ICE table. This activity focuses on the structure of equilibrium questions. (LO 6.5) [CR3f] 6 SCIENCE DEPARTMENT AP Chemistry Syllabus Equilibria • • • • Ch. Sixteen Principles of Reactivity: The Chemistry of Acids and Bases • • • • • • • • • constant Kc and Kp Use of ICE tables to solve Kc, Kp Conversion between Kc, Kp Le Chatelier’s Principle Concepts of acid and bases Arrhenius Bronsted-Lowry Lewis Strength of acid and bases pH and pOH Ka, Kb Finding pH of strong and weak acids and bases Auto-ionization of water and Kw pH of different salts Guided Inquiry LAB: Equilibrium: Can We Make the Colors of the Rainbow? An Application of Le Châtelier’s Principle LO 6.9 The student is able to use LeChâtelier’s principleto design a set of conditions that will optimize a desired outcome, such as product yield. Ch 15 Quiz Guided Inquiry LAB: Titration: How Much Acid Is in Fruit Juice and Soft Drinks? Students must design an experiment using Titration methods to determine concentration of acid in fruit juice and soft drink. LO 1.20 The student can design, and/or interpret data from, an experiment that uses titration to determine the concentration of an analyte in a solution. Chapter 16 problem Calculations using Ka and Kb equations. Using values obtained to determine pH and/ or pOH Ch 16 Quiz 6 SCIENCE DEPARTMENT AP Chemistry Syllabus Ch. Seventeen Principles of Reactivity: Other Aspects of Aqueous Equilbria • • • • • Acid-base titration curves Indications and their roles Common ioneffect Buffers Solubilty product constant, Ksp LAB: Acid-Base Titration: How Do the Structure and the Initial Concentration of an Acid and a Base Influence the pH of the Resultant Solution During a Titration? LO 6.13 The student can interpret titration data for monoprotic or polyprotic acids involving titration of a weak or strong acid by a strong base (or a weak or strong base by a strong acid) to determine the concentration of the titrant and the pKa for a weak acid, or the pKb for a weak base. LAB: Buffering Activity: LO 6.20 The student can identify a solution as To What Extent Do being a buffer solution Common Household and explain the buffer Products Have Buffering mechanism in terms of Activity? the reactions that would occur on addition of acid or base. Guided Inquiry LAB: Buffer Design: The Preparation and Testing of an Effective Buffer: How Do Components Influence a Buffer’s pH and Capacity? LO 6.18 The student can design a buffer solution with a target pH and buffer capacity by selecting an appropriate conjugate acid-base pair and estimating the concentrations needed to achieve the desired capacity. 1 3 6 SCIENCE DEPARTMENT AP Chemistry Syllabus Soil Management for farming and gardening activity. Students will receive different soil samples from different areas with different pH values. Dependent on the type of crop grown in that area they must design the most effective buffer to maintain sustainable growth. Chapter 17 problem set Worksheet: Student will interpret charts that depict strong acid with strong base, strong acid and weak base, and strong base with weak acid. Each chart will be accompanied by guided question and calculations. Fourth Nine-‐Weeks There will be review conducted up until the day of the exam. Tutoring sessions will be announced in January. We will review on experimental design of previous labs. AP Exam will be scheduled early May. Final Exam will be administered the last week in May. Grading Policy: The grading system is based on weighted percentages. Each assignment will have a point value and weighed according to the category. (15%): Homework (Includes Mastering chemistry online assignments and other home learning assignments.) (15%): Classwork (In class assignments that are turned in for a grade, including group assignments) (20%): Laboratory (This includes lab attendance, pre-lab and post lab assignments) (20%): Quizzes (This includes scheduled and pop-quizzes) (30%): Chapter Tests (All cumulative exams at the end of each nine weeks) SCIENCE DEPARTMENT AP Chemistry Syllabus Classroom Expectations: -All students must respect themselves, the teacher and each other. -No disruptive behavior will be tolerated and will be dealt with accordingly with a detention or referral. -NO Electronic Devices of Any Kind Will be allowed during lectures, quizzes and exams. The only exception is the BYOD (bring your own device) policy during labs and group assignments. -NO food, drink, or gum should be brought into the classroom. -You are expected to be in class and in your assigned seat on time. -Be prepared for class! This means all necessary materials must be brought to class each day (homework, pen, paper, notebook etc). -The laboratory or room must be clean at the end of the period before leaving. -All school rules will be followed as stated in the student handbook. -All safety rules as stated in the Science Safety Agreement must be followed. SCIENCE DEPARTMENT AP Chemistry Syllabus Please detach and return with Safety Contract by Monday, August 25 (B day) or Tuesday August 26 (A day) Parent/Student Acknowledgement I acknowledge by my signature below, that I have read and discussed the AP Chemistry Syllabus with my parent/child. Student Name (print) __________________________________________ Period______ Student signature Parent Name (print) Parent signature IMPORTANT CONTACT INFORMATION Home phone # Best time to call Cell phone # Best time to call Work phone # Best time to call Parent’s Email address ________________________________________ Student’s Email address _______________________________________