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chlorine silver nitrogen gold oxygen hydrogen helium mercury sodium niobium neodymium carbon Physical & Chemical Properties What are properties? • Matter has observable and measurable qualities. • We can use general properties to identify substances. • Two basic types of properties of matter: Physical properties and Chemical properties: Physical Properties • Physical properties are used to identify, describe and classify matter. – Characteristic of a substance that can be observed (using your senses) without changing the substance into something else. Hardness Texture Color Odor Taste Not Chemicals Temperature More EXAMPLES - Physical • size, shape, freezing point, boiling point, melting point, magnetism, viscosity, density, luster and many more. – Viscosity - The resistance of a liquid to flowing. – Examples: – Low viscosity-water, rubbing alcohol – High viscosity-honey Chemical Properties • Chemical properties are characteristics involved when a substance interacts with another substance to change its chemical make-up. Flammability Rusting Color change Creating a Reactivity with new chemical water product Creating gas bubbles pH The material itself is the same before and after the change. The change CAN be “undone.” •Ice melting: an example of physical change Chemical Change Occurs when one or more substances are changed into entirely NEW substances They have different properties from the original substance •Some signs (or evidence) of chemical change are: •a gas is produced, •the temperature changes, •a substance disappears, •a solid is formed •a color change occurs, •a new odor is produced. Chemical Change •Cannot easily be undone •Have you ever tried to un-fry and egg? Heat is added Original Substance-Eggs New Substance-Fried Eggs Examples of Physical and Chemical Changes Physical Changes Chemical Changes Rubbing alcohol evaporates on your hand. Hydrogen peroxide bubbles in a cut. A juice box in the freezer freezes. Gasoline is ignited. Water evaporates from the surface of the ocean. Butter melts on warm toast. Rust forms on a nail left outside. Clay is molded into a new shape. Bread becomes toast. Milk goes sour. Summing it Up Physical Change: The matter is the same. The original matter can be recovered. The particles of the substance are rearranged. Chemical Change: The matter is different. The old matter is no longer present. The original matter cannot be recovered. Copper Penny Story Physical & chemical properties are very important when it comes to making coins. Cost is also important. • In the 1980s copper became to expensive to use for penny production in the USA. • A replace with similar properties was needed. • Zinc was used to replace most of the copper in all post 1982 pennies. • Zinc is as hard as copper, has similar density, its readily available and less expensive than copper. • Zinc is more reactive and in the 1940s was used to make pennies and it corroded so production ended. • Post 1982 pennies are copper on the outside and zinc on the inside. Periodic Table Periodic Table • The modern table was devised in 1869 by Dimitri Mendeleev • He arranged the elements by weight and by their chemical properties Mendeleev first trained as a teacher in the Pedagogic Institute of St. Petersburg before earning an advanced degree in chemistry in 1856. "...if all the elements be arranged in order of their atomic weights a periodic repetition of properties is obtained." - Mendeleyev Concerning the relation between the properties and atomic weights of elements. By D. Mendeleev. •Arranging the elements in vertical columns with increasing atomic weights, so that the horizontal rows contain similar elements, again in increasing weight order, the following table is obtained from which general predictions can be drawn •Elements show a periodicity of properties if listed in order of size of atomic weights. •Elements with similar properties either have atomic weights that are about the same (Pt, Ir, Os) or increase regularly (K, Rb, Cs). •The arrangement of the elements corresponds to their valency, and somewhat according to their chemical properties (eg Li, Be, B, C, N, O, F). Concerning the relation between the properties and atomic weights of elements. By D. Mendeleev. •The commonest elements have small atomic weights. •The value of the atomic weight determines the character of the element. •There are unknown elements to discover eg elements similar to Al and Si with atomic weights in range 65-75. •The atomic weights of some elements may be changed from knowing the properties of neighbouring elements. Thus the atomic weight of Te must be in range 123-126. It cannot be 128. •Some typical properties of an element can be predicted from its atomic weight. Periods and Groups • Horizontal rows in the periodic table are called periods • Vertical columns are called groups • We will learn later why the elements can be arranged in this fashion based on the arrangements of the electrons outside the nucleus Periods and Groups • Sizes of the atoms decrease as we move from left to right across a period • This is due to the increasing number of protons in the nucleus, so the electrical attraction between the nucleus and the orbiting electrons gets stronger and pulls the electrons closer to the nucleus. Periods and Groups • We can display the table to demonstrate other properties as well • As you move from left to right across a period, the ability of the atom to attract another electron increases • This property is called electronegativity Key to the Periodic Table • Elements are organized on the table according to their atomic number, usually found near the top of the square. – The atomic number refers to how many protons an atom of that element has. – For instance, hydrogen has 1 proton, so it’s atomic number is 1. – The atomic number is unique to that element. No two elements have the same atomic number. • Atomic Mass (bottom number) refers to the “weight” of the atom. • It is derived at by adding the number of protons with the number of neutrons. Atomic Mass and Isotopes • While most atoms have the same number of protons and neutrons, some don’t. • Some atoms have more or less neutrons than protons. These are called isotopes. Symbols C Carbon Cu Copper • All elements have their own unique symbol. • It can consist of a single capital letter, or a capital letter and one or two lower case letters. Properties of Metals • Metals are good conductors of heat and electricity. • Metals are shiny. • Metals are ductile (can be stretched into thin wires). • Metals are malleable (can be pounded into thin sheets). • A chemical property of metal is its reaction with water which results in corrosion. Properties of Non-Metals • Non-metals are poor conductors of heat and electricity. • Non-metals are not ductile or malleable. • Solid non-metals are brittle and break easily. • They are dull. • Many non-metals are gases. Sulfur Properties of Metalloids • Metalloids (metal-like) have properties of both metals and non-metals. • They are solids that can be shiny or dull. • They conduct heat and electricity better than nonmetals but not as well as metals. • They are ductile and malleable. Silicon Hydrogen • The hydrogen square sits atop the Alkali Metals Family, but it is not a member of that family. Hydrogen is in a class of its own. • It’s a gas at room temperature. • It has one proton and one electron in its one and only energy level. • Hydrogen only needs 2 electrons to fill up its valence shell (outer most electron shell). Alkali Metals • They are the most reactive metals. • They react violently with water. • Alkali metals are never found as free elements in nature. They are always bonded with another element. What does it mean to be reactive? • We will be describing elements according to their reactivity. • Elements that are reactive bond easily with other elements to make compounds. • Some elements are only found in nature bonded with other elements. • What makes an element reactive? – An incomplete valence electron level. – All atoms (except hydrogen) want to have 8 electrons in their very outermost energy level (This is called the rule of octet.) – Atoms bond until this level is complete. Atoms with few valence electrons lose them during bonding. Atoms with 6, 7, or 8 valence electrons gain electrons during bonding. Alkaline Earth Metals • They are never found uncombined in nature. • They have two valence electrons. • Alkaline earth metals include magnesium and calcium, among others. Transition Metals • These are the metals you are probably most familiar: copper, tin, zinc, iron, nickel, gold, and silver. • They are good conductors of heat and electricity. • The compounds of transition metals are usually brightly colored and are often used to color paints. • Transition elements have 1 or 2 valence electrons, which they lose when they form bonds with other atoms. Boron Family • The Boron Family is named after the first element in the family. • Atoms in this family have 3 valence electrons. • This family includes a metalloid (boron), and the rest are metals. • This family includes the most abundant metal in the earth’s crust (aluminum). • Atoms of this family have 4 valence electrons. • This family includes a nonmetal (carbon), metalloids, and metals. • The element carbon is called the “basis of life.” There is an entire branch of chemistry devoted to carbon compounds called organic chemistry. Nitrogen Family • The nitrogen family is named after the element that makes up 78% of our atmosphere. • This family includes nonmetals, metalloids, and metals. • Atoms in the nitrogen family have 5 valence electrons. They tend to share electrons when they bond. • Other elements in this family are phosphorus, arsenic, antimony, and bismuth. Chalcogen Family • Atoms of this family have 6 valence electrons. • Most elements in this family share electrons when forming compounds. • Oxygen is the most abundant element in the earth’s crust. It is extremely active and combines with almost all elements. Halogen Family • The elements in this family are fluorine, chlorine, bromine, iodine, and astatine. • Halogens have 7 valence electrons, which explains why they are the most active non-metals. They are never found free in nature. Halogen atoms only need to gain 1 electron to fill their outermost energy level. They react with alkali metals to form salts. Noble Gases • Noble Gases are colorless gases that are extremely unreactive. • One important property of the noble gases is their inactivity. They are inactive because their outermost energy level is full. • Because they do not readily combine with other elements to form compounds, the noble gases are called inert. • The family of noble gases includes helium, neon, argon, krypton, xenon, and radon. • All the noble gases are found in small amounts in the earth's atmosphere. Rare Earth Elements • The thirty rare earth elements are composed of the lanthanide and actinide series. • One element of the lanthanide series and most of the elements in the actinide series are called trans-uranium, which means synthetic or man-made.