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Early Ideas of Atoms CK12 Editor Say Thanks to the Authors Click http://www.ck12.org/saythanks (No sign in required) To access a customizable version of this book, as well as other interactive content, visit www.ck12.org CK-12 Foundation is a non-profit organization with a mission to reduce the cost of textbook materials for the K-12 market both in the U.S. and worldwide. Using an open-content, web-based collaborative model termed the FlexBook®, CK-12 intends to pioneer the generation and distribution of high-quality educational content that will serve both as core text as well as provide an adaptive environment for learning, powered through the FlexBook Platform®. Copyright © 2012 CK-12 Foundation, www.ck12.org The names “CK-12” and “CK12” and associated logos and the terms “FlexBook®” and “FlexBook Platform®” (collectively “CK-12 Marks”) are trademarks and service marks of CK-12 Foundation and are protected by federal, state, and international laws. Any form of reproduction of this book in any format or medium, in whole or in sections must include the referral attribution link http://www.ck12.org/saythanks (placed in a visible location) in addition to the following terms. Except as otherwise noted, all CK-12 Content (including CK-12 Curriculum Material) is made available to Users in accordance with the Creative Commons Attribution/NonCommercial/Share Alike 3.0 Unported (CC BY-NC-SA) License (http://creativecommons.org/licenses/by-nc-sa/3.0/), as amended and updated by Creative Commons from time to time (the “CC License”), which is incorporated herein by this reference. Complete terms can be found at http://www.ck12.org/terms. Printed: September 18, 2012 AUTHOR CK12 Editor www.ck12.org C ONCEPT Concept 1. Early Ideas of Atoms 1 Early Ideas of Atoms Lesson Objectives • • • • Define matter and explain how it is composed of building blocks known as atoms. Give a short history of the concept of the atom. Describe the contributions of Democritus and Dalton to atomic theory. Summarize Dalton’s atomic theory and explain its historical development. Introduction Matter is anything that has mass and volume. The entire universe is composed of matter, which is in turn composed of atoms. An atom is the basic building block of all matter. All modern scientists accept the concept of the atom, and perhaps you may have already learned about atoms elsewhere. However, when the concept of the atom was first proposed about 2,500 years ago, ancient philosophers laughed at the idea. After all, how can we be convinced that something we cannot see even exists? We will spend some time considering the evidence (observations) that convinced scientists of the existence of atoms. Democritus and the Greek Philosophers Before we discuss the experiments and evidence that have, over the years, convinced scientists that matter is made up of atoms, it’s only fair to give credit to the man who proposed the existence of atoms in the first place. About 2,500 years ago, early Greek philosophers believed the entire universe was a single, huge, entity. In other words, “everything was one.” They believed that all objects, all matter, and all substances were connected as a single, big, unchangeable “thing.” One of the first people to propose the existence of atoms was a man known as Democritus (Figure 1.1). Unlike the other Greek philosophers, he suggested that atomos – tiny, indivisible, solid objects - make up all matter in the universe. Democritus then reasoned that changes occur when the many atomos in an object were reconnected or recombined in different ways. Democritus even extended his theory by suggesting that there were different varieties of atomos with different shapes, sizes, and masses. He thought, however, that shape, size, and mass were the only properties differentiating the different types of atomos. According to Democritus, other characteristics, like color and taste, did not reflect properties of the atomos themselves, but rather, resulted from the different ways in which the atomos were combined and connected to one another. Most of the other Greek philosophers believed that, above all else, our understanding of the world should rely on logic. In fact, they argued that the world couldn’t be understood using our senses at all because our senses could deceive us. Therefore, instead of relying on observation, Greek philosophers tried to understand the world using their minds and, more specifically, the power of reason. You may recall from the "Introduction to Chemistry" chapter that Aristotle concluded in a logical manner that men had more teeth than women without ever checking in anyone’s mouth! As a result, the Greek philosophers may have missed or rejected a lot of discoveries that they could have made otherwise because they did not perform any experiments. For this reason, Democritus’s theory was dismissed by most of his fellow Greek philosophers. It would take over two millennia before the theory of atomos (or atoms, as they’re known today) was fully appreciated. 1 www.ck12.org FIGURE 1.1 Democritus was known as the “Laughing Philosopher.” It’s a good thing he liked to laugh, because most other philosophers were laughing at his theories. Dalton’s Atomic Theory Let’s begin our discussion of the atomic theory by considering a simple but important experiment that suggested matter might be made up of atoms. In the late 1700s and early 1800s, scientists began noticing that when certain substances, like hydrogen and oxygen, were combined to produce a new substance, like water, the reactants (hydrogen and oxygen) always reacted in the same proportions by mass. In other words, if 1 gram of hydrogen reacted with 8 grams of oxygen, then 2 grams of hydrogen would react with 16 grams of oxygen, and 3 grams of hydrogen would react with 24 grams of oxygen. Strangely, the observation that hydrogen and oxygen always reacted in the same proportions by mass wasn’t unique to hydrogen and oxygen. In fact, it turned out that for each chemical reaction, the reactants react in the same proportions by mass. Take, for another example, nitrogen and hydrogen, which can react to produce ammonia. In chemical reactions, 1 gram of hydrogen will react with 4.7 grams of nitrogen, and 2 grams of hydrogen will react with 9.4 grams of nitrogen. Can you guess how much nitrogen would react with 3 grams of hydrogen? Scientists studied reaction after reaction, but every time the result was the same. The reactants for a given chemical reaction always reacted in the same proportions. At the same time that scientists were recognizing this pattern, a man named John Dalton (pictured in Figure 1.3) was experimenting with several reactions in which the reactant elements formed more than one type of product, depending on the experimental conditions he used. One common reaction that he studied was the reaction between carbon and oxygen. When carbon and oxygen react, they produce two different substances – we’ll call these substances A and B. It turned out that, given the same amount of carbon, forming B always required exactly twice as much oxygen as forming A. In other words, if you can make A with 3 grams of carbon and 4 grams of oxygen, B 2 www.ck12.org Concept 1. Early Ideas of Atoms FIGURE 1.2 Early Greek philosophers tried to understand the nature of the world through reason and logic, but not through experiment and observation. can be made with the same 3 grams of carbon, but with 8 grams oxygen instead. Dalton asked himself – why does B require twice as many oxygen as A? Why not 1.21 times as many oxygen, or 0.95 times as many oxygen? Why a whole number like 2? The situation became even stranger when Dalton tried similar experiments with other substances. For example, when he reacted nitrogen and oxygen, Dalton discovered that he could make three different substances – we’ll call them C, D, and E. As it turned out, for the same amount of nitrogen, D always required twice as many oxygen as C did. Similarly, E always required exactly four times as many oxygen as C did. Once again, Dalton noticed that small whole numbers (2 and 4) seemed to be the rule. Dalton thought about his results and tried to find some theory that would explain his findings, as well as satisfy the law of conservation of Mass (mass is neither created nor destroyed). One way to explain the relationships that Dalton and others had observed was to suggest that materials like nitrogen, carbon, and oxygen were composed of small, indivisible quantities which Dalton called “atoms” (in reference to Democritus’s original idea). Dalton used this idea to generate what is now known as Dalton’s atomic theory. Dalton’s atomic theory: 3 www.ck12.org FIGURE 1.3 Unlike the Greek philosophers, John Dalton believed in both logical thinking and experimentation. a. Matter is made of tiny particles called atoms. b. Atoms are indivisible. During a chemical reaction, atoms are rearranged, but they do not break apart, nor are they created or destroyed. c. All atoms of a given element, or type, are identical in mass and other properties. d. The atoms of different elements differ in mass and other properties. e. Atoms of one element can combine with atoms of another element to form compounds – new, complex particles. In a given compound, however, the different types of atoms are always present in the same relative numbers. Lesson Summary • 2,500 years ago, Democritus suggested that all matter in the universe was made up of tiny, indivisible, solid objects he called atomos. • Other Greek philosophers disliked Democritus’s atomos theory because they felt it was illogical. • Dalton used observations about the ratios reactants combine in and the law of conservation of mass to propose his atomic theory. • Dalton’s atomic theory states: 4 www.ck12.org Concept 1. Early Ideas of Atoms Further Reading / Supplemental Links • To see a video documenting the early history of the concept of the atom, go to the Utah Education Network. Go to the k-12 library. Search for “history of the atom”. Watch part 01. (username to pioneer: pioneer; password: time) – http://www.uen.org/dms/ • To learn more about the history of the concept of the atom, read the Vision Learning article "From Democritus to Dalton." – http://visionlearning.com/library/module_viewer.php?c3=&mid=49&l= Review Questions 1. It turns out that a few of the ideas in Dalton’s atomic theory aren’t entirely correct. Are inaccurate theories an indication that science is a waste of time? 1. Match the person, or group of people, with their role in the development of chemistry. (a) early Greek philosophers (i) suggested that all matter was made up of tiny, indivisible objects (b) John Dalton (ii) relied on logic to understand the world around them (c) Democritus (iii) proposed the first scientific theory relating chemical changes to the structure, properties, and 1. Which of the following is notpart of Dalton’s Atomic Theory? a. b. c. d. Matter is made of tiny particles called atoms. During a chemical reaction, atoms are rearranged. During a nuclear reaction, atoms are split apart. All atoms of a specific element are the same. 2. What is the greatest advantage Dalton’s atomic theory had over Democritus’s? 3. Choose one of the commonly believed topics from the list below (or choose your own): air, genes, global warming, gravity, trust, or UV rays. If you had to make a case proving that this concept really exists, how would you prove it? a. b. c. d. Which topic did you pick? Can you SEE it? Explain. What observations can you make about this topic? What effects do you see because of this? There are other things we never see with our own two eyes, yet we still know things about them. List some examples here. How do we know things really exist like we believe they do? Matter Anything that has mass and volume. Atom The basic building block of all matter. Atomos Democritus’s word for the tiny, indivisible, solid objects that he believed made up all matter in the universe. Dalton’s atomic theory The first scientific theory to relate chemical changes to the structure, properties, and behavior of the atom. 5