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Getting to Know: Atomic Theory The phrase “atomic theory” sounds mysterious, doesn’t it? It evokes images of nuclear laboratories and brilliant scientists; that could be you someday! Atomic theory is simply the study of the atom. You probably already know quite a few things about the atom, like how it is made of different subatomic particles called protons, neutrons, and electrons. You also probably know that atoms have mass and are the basic building blocks of all matter. Understanding more about atomic theory will help you learn how we have come to know so much about the atom. In this lesson, you will also learn about important scientists who furthered our understanding of the atom, and you will learn about different models that have been used to explain the atom. Is this still the current model of the atom? Read on to find out! Who invented the atomic theory? Atomic theory was not invented by a single scientist. Instead, many different scientists have been interested in the building blocks of matter. Over many years, different scientists have built on the work of people before them to add to our knowledge of the atom. Misconception 1: I heard my teacher refer to cells as building blocks. Are cells and atoms the same thing? No, cells and atoms are not the same things. Atoms are the building blocks of all matter; that includes cells as well as nonliving things. Atoms make up cells, whereas cells make up all living things. Ancient philosophers in Greece, India, and China all conceptualized the idea of the atom long before our technology had developed enough to prove it. It was the Greeks, approximately 300 B.C., who gave us the name atomos, which means “not able to be divided.” They believed that if you broke a piece of bread into smaller and smaller pieces, eventually you would have a piece of bread so small it could not be divided further—a bread atom. It was many years before their idea was picked up by John Dalton, a pioneer of atomic theory. He lived from 1766 to 1844. Dalton proposed that atoms were essentially solid spheres that combined to form matter. His thinking helped us understand how atoms of different elements combined to form molecules. For example, he noticed that water could be broken Concept: Atomic Theory 1 © Discovery Communications, LLC down into two other substances, hydrogen and oxygen, but that hydrogen and oxygen could not be divided further. Dalton was on the right path, but there was still much to learn about the atom. John Dalton inspired the scientists who came after him. J. J. Thompson was the next notable scientist to add to the atomic theory. He used x-rays to take some of the first pictures of the insides of people’s bodies and in his research discovered negatively charged particles, which he called electrons. However, he did not know how the electrons were arranged in the atom. He imagined that they were probably spread out evenly between the positive charges, much like plums in a pudding. Thus, his contribution is called the “plum pudding” model. Although Thompson was the first to identify the electron, he did not understand the other subatomic particles and did not realize that atoms had uncharged subatomic particles, or neutrons. Another scientist, Ernest Rutherford, conducted what is now a famous experiment, called the gold foil experiment. He shot helium nuclei through a very thin sheet of gold foil—a sheet so thin that it was only one-atom thick. He expected all of the particles to pass straight through the gold foil, but he found that a tiny portion of the particles deflected off of the gold foil and bounced at odd angles. Some even shot straight backward! He realized that the atoms of gold were not evenly distributed, but instead were composed of a tiny, dense center surrounded by a lot of empty space. Rutherford bombarded gold foil with tiny particles. Wow, interesting! I guess the next scientists learned about how the electrons move in circles, right? That’s right. Niels Bohr developed the model that you are talking about in 1920. He observed that when energy was added to an atom, electrons could use that energy to move farther away from the nucleus. However, they did not just move anywhere. They were much more likely to be in some places than others, just like a person climbing a ladder. When someone climbs a ladder, he or she can be on the third step or the fourth step but not somewhere in between. When the electrons dropped down to lower energy levels, they released the energy back as light at specific frequencies. The color of the light told Bohr how much energy was needed to travel from one level to another. Bohr imagined that the electrons moved in circular orbits like planets, which is not the most accurate model of the electron paths, although it is still a helpful way to visualize how electrons participate in bonding between atoms. So if Bohr’s model does not tell the whole story, what else is there? Although Bohr’s model is still used sometimes, there is another atomic theory that is more prevalent. It is called the electron cloud model. Rather than showing electrons moving in Concept: Atomic Theory 2 ©Discovery Communications, LLC concentric rings, the electron cloud model shows the spaces where an electron is likely to be or unlikely to be. When the locations of an electron are plotted over time, it looks like a cloud. This probability model shows that there are several different shapes that electrons can fill, although we can never know with certainty where a specific electron is at a specific time. All of these changing ideas about the atom should tell you one thing: we are still learning about the atom, its properties, and its subatomic particles. Misconception 2: I remember learning long ago that the atom is the smallest thing there is. However, now I know that there are even smaller things, like protons, neutrons, and electrons. Are those the smallest things ever known? No, amazingly, protons, neutrons, and electrons are not the smallest known things! Scientists have discovered that even subatomic particles are made of smaller particles. These tiny particles are called quarks. Quarks combine to form particles called hadrons. For example, two up quarks and one down quark combine to make the familiar hadron, a proton. Meanwhile, a neutron is made of two down quarks and one up quark. Concept: Atomic Theory 3 ©Discovery Communications, LLC