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Glencoe Science Chapter Resources Chemical Bonds Includes: Reproducible Student Pages ASSESSMENT TRANSPARENCY ACTIVITIES ✔ Chapter Tests ✔ Section Focus Transparency Activities ✔ Chapter Review ✔ Teaching Transparency Activity ✔ Assessment Transparency Activity HANDS-ON ACTIVITIES ✔ Lab Worksheets for each Student Edition Activity Teacher Support and Planning ✔ Laboratory Activities ✔ Content Outline for Teaching ✔ Foldables–Reading and Study Skills activity sheet ✔ Spanish Resources ✔ Teacher Guide and Answers MEETING INDIVIDUAL NEEDS ✔ Directed Reading for Content Mastery ✔ Directed Reading for Content Mastery in Spanish ✔ Reinforcement ✔ Enrichment ✔ Note-taking Worksheets Name Date Directed Reading for Content Mastery Class Overview Chemical Bonds Directions: All of the statements below are false as written. In the space provided, write a term or phrase that makes the statement true when it is substituted for the underlined words. 1. The properties of a compound are the same as the properties of the elements that it contains. Meeting Individual Needs 2. Superscript numbers in chemical formulas tell how many atoms of each element are found in a unit of compound. 3. All the noble gases except helium have 18 electrons in their outer energy level. 4. A(n) chemical formula is the force that holds atoms together in a compound. 5. An ion is a(n) neutral particle that has either more or fewer electrons than protons. 6. Oxidation numbers are written as subscripts. Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. 7. A(n) covalent bond is the force of attraction between the opposite charges of the ions in an ionic compound. 8. The charge on a compound is always positive. 9. Equal sharing of electrons in covalent bonds results in polar molecules. 10. Only two identical atoms can share electrons unequally. 11. A binary compound contains five different elements. 12. An oxidation number tells how many protons an atom must gain, lose, or share to become stable. 13. The oxidation number of the copper(II) ion is 3+. 14. When writing chemical formulas, add superscripts so that the sum of the oxidation numbers equals ten. 15. A polyatomic ion never has a positive or negative charge. 16. The polyatomic ion SO42 is called the sulfide ion. Chemical Bonds 19 Name Date Directed Reading for Content Mastery Class Section 1 Stability in Bonding Section 2 Types of Bonds ■ ■ Directions: In the blanks, write the terms from the word list that complete the definition. Words can be used more than once. positive energy level(s) force(s) atom(s) element(s) charged ion(s) compound(s) number(s) electron(s) negative ____________________ and the exact ____________________ of atoms of each element in a unit of compound. 2. An atom is chemically stable when its outer ____________________ is completely filled with ____________________. 3. A chemical bond is a ____________________ that holds ____________________ together in a compound. 4. An ____________________ that has lost or gained ____________________ is called an ion. 5. An ionic bond is the ____________________ of attraction between the opposite charges of the ____________________ in an ionic ____________________. 6. The attraction that forms between ____________________ when they share ____________________ is known as a covalent bond. 7. A polar molecule has a slightly ____________________ end and a slightly ____________________ end. 8. A nonpolar molecule does not have oppositely ____________________ ends. Only atoms that are exactly alike can share their ____________________ equally. 20 Chemical Bonds Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. Meeting Individual Needs 1. A chemical formula tells what ____________________ make up a Name Date Directed Reading for Content Mastery Section 3 Class ■ Writing Formulas and Naming Compounds Meeting Individual Needs Directions: The words in each group below are related. Using all the words in the group, write a sentence that shows how the words are related. Example: compound, properties, elements The properties of a compound differ from the properties of the elements that make up the compound. 1. hydrate, compound, water 2. oxidation number, element, electrons 3. zero, oxidation numbers, noble gases Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. 4. oxidation number, Roman numeral, element 5. chemical formulas, neutral, compounds 6. polyatomic, covalent, charged 7. Greek prefixes, binary covalent compounds 8. charge, oxidation number, ionic compounds Chemical Bonds 21 Name Date Directed Reading for Content Mastery Class Key Terms Chemical Bonds Directions: Match each term in Column I with its description in Column II. Write the letter of the correct term in the space provided. 1. binary compound 2. chemically stable Meeting Individual Needs 3. nonpolar molecule 4. ion 5. ionic bond 6. polar molecule Column II a. number that indicates how many electrons an atom must gain, lose, or share to become stable b. shorthand that tells what elements a compound contains and the exact number of atoms of each element in a unit of the compound 7. oxidation number c. positively or negatively charged, covalently bonded group of atoms 8. chemical formula d. compound composed of two elements 9. covalent bond e. describes an atom that has a full outermost energy level 10. hydrate 11. chemical bond 12. polyatomic ion f. molecule that has a slightly positive end and a slightly negative end g. the attraction that forms between atoms when they share electrons h. the force that holds atoms together in a compound i. a compound that has water chemically attached to it j. the force of attraction between the opposite charges of the ions in an ionic compound k. molecule made of two identical atoms that share the electrons equally l. a charged particle that has either more or fewer electrons than protons 22 Chemical Bonds Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. Column I Name Date 1 Reinforcement Class Stability in Bonding Directions: Each statement below contains a pair of terms or phrases in parentheses. Circle the term or phrase that makes each statement true. 1. The properties of a compound are (the same as, different from) the properties of the elements that make up the compound. 2. Na and Cl are chemical (symbols, formulas). 4. In the formula H2O, the number 2 is a (subscript, superscript). 5. The number 2 in the formula H2O tells you that each unit of this compound contains two (hydrogen, oxygen) atoms. 6. If a symbol in a chemical formula does not have a subscript after it, a unit of that compound contains (no atoms, one atom) of that element. 7. The total number of atoms in Fe2O3 is (two, five, six). 8. There are (three, seven, ten) different elements in H2SO4. 9. An atom is chemically stable if its outer energy level (is filled with, contains no) electrons. Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. 10. For atoms of most noble gases and most other elements, the outer energy level is full when it has (3, 8) electrons. 11. The noble gases do not readily form compounds because they (are, are not) chemically stable. 12. A chemical bond is a (force, chemical) that holds atoms together in a compound. 13. Chemical bonds form when atoms lose, gain, or (share, multiply) electrons. Directions: Complete the table below by using the formula of each compound to identify the elements that each compound contains and the number of atoms of each of these elements in a unit of the compound. The first formula has been done for you. Formula Element 1 Element 2 HO 2 hydrogen 1 oxygen 2 14. NaOH 15. NaCl 16. NH 17. H SO 18. SiO Element 3 3 2 4 2 Chemical Bonds 27 Meeting Individual Needs 3. NaCl and NaOH are chemical (symbols, formulas). Name 2 Date Reinforcement Class Types of Bonds Directions: Study the diagram below. Write your answers to the questions in the spaces provided. A. B. 12P 12N 8P 8N b. how many electrons will atom B gain? c. what will be the oxidation number of atom A? d. what will be the oxidation number of atom B? e. what will be the total charge of the compound formed? f. what type of bond will form? 2. Explain why an element’s oxidation number is related to the group on the periodic table to which it belongs. Directions: Complete the table comparing ionic compounds and covalent compounds. Characteristic 3. How the compound is formed 4. Smallest particle 5. Usual state at room temperature 28 Chemical Bonds Ionic compounds Covalent compounds Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. Meeting Individual Needs 1. If atom A loses electrons to atom B, a. how many electrons will atom A lose? Name 3 Date Class Writing Formulas and Naming Compounds Reinforcement Directions: Answer the following questions in the spaces provided. Refer to the periodic table for help. 1. Define an oxidation number. 2. What is the usual oxidation number of oxygen? Of hydrogen? 4. Explain the difference between CoCl2 • 6H2O and anhydrous cobalt chloride. Directions: Use the periodic table in your textbook to identify the oxidation numbers of the elements in each group. Group Oxidation number 1 2 5. 6. 16 7. 17 8. 18 9. Directions: Write the formulas for the following compounds. Use the periodic table in your textbook for help. 10. copper(II) sulfate Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. 11. calcium chloride 12. iron(II) oxide 13. copper(I) oxide 14. sodium sulfide 15. magnesium sulfate heptahydrate Directions: Complete the following table by providing the name of the compound and the total number of atoms in each formula given. Formula Name Number of Atoms 16. NH4OH 17. NH4C1 18. Ag2O 19. K2SO4 20. Ca (NO3)2 21. Na2S Chemical Bonds 29 Meeting Individual Needs 3. What is the sum of all the oxidation numbers in any compound? Name 1 Date Enrichment Class Electron Dot Diagrams The electrons in an atom’s outer energy level are the electrons that are important to consider in chemical bonds and chemical reactions. These electrons can be represented in a diagram called an electron dot diagram. The outermost electrons are drawn as dots around the chemical symbol. In this activity, you will draw electron dot diagrams for several elements. Procedure Example: The symbol for chlorine is Cl. In an electron dot diagram, this symbol represents the nucleus and the ten electrons in the first two energy levels. 2. Use the periodic table to determine how many outer electrons the element has. Do this by finding to which group the element belongs. 3. Draw a dot to represent each electron in the outer level of the element. Two electrons can be placed on each side of the symbol. The first two electrons should be paired on the right side of the symbol. The rest of the outer electrons should be distributed counterclockwise one by one around the other sides of the symbol. Example: The electron dot diagram for chlorine is Cl Example: Chlorine belongs to Group 17, the halogens, which have seven outer electrons. Conclude and Apply 1. Write electron dot diagrams for the elements listed. a. hydrogen e. aluminum b. neon f. fluorine c. sodium g. argon d. calcium h. potassium 2. Why do sodium and potassium have the same number of dots in their electron dot diagrams? What does this tell you about the chemistry of these two elements? 30 Chemical Bonds Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. Meeting Individual Needs 1. Write the symbol for the element. For electron dot diagrams, this symbol represents the nucleus and all of the electrons of the atom except the outermost electrons. Name Enrichment Class Paper Chromatography Paper chromatography uses polarity to separate substances from a solution. The polarity of a substance affects how fast a particular substance dissolved in a particular solvent can move along paper. Because the rates of movement are very specific, chromatography can also be used to identify substances. In paper chromatography, a small sample of a solution is placed on absorbent paper. A solvent passes through the sample and carries the dissolved substances. The various substances in the solution move outward at different rates. The procedure described below demonstrates how components of a mixture can be separated. If a procedure is set up in a way that can identify how far the solvent travels and how far the dissolved substance travels, these distances can be measured and compared. The number obtained by dividing the distance the dissolved substance traveled by the distance the solvent traveled is known as R f. If specifics of the procedure such as temperature, solvent, and type of paper are controlled, the R f values can be used to identify the substances in a solution. Paper chromatography and other types of chromatography have many uses. An environmental chemist might use chromatography to identify pollutants in water, or a medical chemist to identify poison or medicines in the blood of a patient. Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. Materials Pipe cleaner petri dish yellow food coloring ink round filter paper metric ruler pipe cleaner toothpick solvent (water, rubbing alcohol, or ethanol) WARNING: Alcohol and ethanol are flammable. Food coloring Procedure Solvent 1. Add a small amount of solvent to a petri dish. 2. Use a toothpick to place a small drop of food coloring at the center of the filter paper. 3. Punch a small hole in the center of the filter paper with the toothpick. Place the pipe cleaner through this hole. 4. Carefully place the filter paper on top of the petri dish so that the end of the pipe cleaner touches the solvent. Observe what Filter paper Petri dish happens as the solvent moves up the pipe cleaner and across the filter paper 5. When the solvent has finished moving, remove the filter paper from the dish. Allow the filter paper to dry. 6. Repeat steps 2 through 5, using ink instead of food coloring. Use a new pipe cleaner and filter paper. Conclude and Apply 1. Why do different bands of color appear on different areas of the filter paper? 2. A student used felt-tip markers to make labels for one of his collections. When water splashed on the labels, the colors began to run and smear. Use your observations from this activity to explain what happened to the writing. 3. When paper chromatography is used as an analytical tool, the solute and solvent must move only in one direction. Explain why this controlled direction is necessary to calculate the R f. Chemical Bonds 31 Meeting Individual Needs 2 Date Name Date Enrichment The Crisscross Method Meeting Individual Needs The process of writing chemical formulas can be made easier by using oxidation numbers. Remember that the total charge on a compound must be zero. Remember also that oxidation numbers describe the number of electrons an atom or ion gains or loses when forming compounds. Atoms in the same group on the periodic table usually will have the same oxidation number. Use the periodic table to determine the oxidation numbers of atoms. Refer to your textbook for oxidation numbers of polyatomic ions. Example: Write the formula for barium chloride. Step 1: Determine the oxidation numbers for the two elements or ions. Because barium is in Group 2, its oxidation number is 2+. Elements in Group 2 tend to lose the two electrons in the outer energy level, leaving the ions with positive charges. Chloride is in Group 17, so its oxidation number is 1–. Elements in Group 17 have seven electrons in the outer energy level and tend to gain one electron. The ions are negative. Step 2: Write the chemical symbols in the correct order, with the metal ion first. Ba Cl Now, write the oxidation numbers as superscripts. For an ion with an oxidation number of 1+ or 1–, write only the sign and not the number. Ba2 Cl Next, crisscross the numbers only—not the signs this time, writing the oxidation number of one element as the subscript for the other. Don’t write the number 1 here either. Ba2 Cl Ba Cl2 Step 3: Determine whether the formula is in its simplest form. Reduce the subscripts to their simplest form by dividing by a common denominator. The formula for barium chloride is BaCl 2 , which cannot be further reduced. Step 4: Check the formula by calculating the total positive and total negative charges and confirming that the total charge on the compound is zero. Barium Chlorine Oxidation Number (+2) (–1) Subscript ✕ (1) = ✕ (2) = +2 –2 Directions: Use the crisscross method to write the chemical formulas for the compounds described below. Check that the total charge on each compound equals zero. 1. Write the correct chemical formula for a compound containing barium and oxygen. What is the name of this compound? 2. Write the formula for zinc iodide, a compound that is used as an antiseptic. 3. One of the uses of ammonium sulfate is in flameproofing fabrics and paper. Write the formula for ammonium sulfate. 32 Chemical Bonds Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. 3 Class Name Date Note-taking Worksheet Section 1 Class Chemical Bonds Stability in Bonding A. Some elements combine chemically and no longer have the same ___________________ they did before forming a compound. B. A(n) _________________________ is composed of symbols and subscripts indicating the C. Atoms form compounds when the compound is more _______________ than the separate atoms. 1. Noble gases are more __________________________ than other elements because they have a complete outer energy level. 2. Elements that do not have full outer energy levels are more stable in __________________. 3. Atoms can lose, gain, or ______________ electrons to get a stable outer energy level. 4. A(n) ______________________ is the force that holds atoms together in a compound. Section 2 Types of Bonds A. A(n) ____________ is a charged particle because it has more or fewer electrons than protons. Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. 1. When an atom ______________ an electron, it becomes a positively charged ion; a superscript indicates the charge. 2. When an atom ______________ an electron, it becomes a negatively charged ion. B. An ionic compound is held together by the ___________________—the force of attraction between opposite charges of the ions. 1. The result of this bond is a(n) ________________ compound. 2. The sum of the charges on the ions in a unit of the compound is _____________. C. __________________ are neutral particles formed as a result of sharing electrons. 1. A ______________________ is the force of attraction between atoms sharing electrons. 2. Atoms can form double or triple ______________ depending on whether they share two or three pairs of electrons. 3. Electrons shared in a molecule are held _____________________ to the atoms with the larger nucleus. Chemical Bonds 33 Meeting Individual Needs number of atoms of an element in a compound. Name Date Class Note-taking Worksheet (continued) 4. A(n) ______________ molecule has one end that is slightly negative and one end that is slightly positive although the overall molecule is neutral. 5. In a(n) _________________ molecule, electrons are shared equally. Section 3 Writing Formulas and Naming Compounds A. Chemists use ________________ from the periodic table to write formulas for compounds. B. ________________________—composed of two elements become stable 2. Use oxidation numbers and their least common multiples to write _________________. a. When writing formulas, remember that the compound is ________________. b. A formula must have the correct number of positive and negative ions so the charges ________________. 3. Use the name of the first element, the root name of the second element, and the suffix –ide to write the _____________ of a binary ionic compound. C. _______________________—positively or negatively charged, covalently bonded group of atoms 1. The compound contains ______________ or more elements. 2. To write names, write the name of the _________________ ion first; then write the name of the _________________ ion. 3. To write _________________, use the oxidation numbers, their least common multiple, and put parentheses around the polyatomic ion before adding a subscript. D. ________________—compound with water chemically attached to its ions E. Name binary covalent compounds by using _________________ to indicate how many atoms of each element are in the compound. 34 Chemical Bonds Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. Meeting Individual Needs 1. _________________________—how many electrons an atom has gained, lost, or shared to Name Date Chapter Review Class Chemical Bonds Part A. Vocabulary Review Directions: Complete the sentence by writing the correct terms in the blanks. 1. An atom that has gained or lost electrons is called a(n) ____________________. 2. An atom is ____________________ when its outer energy level is filled with electrons. 3. A(n) ____________________ tells what elements make up a compound and the ratios of the atoms of those elements. 4. A molecule that has a positive end and a negative end is a(n) ____________________ molecule. 5. A bond that forms between atoms when they share electrons is a(n) ____________________ bond. 6. A positive or negative number that is assigned to an element to show its combining ability in a compound is a(n) ____________________. 7. A compound that is composed of only two elements is a(n) ____________________. 8. A group of atoms with a positive or negative charge is a(n) ____________________. 9. A(n) ____________________ is a compound that has water chemically attached to its ions. a(n) ____________________. 11. Molecules that do not have oppositely charged ends are ____________________ molecules. 12. A(n) ____________________ is formed when atoms gain, lose, or share electrons. Part B. Concept Review Directions: Place a plus sign (+) beside each statement that agrees with what was said in your textbook. Place a minus sign (–) beside each statement that does not agree, and rewrite the statement so that it is correct. 1. Compounds have properties unlike those of their elements. 2. In a chemical formula, a subscript tells how many atoms of an element are in a unit of a compound. Chemical Bonds 37 Assessment Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. 10. The force of attraction between the opposite charges of the ions in an ionic compound is Name Date Class Chapter Review (continued) 3. A chemical bond occurs when atoms lose, gain, or share electrons. 4. Because each noble gas has an outer energy level that is completely filled with electrons, these elements form chemical bonds easily. 5. Compounds containing polyatomic ions can have both ionic and covalent bonds. 6. A covalent bond is the force of attraction between the opposite charges of the ions in an ionic compound. 7. Neutral particles formed as a result of covalent bonding are called molecules. Assessment 9. When writing the formula of a compound, the symbol of the element with the positive oxidation number comes first. 10. When cobalt chloride unites with water to form cobalt hexahydrate, its formula is written CoCl2 • 6H2O. 38 Chemical Bonds Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. 8. An element that loses electrons when bonding with other atoms has a negative oxidation number. Name 1 Date Section Focus Transparency Activity Class Picking Up the Pieces Transparency Activities 1. Where do the remaining pieces belong? How do you know? 2. How might a compound and its individual elements compare to a puzzle and its pieces? 44 Chemical Bonds Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. Jigsaw puzzles can have hundreds—even thousands—of pieces. To complete the puzzle, you need to infer how each piece fits together. Size, shape, and markings all give clues as to how the pieces should be placed to make a picture. Name 2 Date Section Focus Transparency Activity Class A Crystal Nature 1. Describe the appearance of the salt in the picture. 2. What happens to salt in water? How might you recover salt from ocean water? Transparency Activities Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. This picture shows salt crystals on the Dead Sea shore. When a salt crystal is pure, it is in the shape of a colorless cube. Impurities can make salt appear to be different colors, like white or gray. Table salt is a compound of sodium and chlorine. 3. How do people use salt? Chemical Bonds 45 Name 3 Date Section Focus Transparency Activity Class For Best Results, Add Water 1. How might construction be different in the desert compared to a rainy, temperate region? Transparency Activities 2. What would happen if a bag of dry concrete got a little damp? What if it got very wet? 3. When a new sidewalk is finally dry, where does the water go? 46 Chemical Bonds Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. Why are these workers trying to keep the concrete wet rather than letting it dry? Concrete doesn’t harden because it dries. It hardens by incorporating water into its molecular structure. If there’s not enough water, the concrete won’t harden properly, and it won’t be very durable. Beryllium 4 Be Lithium 3 Li Calcium 20 Ca Potassium 19 K 88 Ra 87 Fr Chemical Bonds 47 Transparency Activities Radium Francium Sodium 56 Ba 55 Cs Na Barium Cesium Chlorine Cl Rn Xe → 49 In Indium 31 Ga 81 Tl Thallium → 14 Si Silicon 6 C Carbon 4 5 Cl 84 Po Polonium 52 Te Tellurium 34 Se Selenium 16 S Sulfur 8 O Oxygen 2 Sodium chloride 83 Bi Bismuth 51 Sb Antimony 33 As Arsenic 15 P Phosphorus 7 N Nitrogen Na 82 Pb Lead 50 Sn Tin 32 Ge Gallium Germanium 13 Al Aluminum 5 B Boron 3 85 At Astatine 53 I Iodine 35 Br Bromine 17 Cl Chlorine 9 F Fluorine 1 86 Rn Radon 54 Xe Xenon 36 Kr Krypton 18 Ar Argon 10 Ne Neon 2 He Helium Date 38 Sr 37 Rb Ar Ne 0 Teaching Transparency Activity Rubidium Strontium 12 Mg 11 Na Sodium Magnesium 2 1 H Hydrogen Kr 3 1 He Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. Name Class Common Oxidation Numbers of Selected Groups Name Teaching Transparency Activity Date Class (continued) 1. When does an ionic bond form between elements? 2. What is a covalent bond? 3. The formula for baking soda is NaHCO3. Name the elements in baking soda. 4. How many pairs of electrons are shared when hydrogen and oxygen unite to form a molecule of water? 6. Write the formula for barium (Ba2+) chlorate (ClO3–). 7. Name two pieces of information you can get from a dot diagram. Transparency Activities 48 Chemical Bonds Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. 5. Using the oxidation numbers given on the transparency, write the formula for calcium chloride, a compound of calcium and chlorine. Name Date Assessment Transparency Activity Class Chemical Bonds Directions: Carefully review the tables and answer the following questions. Group B Water H 2O Epsom salts Mg(OH)2 Carbon dioxide CO2 Sugar C12H22O11 Ammonia NH3 Lye Salt NaCl Baking soda Methane CH4 Vinegar NaOH NaHCO3 C 2H 4O 2 1. The compounds in Group A are different from the compounds in Group B because only the compounds in Group A ___. A are gases at room temperature B are used in preparing food C contain a metal and a nonmetal D contain only two different elements 2. According to the chemical formula for lye, all of the following elements are found in a lye molecule EXCEPT ___. F hydrogen H oxygen G nitrogen J sodium 3. According to the information contained in the tables, which compound has a total number of atoms greater than 10? A Baking soda C Sugar B Methane D Vinegar Transparency Activities Copyright © Glencoe/McGraw-Hill, a division of the McGraw-Hill Companies, Inc. Group A 4. According to the tables, which compound has the LEAST number of total atoms? F Ammonia H Salt G Carbon dioxide J Water Chemical Bonds 49