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Richard T. Wright Environmental Science Tenth Edition Chapter 17 Water Pollution and Its Prevention Copyright © 2008 Pearson Prentice Hall, Inc. Warm-Up • Read the introduction to chapter 17 and be able to answer the following questions – Where does the Mississippi River end? – What was a consequence of filling in the wetlands that drained the Mississippi? – What is a hypoxic area and why is it bad? – What caused the hypoxic area? – What was a solution to lessen the nitrogen problem as a result of the Harmful Algal Bloom and Hypoxia Research and Control Act? – Look up the definition of eutrophic in your glossary. Dead Zone in the Gulf of Mexico Pollution – as defined by the EPA • Pollution: “the presence of a substance in the environment that because of its chemical composition or quantity prevents the functioning of natural processes and produces undesirable environmental and health effects.” Pollution Essentials • Pollution is not usually the result of deliberate actions – Usually a by-product of essential activities • • • • • Producing crops Creating comfortable homes Providing energy Transportation Manufacturing • Exacerbated by growing population and use of nonbiodegradable products – Resist attack and breakdown by detritus feeders and decomposers which cause them to accumulate • Ex – aluminum, plastic, synthetic organic chemicals. Categories of Pollution Point vs. Nonpoint Sources Point Sources • Relatively easy to identify and therefore are easier to monitor and regulate – Discharge of substances from factories, sewage systems, power plants, underground coal mines, oil wells. Nonpoint Sources • Poorly defined and scattered over broad areas – Occurs as rainfall and snowmelt move over and through the ground – Picks up pollutants such as agricultural runoff (farm animals and croplands), storm water drainage, atmospheric deposition Water Pollution: Point and Nonpoint Sources Water Quality Standards • The mere presence of a substance in water does not necessarily pose a problem – The CONCENTRATION of the pollutant is the primary concern Criteria Pollutants • To provide standards for assessing water pollution, the EPA has established the National Recommended Water Quality Criteria – EPA listed 167 chemicals and substances as criteria pollutants and the acceptable concentration in surface waters Clean Water Act • 1972 – Legislation establishing a federal program to protect and restore the physical, chemical, and biological integrity of the nations waters • Requires permits for any discharge of pollution, strengthens water quality standards, and encourages the use of best achievable pollution control technology • Provides funding for sewage treatment plants – Amended in 1987 Drinking Water • Standards are more strict • EPA established Drinking Water Standards and Health Advisories – Cover 94 contaminants and gives maximum contaminant levels for each Safe Drinking Water Act • 1974 – Authorizes EPA to regulate the quality and safety of public drinking-water supplies, maintain drinking –water standards for contaminants, and set requirements for the chemical and physical treatment of drinking water – Amended in 1996 Warm Up • “Improving Old MacDonald’s Farm” article Development of Wastewater Collection and Treatment Systems • Up through the 1970s, wastewater facilities would dump untreated sewage directly into waterways • Clean Water Act 1972 Video Clip • Sewage to Tap Water Pollutants in Raw Wastewater • Sources – All tub, sink, and toilet drains from homes and buildings • Raw wastewater – 99.9% water, 0.01% waste Types of Pollutants • Debris and grit – Plastic bags, sand, gravel, other objects flushed • Particulate organic material – Fecal matter, food wastes, toilet paper • Colloidal and dissolved organic material – Very fine particles of organic matter, bacteria, urine, soaps, detergents, other cleaning agents • Dissolved inorganic material – Nitrogen, phosphorus, other nutrients from excretory wastes and detergents Removing Pollutants from Wastewater • Preliminary Treatment – Removal of debris and grit – Two steps • Screening out debris – With use of bar screen – row of mounted bars • Settling out particulates – Grit chamber – water is slowed down to permit grit to settle Removing Pollutants from Wastewater • Primary Treatment – Removal of particulate organic material • Flows slowly through large tanks called primary clarifiers – Organic material (about 30-50%) settles to the bottom – Fatty or oily material floats to the top where it is skimmed off » Both the material that settles at the bottom and skimmed off of the top is combined and referred to as raw sludge Removing Pollutants From Wastewater • Secondary Treatment – Removal of colloidal and dissolved organic material • Biological treatment – uses natural decomposers and detritus feeders • Feeds on colloids and dissolved o.m to break it down to carbon dioxide, minerals, and water through cell respiration • Oxygen needs to be added so respiration will continue Secondary Treatment • Adding oxygen to water – Trickling filter – Activated sludge system – what you saw on field trip • Air bubbling system and activated sludge is added to water – As organisms feed they form clumps and settle when water is stilled – Go into second clarifier so organic sludge can settle out Trickling Filters for Secondary Treatment Trickling Filters for Secondary Treatment Biological Nutrient Removal (BNR) • To ease eutrophication – Nitrogen removal • Denitrification – bacteria convert ammonia and nitrate back to atmospheric nitrogen – Phosphorus removal • Bacteria take up phosphate from solution and store it in their bodies Final Cleansing and Disinfection • Chlorinate water • More common – use of UV Light • After these treatments, it is released back into a surface water source Removing Pollutants from Sewage: Match Technology with Function Technology Function Bar Screen Particulate organics Grit Screen Dissolved organics Primary Treatment Dissolved inorganics Secondary Treatment Large or small debris Warm-Up Warm Up • What are the steps of water purification in a sewage treatment plant? Treatment of Sludge • Raw Sludge – Gray, foul – smelling, syrupy liquid with a water content of about 97% • Pathogens are present in raw sludge because it includes material directly from toilets – Considered a biologically hazardous material, but if properly treated can be used as an organic fertilizer 3 Common Methods to Treat Sludge • Anaerobic digestion • Composting • Pasteurization Anaerobic Digestion • Process of allowing bacteria to feed on the detritus in the absence of oxygen. – Raw sewage is put into large, airtight sludge digesters • End products are CO2, CH4, H20 • Major bi-product is BIOGAS • Mixture that is about 2/3 CH4, therefore it is flamable and can be used for fuel Composting • Raw sludge is mixed with wood chips, or other material, to reduce water content • Mixture is then placed in a windrow – Long narrow piles that allow air to circulate and provides oxygen for bacteria to break down organic matter Pasteurization • After raw sludge is de-watered, the resulting sludge cake is put through ovens that operate like clothes dryers • Pasteurized sludge is heated sufficiently to kill any pathogens Applied Products • Milwaukee has rich sludge from brewing process • Uses pasteurization to make fertilizer pellets named Milogranite Alternative Treatment Systems • Many homes in rural and suburban areas may be outside the reaches of the municipal services • Currently, 25% of Americans has an on-site sewage system • Most Common – Septic Tank and Leaching Fields Septic Tanks/Leaching Fields • Wastewater flows into a tank where organic material sinks to the bottom – Acts as primary clarifier in a municipal plant • Water containing colloidal and dissolved o.m, and dissolved nutrients will flow onto a leaching field and gradually percolates into the soil • O.M that settles in the tank is digested by bacteria – Tanks need to be pumped out every so often Reconstructed Wetland Systems • Wetlands are capable of absorbing nutrients – Wetland function jigsaw. – You are all given a wetland function. You are to read about the function and put together a poster and notes-sheet to pass out to your classmates. – You are to make up a 5 question quiz on your function to administer at the end of your presentation Eutrophication • Different kinds of aquatic plants • The impacts of nutrient enrichment • Combating eutrophication Different Kinds of Aquatic Plants • Benthic plants – Benthos – Greek for deep – Emergent vegetation • Grows with the lower parts in water but the upper parts emerging from the water – Submerged aquatic vegetation (SAVs) • Grows totally underwater • Requires clear enough to allow sunlight • Absorbs nutrients from bottom sediments Different Kinds of Aquatic Plants • Phytoplankton – Live suspended in the water and are found wherever sunlight and nutrients are available • Green filamentous and single cell • Blue-green single cell • Diatoms single cell The Impacts of Nutrient Enrichment • Oligotrophic: nutrient-poor water – Fed by watershed that holds its nutrients well – Limit growth of phytoplankton • Eutrophic: nutrient-rich water – Rapid growth of phytoplankton, increases turbidity What kind of plants would dominate in oligotrophic vs. eutrophic conditions? Eutrophication in Shallow Lakes and Ponds Oligotrophic Eutrophic • As nutrients are added from pollution, an oligotrophic condition rapidly becomes eutrophic. Eutrophic or Oligotrophic? • High dissolved O2 • Deep light penetration • High phytoplankton Eutrophic or Oligotrophic? • • • • Turbid waters High species diversity Good recreational qualities High detritus decomposition Eutrophic or Oligotrophic? • • • • • • Low bacteria decomposition Benthic plants Warm water High nutrient concentration BOD High sediments Natural and Cultural Eutrophication • Natural eutrophication – aquatic succession – occurs over several hundreds of years • Cultural eutrophication – driven by human activities – occurs rapidly Combating Eutrophication • Attack the symptoms – Chemical treatment – Aeration – Harvesting aquatic weeds – Drawing water down Combating Eutrophication • Getting at root cause – Controlling point sources – Controlling nonpoint sources Controlling Point Sources • Ban phosphate detergents • Sewage-treatment improvements Controlling Nonpoint Sources • Difficult to address runoff pollutants – Urban – Agricultural fields – Deforested woodlands – Overgrazed pastures Controlling Nonpoint Sources • Best Management Practices (BMP): Table 17-2 – Agriculture – Construction – Urban Collecting Pond for Dairy-Barn Washings Public Policy • What was the legislative milestone in protecting natural waters and water supplies for each of the acts listed in Table 17-3? Lesson Activity • In some States, bio-solids are dried, bagged, and sold commercially for garden use, similar to cow manure or compost (Milorganite in Milwaukee for example) How is milorganite used? http://www.milorganite.com/