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Scientific Notation If there is no decimal place a decimal at the end of the number Move the decimal so that the new number is between 1-10 Write the new number and place a (x10) after the number Place an exponent above the 10, the exponent should be the number of places the decimal was moved. If the original number was greater than 1, than the exponent will be positive. If the number is less than one, the exponent will be negative Example: 45,000 = 4.5 x 104 0.00045 = 4.5 x 104 ** Use EE button on calculator for x10 ________________________________________________________________________ Rules for Significant Figures No decimal: Count Right to Left- 24,500 count has 3 significant figures Decimal: Count Left to Right- 0.045 count has 2 significant figures All non-zero digits (1-9) are significant ZEROS WHICH ARE PLACE HOLDERS ARE NOT SIGNIFICANT All non-zero digits (1-9) are significant. Zeros between non-zero digits are significant. Ex: 3004 has 4 significant figs. Zeros to the left of the first non-zero digit are not significant. Ex: 0.004 has 1 significant fig. If a number ends in zeros to the right of the decimal point, those zeros are significant. number 40.0 has 3 significant figures Ex: The Multiplication and division, the result may have no more significant figures than the factor with the fewest number of significant figures. Example: 2.52 x (3 sig figs) (smallest) 1.003 (4 sig figs) = 2.52756 recorded to 2.53 = (3 sig. figs) Adding and subtracting: Add or subtract the numbers. The final answer can contain only as many decimal places as found in the measurement with the fewest number of decimal places. Example: 134.052 m + 1.23 m = 135.282 rounds to 135.28 (3 decimal places) (2 decimal places) (2 decimal places) ________________________smallest_________________________________________ Density (mass unit/volume unit) = Mass (unit) ÷ Volume (unit) ________________________________________________________________________ Specific heat (c) (units) = calories / (grams x C) or joules / (grams x C) Heat released (cal or J) = mass (g) x Specific heat (choose one unit above) x temp change (ºC) ________________________________________________________________________ Conversions: When converting units make sure the unit you are looking for is on top of the conversion fraction and the unit given is on the bottom of the conversion fraction so the units given can cancel. 1 dozen Example: 132 pencils = ________ dozen 132 pencils x ---------------- = 11 dozen 12 pencils ________________________________________________________________________ Lewis / Electron-dot diagrams 1. Write symbol of element 2. Place the correct number of dots around the symbol (The number of dots equals the number of valance electrons or the group / roman number the element is in) 3. Spread out the dots before doubling up ● Aluminum = Group III ● Al ● ●● Nitrogen = Group V ● N ● ● Metric Conversions Units Length meters (Decreasing order) Kilo: 0.001 Km 1m Base unit: Centi: 100 cm 1000 mm Milli: 1,000,000 µm Micro: 1,000,000,000 nm Nano: Mass grams 0.001 Kg 1g 100 cg 1000 mg 1,000,000 µg 1,000,000,000 ng Volume liters 0.001 KL 1L 100 cL 1000 mL 1,000,000 µL 1,000,000,000 nL 1cm3 = 1 mL When choosing the ratios from the table above, one part of the ratio goes on top of the fraction and the other goes on the bottom. The ratio should be set up so that the top of the ratio should have the units that you are looking for and the bottom should be the units that you start with. Example: 2 mm = _______ cm Get from chart above 100 cm 2 mm ---------------- = 0.2 cm 1000 mm ________________________________________________________________________ Elements Nucleus is positively charged Number of neutrons= atomic mass - atomic number Atomic number= number of protons Number of protons= number of electrons Valence electrons= group number Electron: negative sub particle (outside of the nucleus) CHARGE= -1 Proton: positive sub particle (found in nucleus) CHARGE= +1 Neutron: neutral sub particle (found in nucleus) CHARGE= 0 Periodic table of elements: list of elements in order ______________________________________________________________________________ Percent Error Formula Percent error = [Measured value – Accepted value] Accepted value x 100 Percent Composition Percents 1. Place each part of the mixture over the total 2. Each fraction is divided 3. Each decimal is multiplied by 100 Percent composition Formula= Percent composition = (Mass of element x subscript) (mass of compound) x 100 the mass of each element is multiplied by their subscript the molar mass of the compound is the sum of the elements ________________________________________________________________________ Writing Formulas Ionic Compounds: oppositely charged ions. A metal and nonmetal(s) Binary Ionic Compounds Criss-cross to arrive at subscripts Ex: Sodium nitride = Na+1 and N -3 Na3N Ternary Ionic Compounds Aluminum hydroxide = Al+3 and (OH-1) switch numbers to get Al(OH)3 Binary Molecular (Covalent) Compounds: Prefixes (see chart below) become subscripts: Ex: Trinitrogen pentabromide N3Br5 Naming Compounds Binary Ionic: 1. One metal and nonmetal 2. If metal is from transitional group must use roman number if not just name metal 3. Nonmetal drops ending and adds “ide” Example: CaCl2 Example: Cr2S3 Calcium chloride Chromium (IIII) sulfide (Roman number is found as other subscript) Ternary Ionic Compounds 1. One metal and more than one nonmetal 2. If metal is from transitional group must use roman number if not just name 3. Nonmetal group gets name from polyatomic ion chart. Example: Ca(NO3)2 Calcium nitrate Example: Fe(OH)2 Iron (II) hydroxide (Roman number is found as other subscript) Binary Molecular (Covalent) Compounds: Both negative charged ions. Both non-metals (Use prefixes as subscripts) 1. Second nonmetal drops ending and adds “ide” Ex: N2O3 Dinitrogen trioxide Prefix Mon Di Tri Tetra Penta Number of atoms 1 2 3 4 5 Prefix Hexa Hepta Octa Nona Deca Number of atoms 6 7 8 9 10 Drawing Bohr diagrams 1. The number of protons and neutrons are place in the nucleus. 2. The electrons are placed in energy levels according to the maximum occupancy. (Fill each shell in numerical order until all electrons are used) Energy Level Maximum number of electrons 1 2 2 8 3 18 4 32 Ex: Argon #18 18p+ 22 n0 ﴿ 2e﴿ ﴿ 8e﴿ ﴿ 8e﴿ Temperature Conversions using formulas 1. To change Celsius to Fahrenheit: Take the given temperature and multiply by 1.80 then press equal then add 32 then press equal. 2. To change Fahrenheit to Celsius: Take the given subtract 32 then press equal then multiply the number by 0.56 then press equal. 3. To change Celsius to Kelvin: Add 273 to the given temperature 4. To change Kelvin to Celsius: Subtract 273 from the given temperature. Types of Equations Combination: A + B AB Decomposition: AB A + B Single Replacement: A + BC AC + B A + BC BA + C Double Replacement: Complete Combustion: (A is metal) (A is a nonmetal) AB + CD AD + CB AB + O2 CO2 + H2O Incomplete Combustion: AB + O2 CO + H2O ________________________________________________________________________ Scientists JJ Thompson discovered the negative part of the atom Rutherford discovered the center of the atom Aristotle believed all matter was made of earth, fire, wind and water Mendeleev organized the elements ________________________________________________________________________ Atomic Mass Diatomic Elements: H2, N2, O2,, F2, Cl2, Br2, I2 Double the mass Example: Bromine: 79.9 x 2= 158.80 Compounds Multiply the subscript of each element by the element’s atomic mass, and then add. Example: H2 O H2= 1.01 x 2 = 2.02 O= 15.99 x 1 = 15.99 Atomic Mass : 18.01 Compounds with Parenthesis Distribute number outside of parenthesis to numbers inside parenthesis, multiply the subscript of each element by the element’s atomic mass, and then add. Example: Ca(OH) 2 Ca O2 H2 Ca: 1 x 40.07 = 40.07 O2: 2 x 15.99 = 32.00 H2: 2 x 1.01 = 2.02 74.09 The Mole Mass to Moles Take the number of grams given and divide by the mass of the compound from the periodic table Example: 40.0 grams of H2O= 40g H2O / ( 2xH (1.01) + 1xO (16.0)) 40g H2O / (2.02 + 16) 40g H2O/ 18.02= 2.22 moles Moles to Mass Take the number of moles given and multiply by the mass of the compound from the periodic table Example: 4.00 moles of H2O = 4.0 mol H2O x (2 x H (1.01) + 1 x O (16.0)) 4.0 x (2.02 + 16) = 72.08 grams Moles to Particles Take the number given and multiply by 6.02 x 1023 Example: 4.5 moles of H2O= 4.5 mol H2O x 6.02 x 1023 2.71 x 1024 particles Particles to Moles Take the given number and divide by 6.02 x 1023 Example: 4.50 x 1024 particles of H2O= 4.50 x 1024 / 6.02 x 1023= 7.47 moles