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Energy • There are things that ________________________have mass and volume. • These things fall into a category we call __________________________. • Energy is anything that has the capacity to do_______________________________. • Although chemistry is the study of matter, matter is _________________________by energy. • It can cause physical and/or chemical changes in matter. Law of Conservation of Energy • “Energy can neither be ________________nor______________________.” The ___________________amount of energy in the universe is constant. There is no process that can increase or decrease that amount. • However, we can _____________________energy from one place in the universe to another, and we can ________________________its form. Matter Possesses Energy • When a piece of matter possesses energy, it can give _______________of it to another object. It can do ___________________on the other object. • All chemical and physical changes result in the matter changing_______________________. Kinds of Energy--Kinetic and Potential • Potential energy is energy that is_____________________________. Water flows because gravity pulls it downstream. However, the dam won’t allow it to move, so it has to store that energy. • Kinetic energy is energy of ________________, or energy that is being _________________________________from one object to another. When the water flows over the dam, some of its potential energy is ________________________________to kinetic energy of motion. Some Forms of Energy • • Electrical Kinetic energy associated with the ____________________________________. • Heat or Thermal Energy Kinetic energy associated with ____________________________. • Light or Radiant Energy Kinetic energy associated with _____________________in an atom. • Nuclear Potential energy in the________________________________ of atoms. Chemical Potential energy in the ______________of atoms or because of their____________. Converting Forms of Energy • When water flows over the dam, some of its potential energy is __________________to kinetic energy. Some of the energy is stored in the water because it is at a higher elevation than the surroundings. • The __________________________________of the water is kinetic energy. • Along the way, some of that energy can be used to push a turbine to generate______________. Electricity is one form of_____________________________________. The electricity can then be used in your home. For example, you can use it to heat cake batter you mixed, causing it to change chemically and _____________________some of the energy in the new ____________________________that are made. Using Energy • We use energy to accomplish all kinds of processes, but according to the ______________________________we don’t really use it up! • When we use energy we are __________________it from one ________________to another. For example, converting the ________________________energy in gasoline into ________________________energy to make your car move. Total______________ Total________________ “Losing” Energy • If a process was_____________________, we could theoretically get all the energy transformed into a_____________________________. • Unfortunately we cannot get a 100% efficient process. • The energy ________________in the process is energy transformed into a form we__________________________________. • Only about _____________of the energy from the fuel you put in your tank gets used to move your car down the road or run useful accessories, such as air conditioning. The rest of the energy is ________to engine and driveline inefficiencies and idling. Therefore, the potential to improve fuel efficiency with advanced technologies is enormous. There’s No Such Thing as a Free Ride • When you drive your car, some of the ________________________energy stored in the gasoline is released. • Most of the energy released in the combustion of gasoline is transformed into sound or heat energy that adds energy to the_________________ rather than move your car down the road. Units of Energy • Calorie (cal) is the amount of energy needed to raise _________ gram of water by ________°C. kcal = energy needed to raise 1000 g of water 1 °C. food calories = kcals. Units of Energy Energy Conversion Factors: 1 calorie (cal) = ______________joules (J) 1 Calorie (C) = _______________ calorie (cal) 1 kilowatt-hour (kWh) = ______________ joules (J) Energy Use Unit Energy Energy Required Required to to Raise Light 100-W Temperature of 1 g Bulb for 1 of Water by 1°C Hour 5 joule (J) 4.18 3.6 x 10 calorie (cal) 1.00 8.60 x 10 Calorie (Cal) 1.00 x 10 kWh 1.1 x 10 -3 -6 4 Energy Used by Average U.S. Citizen in 1 Day 9.0 x 10 2.2 x 10 8 8 5 86.0 2.2 x 10 0.100 2.50 x 10 2 Solve: 2567 cal were used to heat a container of water how many Joules is this? Given: Find: Conversions Factors: Solve & Check: Solve: 569.0 J of energy were added to a piece of iron when it was heated in a fire how many calories is this? Given: Find: Conversions Factors: Solve & Check: Solve: 250.0 kWh were used in a light bulb, how many joules is this? Given: Conversions Factors: Solve & Check: Find: Solve: A light stick uses 55500 cal of energy how many kcal is this? Given: Find: Conversions Factors: Solve & Check: Solve: 25.0 kJ of heat were added to a piece of gold how many joules is this? Given: Find: Conversions Factors: Solve & Check: Solve: A candy bar contains 225 Cal of nutritional energy. How many joules does it contain? Given: Find: Conversions Factors: Solve & Check: Solve: Convert 589 Cal to Joules Given: Find: Conversions Factors: Solve & Check: Chemical Potential Energy • The amount of energy _____________________in a material is its chemical potential energy. • The stored energy arises mainly from the attachments ________________________in the molecules and the attractive forces_____________________________. • The stored energy arises from the attractive forces between molecules. • When materials undergo a physical change, the attractions ______________ molecules change as their____________ changes, resulting in a change in the amount of chemical potential energy. • When materials undergo a physical change, the attractions between molecules change as their position changes, resulting in a change in the amount of __________________________energy. Chemical Potential Energy continued The stored energy also arises from the attachments between __________________ in the molecules When materials undergo a chemical change, the _____________________of the molecules change, resulting in a change in the amount of chemical potential energy Converting Forms of Energy Chemical energy is stored in fuels like methane (natural gas) and gasoline. Let's see how methane combining with oxygen (combustion) gives up this type of potential energy. __________________collides with ___________________at high speeds (caused by flame or spark), there's a rearrangement of the atoms. Two oxygen atoms will combine with four hydrogen (H) atoms to form _______________________ (H2O). The other two oxygen atoms will combine with methane's carbon atom to form carbon dioxide. Why does this give off energy? Below is the same diagram as above, except all of the protons and electrons that hydrogen, carbon, and oxygen have are shown. Hydrogen has _______proton and ________electron. Carbon has ________ protons and ________ electrons. Oxygen has _______protons and ________ electrons. Remember the electrons are all being pulled on by the protons (kind of like Earth pulling on objects on the Earth). The reason energy is released during rearrangement is that the electrons are ____________________to the protons than they were originally. When the electron on the hydrogen atom goes from farther away to closer, energy is _________________. Same thing is happening here except several electrons are involved. This "moving" closer to the nucleus means that some of the potential energy gets ________________________ to light. The light is the visible light you see in the picture plus a great deal of infrared light, which is the _____________________________you feel radiating from the flame Energy Changes & Chemical Reactions • Chemical reactions happen most readily when energy is _______________during the reaction. • Molecules with ________________of chemical potential energy are__________________than ones with __________________________ chemical potential energy. • Energy will be __________________________when the reactants have _________________ chemical potential energy than the products. Exothermic Processes • When a change results in the release of energy it is called an __________________ process. • An exothermic chemical reaction occurs when the reactants have __________________ chemical potential energy than the products. • The excess energy is released into the surrounding materials, ______________ energy to them. Often the surrounding materials get hotter from the energy released by the reaction. Endothermic Processes • When a change requires the absorption of energy it is called an___________________ process. • An endothermic chemical reaction occurs when the products have ________________chemical potential energy than the reactants. • The required energy is ____________ from the surrounding materials, taking energy from them. Often the surrounding materials get colder due to the energy being removed by the reaction. _____________________ Temperature The average___________________________of an object!! Temperature Scales • ____________________scale, °F. Used in the U.S. • ___________________scale, °C. Used in all other countries. A Celsius degree is 1.8 times larger than a Fahrenheit degree. ____________________scale, K. • Absolute scale. Temperature Scales 100°C 373 K 212°F Boiling point water 25°C 298 K 75°F Room temp 0°C 273 K 32°F -38.9°C 234.1 K -38°F Melting point ice Boiling point mercury -183°C 90 K -297°F -269°C -273°C 4 K 0 K -452°F Celsius Kelvin Boiling point oxygen BP helium -459 °F Absolute zero Fahrenheit Temperature Scales • The Fahrenheit temperature scale used as its two reference points the freezing point of concentrated _______________ (0 °F) and average _________________temperature (96 °F). More accurate measure now sets average body temperature at 98.6 °F. • Room temperature is about ____________________°F. • The Celsius temperature scale used as its two reference points the freezing point of _______________________(0 °C) and boiling point of _______________________ (100 °C). More reproducible standards. • Most commonly used in science. Room temperature is about ________________________°C. The Kelvin Temperature Scale • Both the Celsius and Fahrenheit scales have ___________________________numbers. Yet, real physical things are always positive amounts! • The Kelvin scale is an absolute scale, meaning it measures the ___________________ temperature of an object. • 0 K is called_______________________. It is too cold for matter to exist because all molecular motion would_______________________________. 0 K = -273 °C = -459 °F. Absolute zero is a _______________value obtained by following patterns mathematically Kelvin vs. Celsius • The __________of a “degree” on the Kelvin scale is the _____________as on the Celsius scale. Although technically, we don’t call the divisions on the Kelvin scale degrees; we call them_____________________________ • When converting between kelvins and °C, remember that the kelvin temperature is always the ____________________number and always _________________________! K C 273 Solve: Convert –25 °C to Kelvins Energy and the Temperature of Matter • The amount the ___________________of an object increases depends on the amount of ____________________ added (__________). If you_________ the added heat energy the temperature will increase _______as much. • The amount the ________________of an object increases also depends on its_____________. If you _______________the mass, it will take ______________as much heat energy to raise the temperature the ____________________ amount. Heat Capacity • Heat capacity is the _______________of heat a substance must absorb to______________ its temperature by__________________. cal/°C or J/°C. Metals have ____________heat capacities; insulators have __________heat capacities. • Specific heat = heat capacity of __________________________of the substance. cal/g°C or J/g°C. Water’s specific heat = __________________________for liquid. Or___________________________. It is less for ice and steam. Specific Heat Capacity • Specific heat is the amount of _______________required to raise the temperature of _________________of a substance by________________________. • The ___________________a material’s specific heat is, the_______________ energy it takes to______________________ its temperature a given amount. • Like density, specific heat is a _____________________________of the type of matter. It doesn’t matter how much material you have. It can be used to _________________________the type of matter. • Water’s _____________________specific heat is the reason it is such a good cooling agent. It absorbs ___________________of heat for a relatively__________________ mass. • The specific heat of water is 1 calorie per 1 gram per 1 degree Celsius Fill in info on slide_____________________________________________________________ Joule = The energy used by 1 watt for 1 second What is the distinction between heat capacity and specific heat capacity. • Heat capacity is the quantity of heat required to change an _____________temperature by 1o C. • The heat capacity of any particular object _______________________________of that object (as well as with the type of material in that object). • The heat capacity of a steel girder is ________________ than the heat capacity of a steel nail. • Specific heat capacity ________________________with the mass of the object, but rather, ____________________________________________of the material in the object. • Specific heat capacity is the quantity of heat required to raise the temperature _______________________of a substance by 1oC. • The specific heat capacities of the steel in the steel girder and the steel in the steel nail are ________________________(assuming the two steels are of the same composition). • Specific heat capacity is a property of a particular ___________________; heat capacity is a property of a particular______________________________. Specific Heat How ______________heats up or cools down is the ________________for all other materials. There is usually an interest to how metals heat up. However, all materials heat up _____________. 1 calorie is defined as the amount of _______________needed to raise _____________of water __________________Celsius 1 kg of water would take 1,000 calories for each degree. Our 700C increase would take 1,000 x 70 = 70,000 calories. The same mass of different materials store different amounts of heat energy. Water takes about _________________________to heat than aluminum, meaning it stores about _____________________________ calories. The same mass of different materials store different amounts of heat energy. Water takes about ___________________________to heat than gold, meaning it stores about _____________________________________at the same temperature!!! Specific Heat Capacities Substance Specific Heat J/g°C Aluminum 0.903 Carbon (dia) 0.508 Carbon (gra) 0.708 Copper 0.385 Gold 0.128 Iron 0.449 Lead 0.128 Silver 0.235 Ethanol 2.42 Water (l) 4.184 Water (s) 2.03 Water (g) 2.02 Heat Gain or Loss by an Object The amount of heat energy ____________________by an object depends on__________ factors: • _______________________material there is • _______________________the material is • _______________________ the temperature changed. • Amount of Heat = Mass x Specific Heat Capacity x Temperature Change q = m x C x DT Example 3.10: • Given: Find: Gallium is a solid metal at room temperature, but melts at 29.9 °C. If you hold gallium in your hand, it melts from body heat. How much heat must 2.5 g of gallium absorb from your hand to raise its temperature from 25.0 °C to 29.9 °C? The heat capacity of gallium is 0.372 J/g°C. Equation: Solution: Sig figs & round: Practice—Calculate the Amount of Heat Released When 7.40 g of Water Cools from 49° to 29 °C Given: Find: Equation: Solution: Sig figs & round: 52.) If 72.4 kJ of heat is applied to a 952 g block of metal, the temperature of the metal increases by 10.7oC. Calculate the specific heat capacity of the metal in J/goC. Given: Find: Equation: Solution: Sig figs & round: 53.) Calculate the energy required in joules and calories to heat 29.2 g of aluminum from 27.2 oC to 41.5 o C. See data table 3.2 Given: Find: Equation: Solution: Sig figs & round: 54.) A particular sample of iron requires 562 J to raise its temperature from 25.0oC to 50.0oC. What must be the mass of the sample of iron? See table 3.2 Given: Find: Equation: Solution: Sig figs & round: 55.) If 100. J of heat energy is applied to 25.0 g sample of mercury, by how many degrees will the temperature of the mercury sample increase? Given: Find: Equation: Solution: Sig figs & round: A 35.0 gram lead ball at 25.0oC was heated with 40.5 joules of heat. What is the final temperature of the lead? Use table for Sp. Heat capacity. Given: Find: Equation: Solution: Sig figs & round: Winter Survival and a Safe Source of Heat for Field Operations Water: Pros and Cons: List ______________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ Metal: Pros and Cons: List ___________________________________________________________________________________________________ Rocks: Pros and Cons: List _______________________________________________________ ___________________________________________________________________________ EXTRA CREDIT: It’s February and you want to heat up your pool. It is currently 50oF (10oC) and you want it raised to 80oF (27oC) Using an electric heater, how much will it cost if 1 kilowatt-hour is 10 cents? The pool is 7.0 meters long, 5.0 meters wide and 2.0 meters deep. A. What’s the volume in cubic meters? ______ B. What is the volume in cubic centimeters?___________ C. What is the total grams of the water? ____________