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Chemistry (offered by the Department of Chemistry) Telephone number 012 429 8004 General Information 1 The use of a pocket calculator is permissible in the examination for ALL Chemistry modules. Note that students who have NOT passed Physical Science at Matriculation level must pass CHE111 and 112 BEFORE they register for any other modules in Chemistry. Students who register for modules in Chemistry are referred to 5 in connection with PRACTICAL WORK. Mathematics (MAT111, 112 (or 101 and 102)) forms part of Chemistry as a major subject. You are advised to register for these modules in your first year of registration. A BA student who has passed the three CHL-modules on first level does NOT qualify for direct admission to modules in Chemistry on second-year level for the BSc degree. There are no further modules in Chemistry for BA students. To qualify for admission to studies for Honours BSc degree in Chemistry students must: (a) hold a Bachelor’s degree or an equivalent qualification (b) have passed CHE311/321, 312/322, 313/323, 314/324 or CHE301–304 or Chemistry III or an equivalent course with an average of 60% or more within the past five years (c) have passed MAT112 (or 101 and 102), MAT113 or an equivalent course Credit for a BSc degree is granted for: (i) either CHE101 or CHE111 if CHE111 was passed with at least 65% prior to 2002 (ii) either CHE102 or CHE112 if CHE112 was passed with at least 65% prior to 2002 Credit for a BA degree is granted for: (i) either CHE101 or CHL101 (or CHE111 or CHL111 prior to 2002) (ii) either CHE102 or CHL102 (or CHE112 or CHL112 prior to 2002) Introduction 2 CHEMISTRY MODULES: CHE111 AND CHE112 These two modules are intended for students who wish to study Chemistry but have (a) NOT passed Physical Science at Matriculation level; or (b) passed Physical Science at Matriculation level several years ago or who obtained poor results for it and who feel that their knowledge of Chemistry is inadequate for CHE101–104. or (c) NOT previously studied Physical Science. 3 Chemistry as a Major Subject For students who intend making a career in Chemistry, the most appropriate subjects from which the other four third-level modules should be selected are Biochemistry, Computer Science, Mathematics, Microbiology, Physics and/or Statistics. Compulsory modules for a major subject combination: First level: CHE101 (or at least 65% in CHE111 prior to 2002), 102 (or at least 65% in CHE112 prior to 2002), 103, 104, MAT111, 112 (or 101 and 102) Second level: CHE211, 212, 213, 214, 221, 222, 223, 224 (or 201, 202, 203, 204) Third level: CHE311, 312, 313, 314, 321, 322, 323, 324 (or 301, 302, 303, 304) 4 Syllabus NB All modules in this subject are offered as YEAR MODULES. FIRST-LEVEL MODULES CHE101N General chemistry A* Prerequisite: Mathematics as in Sc1(1)(b) in Part 7 of the Calendar and Physical Science at Matriculation level (or CHE111 and 112) Advice: MAT111, 112 (or 101 and 102) should be taken together with this module if Chemistry is selected as a major subject. Purpose: to enable students to gain insight into the electronic structure of atoms and apply it to the periodic table, chemical bonding, chemistry of the main group elements, nuclear chemistry and the properties of gases, liquids, solids and solutions. CHE102P General chemistry B* Prerequisite: Mathematics as in Sc1(1)(b) in Part 7 of the Calendar and Physical Science at Matriculation level (or CHE111 and 112) Advice: MAT111, 112 (or 101 and 102) should be taken together with this module if Chemistry is selected as a major subject. 12 Purpose: to enable students to demonstrate an understanding of thermochemistry, the physical behaviour of gases, liquids and solids, chemical equilibria, rates of reaction, acids and bases, redox reactions, chemical thermodynamics. CHE103Q Organic chemistry (Use of molecular models in examination is permissible)* Prerequisite: Mathematics as in Sc1(1)(b) in Part 7 of the Calendar and Physical Science at Matriculation level (or CHE111 and 112) Advice: MAT111, 112 (or 101 and 102) should be taken together with this module if Chemistry is selected as a major subject. Purpose: to enable students to demonstrate an understanding of organic chemistry concepts with reference to the nature and behaviour of hydrocarbons, alkyl halides, alcohols, ethers, aldehydes, ketones, carboxylic acids and introductory stereochemistry. CHE104R Chemistry practical Prerequisite: Mathematics as in Sc1(1)(b) in Part 7 of the Calendar and Physical Science at Matriculation level (or CHE111 and 112) Co-requisite: CHE101, 102, 103 Purpose: to help students develop laboratory skills and techniques associated with some of the theoretical concepts covered in modules CHE101, 102 and 103 (general chemistry and organic chemistry modules). CHE111Q Introductory chemistry A* Co-requisite: CHE112 Purpose: to teach basic chemical vocabulary, skills and concepts to students with little or no background in chemistry. To enable the student to gain insight in the particulate nature of matter, be able to solve stoichiometric problems, demonstrate an understanding of the periodicity of elements, the atomic theory and thermochemistry. CHE112R Introductory chemistry B* Co-requisite: CHE111 Purpose: to help students with little or no background in chemistry to gain insight into the principles and theories in reaction kinetics, chemical equilibrium of reactions and basic organic chemistry with emphasis on the development of a systematic approach to the problem solving in these areas. SECOND-LEVEL MODULES CHE211T Inorganic chemistry* Prerequisite: CHE101 (or at least 65% in CHE111 prior to 2002), 102 (or at least 65% in CHE112 prior to 2002), 103, 104 Co-requisite: CHE221 Purpose: to enable students to demonstrate their understanding of chemical bonding; ionic solids; solvents, solutions, acids and bases; introduction to co-ordination chemistry and transition metals. CHE221V Practical work Co-requisite: CHE211 Purpose: the acquisition and demonstration of laboratory skills and techniques associated with the theoretical concepts covered in module CHE211. CHE212U Physical chemistry* Prerequisite: CHE101 (or at least 65% in CHE111 prior to 2002), 102 (or at least 65% in CHE112 prior to 2002), 103 104, MAT111, 112 (or 101 and 102) Co-requisite: CHE222 Purpose: to enable students to demonstrate their understanding of the laws of thermodynamics and changes of state. CHE222W Practical work Co-requisite: CHE212 Purpose: the acquisition and demonstration of laboratory skills and techniques associated with the theoretical concepts covered in module CHE212. CHE213V Organic chemistry (Use of molecular models in examination is permissible)* Prerequisite: CHE101 (or at least 65% in CHE111 prior to 2002), 102 (or at least 65% in CHE112 prior to 2002), 103, 104 Co-requisite: CHE223 Purpose: to enable students to gain insight into dienes, aromaticity, electrophilic aromatic substitution, benzene, arenes, aldehydes, ketones, carboxylic acids and their functional derivatives, ethers and epoxides, amines, phenols and aryl halides. CHE223X Practical work Co-requisite: CHE213 Purpose: the acquisition and demonstration of laboratory skills and techniques associated with the theoretical concepts covered in module CHE213. CHE214W Analytical chemistry* Prerequisite: CHE101 (or at least 65% in CHE111 prior to 2002), 102 (or at least 65% in CHE112 prior to 2002), 103, 104 Co-requisite: CHE224 Purpose: to enable students to gain insight into statistical treatment of data, titrimetry, gravimetry, potentiometry and coulometry. CHE224Y Practical work Co-requisite: CHE214 Purpose: the acquisition and demonstration of laboratory skills and techniques associated with the theoretical concepts covered in module CHE214. THIRD-LEVEL MODULES CHE311W Inorganic chemistry* Prerequisite: CHE211, 221 (or 201) Co-requisite: CHE321 Advice: A pass in at least TWO other CHE second-level modules. Purpose: to enable students to gain insight into spectroscopy, advanced co-ordination chemistry, organometallic chemistry and bioinorganic chemistry. CHE321Y Practical work Co-requisite: CHE311 13 Purpose: the acquisition and demonstration of laboratory skills and techniques associated with the theoretical concepts covered in module CHE311. CHE312X Physical chemistry* Prerequisite: CHE212, 222 (or 202) Co-requisite: CHE322 Advice: A pass in at least TWO other CHE second-level modules. Purpose: to enable students to gain insight into changes of state, equilibria, electrochemistry, kinetic theory of gases, transport and diffusion and molecular reaction dynamics. CHE3223 Practical work Co-requisite: CHE312 Purpose: the acquisition and demonstration of laboratory skills and techniques associated with the theoretical concepts covered in module CHE312. CHE313Y Organic chemistry (Use of molecular models in examination is permissible)* Prerequisite: CHE213, 223 (or 203) Co-requisite: CHE323 Advice: A pass in at least TWO other CHE second-level modules. Purpose: to enable students to gain insight into and demonstrate an understanding of stereochemistry and conformational analysis, reaction mechanisms, applications of spectroscopic methods, carbanions, polyfunctional compounds, orbital symmetry and synthesis. CHE3234 Practical work Co-requisite: CHE313 Purpose: the acquisition and demonstration of laboratory skills and techniques associated with the theoretical concepts covered in module CHE313. CHE3143 Analytical chemistry* Prerequisite: CHE214, 224 (or 204) Co-requisite: CHE324 Advice: A pass in at least TWO other CHE second-level modules. Purpose: to enable students to demonstrate their understanding of electroanalytical methods, molecular and atomic absorption spectrophotometry, atomic emission and absorption spectrophotometry, chromatography and extraction methods. CHE3245 Practical work Co-requisite: CHE314 Purpose: the acquisition and demonstration of laboratory skills and techniques associated with the theoretical concepts covered in module CHE314. Practical Work 5 Practical work is an integral part of Chemistry and is covered in CHE104. Details of compulsory practical courses and required practical facilities, practical examinations, and exemptions from practical work and practical examinations will be found in Part 7 of the Calendar and 5.1 below. CHE104 Students must attend a compulsory laboratory course at Unisa or at another centre identified by the Department of Chemistry, Unisa during the year of registration. Admission to the laboratory course is restricted to students who have satisfactorily completed a specified number of assignments as specified by the Department of Chemistry. The final examination mark is based on the marks obtained for the assignments, the practical work and practical tests. CHE221–224 Students registered for these modules must attend a compulsory laboratory course in Pretoria lasting 12 days ((3 days per module) (2x Monday to Saturday)) during the year of registration (except in cases where exemption has been granted in terms of 5.1). See dates under 5.2. Admission to the laboratory course is restricted to students who have either: (i) satisfactorily completed a specified number of assignments in the corresponding theoretical modules; or (ii) have already passed the corresponding theory module. CHE321–324 Students registered for these modules must attend a compulsory practical course (one week per module) in the Unisa Chemistry laboratories in Pretoria during June when the entire practical syllabus will be covered. Admission to the practical course in a module is normally only granted to students who obtain at least 50% in the first assignment of that module. Practical examinations for these modules will be completed during the compulsory practical course in June. See Sc6 in Part 7 of the Calendar in connection with the retention of credit. 5.1 EXEMPTION FROM PRACTICAL WORK AND PRACTICAL EXAMINATIONS Exemption from the compulsory practical work and practical examinations may, with the written approval of the Head of the Department of Chemistry, be granted to students who have previously completed or who are attending an equivalent practical course at a recognized university or specially approved 14 academic institution, provided that the results achieved are satisfactory. The responsible person at the university or academic institution concerned must submit a mark to the Head of the Department of Chemistry at Unisa for the practical work, indicate the year in which it was obtained, and certify that it is the student’s own work. This mark will be regarded as an examination mark. Exemption from the practical examination will only be granted for a maximum of two successive calendar years after the year in which the mark was obtained. All applications for exemption must be made in writing, and students must be registered for the module for which the exemption is requested. 5.2 DATES OF PRACTICAL WORK Module Dates of practical CHE104 CHE221 CHE222 CHE223 Module 17 November – 28 November 24 November – 26 November 17 November – 19 November 27 November – 29 November Dates of practical CHE224 CHE321 CHE322 CHE323 CHE324 } } 20 November – 22 November 2 June – 6 June and 9 June – 13 June 17 June – 21 June and 22 June – 26 June 15