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Counting Atoms Chapter 3.3 Take out your PT, you’ll need it Quick Review: Structure of atom • Where are the protons, neutrons, electrons located? • Which 2 subatomic particles make up the majority of the mass of the atom? • Which subatomic particle makes up the majority of the volume of the atom? • What is the charge of the nucleus? • What is the overall charge of an atom? • All atoms of the same element must have the same number of protons, but not neutrons • Atomic number (Z) is # protons in an element • Atomic # identifies element • Atoms are neutral: # protons = # electrons • Atomic # = # protons = # electrons • Isotopes • Atoms of the same element that have different masses (different # neutrons) • Mass number= # protons + # neutrons • ALWAYS A WHOLE NUMBER • Identifying isotopes • Hyphen notation • Nuclear symbol How many protons, neutrons, and electrons are there in an atom of chlorine-37? Atomic mass • Relative atomic mass- based on mass of carbon-12 atom • One atomic mass unit, u, is 1/12 mass of carbon12 atom • Average atomic mass is weighted average of naturally occurring isotopes of an element • Number of isotopes • Atomic Mass of each isotope • Relative abundance (usually expressed as %) • This is the mass expressed on the PT Calculating average atomic mass • Need to know: • Mass of isotope • Relative abundance (%) of each isotope • To calculate weighted average: 1. Change relative abundance to decimal (divide by 100 or move decimal 2 places to the LEFT) 2. Multiply abundance as decimal (result from #1) by atomic mass of isotope 3. Add together results from #2 4. Include units (u) • DO NOT DIVIDE AT THE END! IT IS ALREADY A WEIGHTED AVERAGE (%) SO WE DO NOT NEED TO FIND AVERAGE AT THE END There are 2 naturally occurring isotopes of hydrogen. It consists of 99.9885% Hydrogen-1, with an atomic mass of 1.00785u and 0.0115% Hydrogen-2, with an atomic mass of 2.014102u. What is the average atomic mass of Hydrogen? • Change % to decimal • 99.9885% becomes 0.999885 • 0.0115% becomes 0.000115 • Multiply decimal by atomic mass • 0.999885 x 1.00785u = 1.0077091u • 0.000115 x 2.014102u = 0.00023162173u • Add together • 1.0077091u + 0.00023162173u = 1.007940722u • In general, average atomic masses are rounded to 2 decimal places so our final answer would be 1.01u