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UINT - I ACCOUSTICS, ULTRASONICS AND CRYSTAL PHYSICS PART A – QUESTIONS AND ANSWERS 1. Define reverberation time. It is defined as the time taken by the intensity of sound to fall to onemillionth (10-6) of its initial intensity after the source of sound is cut off. 2. What are the characteristics of musical sound? The characteristics of musical sound are (i) Pitch or Frequency (ii) Quality or Timbre (iii) Intensity or Loudness. 3. State Weber- Fechner law. It states that the loudness of sound (L) is directly proportional to logarithm of intensity L log10 I L = k log10 I where k is a constant, which depends on the quality of the sound, the sensitivity of the ear and other factors. 4. Define absorption coefficient. Absorption coefficient is defined as the ratio of the sound energy absorbed by certain area of the surface to that of an open window of same area. 5. What is meant by loudness? Loudness is the magnitude of sensation produced on the ear and varies form one person to another person. Loudness is different form intensity of sound. 6. What is reverberation? The prolongation or persistence of sound inside a room or hall even after the source of sound has stopped producing the sound is called reverberation. This is due to multiple reflections form the walls, ceiling, floor and other reflecting surfaces of the room. 7. Write Sabine’s for reverberation time. 0.165V Reverberation time T = seconds as where V - volume of the hall in m3 a -absorption coefficients of surface areas of different materials in O.W.U s - surface areas of the different materials in m2 as - Total absorption of sound in m2 8. What is meant by echelon effect? The sound produced in front of regular structures like a set of railings or staircase or any regular spacing of reflected surfaces may produce a musical note dye to regular repetition echoes of the original sound to the listener This makes original sound to appear confused or unintelligible. Such an effect is called echelon effect. 9. What are the different types of noises? How can they be controlled? There are three types of noises 1. Inside noise 2. Airborne noise 3. Structure borne noise Control of inside noise: a. The machineries and typewriters may be placed over the sound absorbing materials or pad. b. Covering the walls, floors and ceilings with suitable sound absorbing materials can reduce this type of noise. Control of airborne noise a. By allotting proper places for doors and windows. b. By making perfect arrangement of shutting the doors and windows. c. Using heavy glasses in doors, windows and ventilators. d. By making the hall air-conditioned, this noise maybe eliminated. Control of structure borne noise a. Introducing discontinuity in the path of the sound like using rubber at junctions can control noise from water pipe. b. Using double walls with an air space between them. c. Covering the floors and ceilings with suitable sound absorbing materials and anti vibration mounts. 10. What is pitch? Pitch is the characteristic of sound, which distinguishes between a shrill sound and a grave sound. Actually pitch of note is the sensation conveyed to our brain by the sound waves falling on our ears. The pitch depends directly on the frequency of the incident sound waves. 11. What is timbre? Timbre of sound wave is that characteristic which enables us to distinguish between musical notes emitted by different instruments or voices even though they have the same pitch and loudness 12. Explain how intensity of sound is measured? The intensity of a sound wave (I) at a point is defined as the amount of sound energy (Q) flowing per unit area held normally at the point to the direction of the propagation of sound wave. The intensity of the sound wave I = Q/tA where Q is the sound energy, t is the time and A is the area of the sound source normal to the propagation of sound. Intensity is purely a measurable physical quantity. It is expressed in J s-1 m-2 The power P = Q/t and Intensity I = P/A 13. What are the factors affecting the acoustic quality of a building? The following factors affect the acoustics buildings. They are Optimum reverberation time a. Loudness b. Focusing c. Echo d. Echelon effect e. Resonance f. Noise 14. What are sound absorbing materials? Give examples. Materials that absorb sound are called as sound absorbing materials. Example: Carpets, open, window, hair felt, ordinary chair. 15. What is phon? Phon is the unit of loudness. The interval of loudness corresponding to one decibel on the intensity scale is called one phon. 16. What is sone? Sone is the unit of loudness and it is defined as the loudness of a 1000Hz tone of 40 dB intensity levels. Sone is also equal to the loudness of any sound having a loudness level of 40 phons. 17. What is Ultrasonic? The sound waves having frequencies above the audible range i.e., frequencies above 20,000 Hz or 20 kHz are known as ultrasonic. 18. Distinguish between loudness and intensity of sound. S. No. Loudness 1. It is the amount of sensation produced in the ear and hence it depends upon the listener. 2. 3. Intensity It is the amount of sound energy flowing across unit area per second. Hence it depends on the source of sound and dies not depend upon the listener. It is not a purely physical 2. It is a pure physical quantity quantity but it is subjective in nature Loudness is measured in Intensity is measured in Wm-2 sones. 19. Mention the properties of ultrasonics. a. Ultrasonic waves have a high-energy content. b. Just like ordinary sound waves, ultrasonic waves get reflected, refracted and absorbed. c. Ultrasonic waves can be transmitted over ling distances with no appreciable loss of energy. d. If an arrangement is made to form stationary waves of ultrasonic waves in a liquid, it serves as a diffraction grating. It is called an acoustic grating. e. Ultrasonic waves produce intense heating effect when passed though a substance. 20. What are the methods used to generate ultrasonic waves? In general there are three methods of producing the ultrasonic waves. a. Mechanical generators b. Magnetostriction generator or oscillator. c. Piezo - electric generator or oscillator. 21. Explain magnetostriction effect. When a ferromagnetic rod like iron or nickel is placed in a magnetic field parallel to its length, the rod experiences a small change in its length. This is called magnetostriction effect. 22.What is piezoelectric effect? When mechanical pressure is applied to one pair of opposite faces of a quartz crystal, then the other pair of opposite faces develop equal and opposite electrical charges on the crystal. 23. What is inverse piezoelectric effect? The piezo electric effect is reversible. If an electric field is applied to one pair of opposite faces of the quartz crystal, alternative mechanical expansion of contraction is produced across the other pair of opposite faces of the crystal. This known as inverse piezo electric effect or electrostriction. 24. List the various modes of scanning in ultrasound imaging. The various modes of scanning in ultrasound imaging are a. A scan b. B scan c. TM scan 25. Mention four applications of ultrasonic? a. Sonar is used in the location of shipwrecks and submarines on the bottom of the sea. b. It is used to fish- finding application and the detection of fish shoals. c. Sonar is useful in all merchant and military ships. d. It is used for seismic survey. 26. What is acoustical grating? When ultrasonic waves travel through a transparent liquid, due to alternating compression and rarefaction, longitudinal stationary waves are formed. If monochromatic light is passed though the liquid perpendicular to these waves, the liquid behaves as a diffraction grating. Such a grating is known as acoustic grating. 27. What is ultrasonic blood flow meter? The ultrasonic blood flow meter is used to measure the velocity of blood flow and it works under the principle of Doppler effect. 28. Define Lattice. The periodic arrangement of atoms in a crystal. 29. Define miller indices The set of integers used to describe a crystal plane. 30. Define primitive cell. The smallest unit cell that can be repeated to form a lattice. 31. Define unit cell. A small volume of a crystal that can be used to reproduce the entire crystal. 32. Define space lattice. A three dimensional representation of atoms. 33. Define atomic radius Half the distance between two adjacent atoms in a structure. 34. Define coordination number. Number of nearest atoms surrounding to a particular atom. 35. Define packing density. Ratio between volume of atoms in a unit cell and the volume of the unit cell. 36. Define Bravais lattices. The fourteen possible way of arranging points in space lattice such that all lattice points have exactly the same surroundings. These fourteen lattices are called the Bravais lattices. 37. Define lattice planes. Sets of parallel and equally spaced planes in a space lattice formed with respect to the lattice points are called lattice planes. 38. Define lattice parameters. The inter axial lengths a, b and c of a unit cell and the interfacial angles , and along three axes are called the lattice parameters. PART B – QUESTIONS 1. State and explain Sabine’s formula for reverberation time of a hall. Derive Sabine’s formula for reverberation time. 2. Derive an expression for the rate of growth of the intensity of sound in an auditorium when a sound source is switched on. Obtain an expression for the decay of sound when it is switched off. Hence arrive at a formula for the reverberation time of the auditorium. 3. Explain piezoelectric effect. Draw the circuit diagram of a piezoelectric oscillator and explain the production of ultrasonic waves using it. Explain the application of ultrasonics in SONAR. 4. Explain the factors affecting the architectural acoustics of a building and their remedy. 5. Draw the circuit diagram of a magnetostriction oscillator and explain the construction, working and production of ultrasonic waves using it. 6. Explain with necessary block diagram the principle and working of different ultrasound scanning methods. 7. Describe the structure of the crystal. Deduce the c/a ratio and hence the packing factor of a hcp crystal. 8. Based on the lattice parameters, classify the different Bravais lattices of standard crystal structures. 9. Deduce an expression for the inter planar distance of a cubic lattice in terms of Miller Indices and lattice constant. 10. Deduce the atomic radii in terms of lattice parameters and hence the packing factors of sc, bcc and fcc crystals. 11. What are Miller indices? Sketch two successive (110) Planes. Show that for a cubic lattice the distance between two planes (hkl) is given by a h2 k 2 l 2 UNIT II WAVE OPTICS, LASERS AND FIBRE OPTICS PART A – QUESTIONS AND ANSWERS 1. What are the applications of Michelson’s interferometer? It is used to find a. The wavelength of the given source of light. b. The refractive index or thickness of a transparent material. c. The resolution of wavelengths and d. The standardization of one meter. 2. What is polarization of light? The light, which has acquired the property of one sidedness, is called polarization of light. 3. What are the different types of polarized light? a. Plane b. Circular and c. Elliptically polarized light. 4. Define plane of vibration and plane of polarization. a. The plane in which the vibrations take place (i.e, the plane containing the direction of vibration and the direction of propagation) is called the plane of vibration. b. A plane perpendicular to the plane of vibration is called the plane of polarization. 5. What are uniaxial and biaxial crystals? Give examples. In uniaxial crystal there is one direction called the optic axis along which the two refracted rays travel with the same velocity. Example: calcite, tourmaline and quartz. In biaxial crystals there are two optic axes Example: topaz and aragonite. 6. Light waves can be polarized but sound waves cannot be polarized. Why? Light waves can be polarized because they are transverse in nature. 7. What are circularly and elliptically polarized light? If the vibration of the light are along a circle or an ellipse lying in a plane perpendicular to the direction of polarization, the light is said to be circularly or elliptically polarized light. 8. What is plane-polarized light? When the vibrations of the light are confined along a single direction perpendicular to the direction of propagation, the light is known as plane polarized light. 9. What is meant by double refraction? The phenomenon of producing two refracted rays by a crystal is called double refraction. It is also called birefringence. 10. What is a nicol prism? It is an optical device made from a calcite crystal for producing and analyzing plane polarized light. 11. What is a quarter wave plate? A double refracting crystal plate having a thickness so as to produce a path difference of /4 or a phase difference of /2, between the ordinary and extraordinary rays is called a quarter wave plate. 12. What is a half wave plate? A double refracting crystal plate having a thickness such as to produce a path difference of /2 between the ordinary and extraordinary rays is called a half wave plate. 13. What are uses of a half wave plate? If plane polarized light is passed thorough a half wave plate, the emergent light is also plane polarized but its direction of vibration is inclined at angle 2 to that of the incident light, where is the angle between the incident vibration and the principal section of the plate. Hence such a plate is used in polarimeters as half shade devices to divide the field of view into two halves presented side by side. 14. What are uses of quarter wave plate? The quarter wave plate is used for producing circularly and elliptically polarized lights. In conjunction with a nicol prism, it is used for analyzing all kinds of polarized light. 15. What is photo elastic effect? When a transparent medium such as plastic or glass is mechanically stressed, it exhibits temporary double refraction. This optical phenomenon is known as the photo elastic effect. 16. Explain stress optic law. The changes in the indices of refraction of a material when subjected to stress are linearly proportional to the stresses. 1 - 0= c11 + c22 2 - 0 = c12 + c21 where 1, 2 are principle refractive indices of the material in the stressed state associated with principal stresses 1and2 17. What are isoclinic fringes? Isoclinic are loci points where one of the principle stress direction coincides with the axis of the polarizer. 18. What are isochromatic fringes? Isochromatic are the interference fringes each of which is the locus of points of equal stress difference. 19. What are the essential parts of a photoelastic bench? a. Polariscope b. Compensator c. Loading frame d. Camera e. Monochromatic lamp 20. Explain the principle used in photo elastic bench. The photo elastic bench is based on the principle of photo elasticity. When the transparent medium is strained, it becomes double refracting and the medium is examined between crossed nicol prisms using monochromatic light, interference fringes will be seen. This is made use of for the testing and measurement of strains and stresses. 21. What is a polariser? Give examples. The crystal, which produces polarized light, is called polariser. Example: tourmaline crystal. 22. What is an analyzer? Give examples. The crystal, which is used to analyses polarized light, is called an analyzer. Example: tourmaline crystal. 23. Explain the basic principle of fibre optic communication. When light travels from a denser to a rarer medium, at a particular angle of incidence called critical angle, the ray emerges along the surface of separation. When the angle of incidence exceeds the critical angle, the incident ray is reflected in the same medium and this phenomenon is called total internal reflection. 24. What are the conditions to be satisfied for total internal reflection? a. Light should travel from denser medium to rarer medium. b. The angle of incidence () on core should be greater than the critical angle (c). i.e. >c c. The reflective index of the core(n1) should be greater than the refractive index of the cladding(n2) n1 >n2 25. Distinguish between step index and graded index fibres. S. No. Step index fibre Graded index fibre 1. The light rays propagate The light propagation is in as meridinal rays and the form of skew rays and pass through fibre axis. does not cross the fibre axis. 2. It follows a zig-zag path of It follows a helical path of light propagation. light propagation. 3. It has a low bandwidth. 4. Distortion is more in Distortion is very less and multimode step index is almost zero due to selffocusing effect. fibre. It has high bandwidth. 26. Define numerical aperture. Numerical aperture determines the light gathering ability of the fibre. It is measure of the amount of light that can be accepted by a fibre. Numerical aperture can also be defined as the sine of the acceptance angle (im). If n1 and n2 are the refractive indices of the core and cladding respectively. then, numerical aperture= sin im = n12 n22 27. Define acceptance angle. Accpetance angle is the maximum angle to the axis at which light may enter into the fibre so that it can have total internal reflection inside the fibre. 28. What is meant by fractional index change? Fractional index change is the ratio of refractive index difference between the core(n1) and the cladding(n2) to the refractive index of core. n n2 i.e 1 n2 29. How will you classify optical fibres? Optical fibre are classified into three major categories based on a. Material b. Number of modes c. Refractive index profile. a. Based on the material it can be classified into i. Glass fibre ii. Plastic fibre b. Based on number of modes they classified as i. Single mode fibre ii. Multi mode fibre c. Based on refractive indeed profile they can be classified as i. Step index fibre ii. Graded index fibre. 30. Differentiate between single mode and multimode fibre. S. No. 1. 2. Single mode fibre Multimode fibre Only one mode can be The fibre in this case propagated allows large number of modes of light to propagate through it. It has a smaller core diameter and difference in refractive index of core and cladding is small. Here, since the core diameter is large the core and cladding refractive index difference is also large. 31. Mention the applications of optical fibres in the engineering field. a. It can be used for long distance communication in trunk lines. b. A large number of telephone signals nearly 15,000 can be passed through the Optical fibres in particular time without any interference. c. It is used in computer networks especially in LAN. d. It is also used as optical sensors. 32. What are the types of sensors used in the fibre optics? a. Intrinsic sensors. b. Extrinsic sensors. 33. What is the characteristic of laser radiation? Laser beam has a. Directionality b. Monochromaticity c. High intensity and d. Coherence. 34. What do you mean by coherence in laser light? A coherent light is a pure sine wave and during its transmission it can maintain constant phase difference between any two points in spare as well as in a given time interval at any point along the transmission path. 35. What is meant by laser action? What are the conditions to achieve it? Laser action means the amplification of light by stimulated emission of radiation. For laser action there should be population inversion and stimulated emission should take plane. 36. What is meant by threshold condition for laser oscillation? There should be a minimum amount of population inversion from which laser oscillation starts. This is called threshold condition for laser. 37. What is meant by population inversion? In general the number of atoms in the ground state will be more than that of a in the excited state. The establishment of a situation in which there are more number of in the excited state than the ground state called population inversion. 38. What are the different methods to achieve population inversion? There are five methods by which the population inversion can be achieved. a. Optical pumping b. Electrical discharge or direct electron oscillation c. Inelastic atom – atom collision d. Direct conversion e. Chemical process 39. What is pumping? In laser technology the process of creating population inversion in the atomic stated is known as pumping actions. It is an essential requirement for producing a laser beam. 40. What is meant by active medium in laser? A medium in which the population inversion is achieved is called an active medium. 41. What are the kinds of laser? Depending on the type of active medium used, lasers are classified into four types. a. Solid state lasers b. Gas lasers c. Liquid lasers d. Semiconductor lasers. 42. List any two uses of laser beams in engineering workshops. a. Using high power lasers, we can weld or melt any material. b. We can make small hole in the hard materials that cannot be done by mechanical drilling. c. Laser in used to test the quality of material. 43. Compare the characteristic of laser with ordinary thermal source of light. S. No. Ordinary light 1. Light emitted monochromatic 2. 3. 4. is Laser light not Light emitted is monochromatic highly Light emitted does not It has high degree of have high degree of coherence coherence Emits light in all direction Emits light only in one direction Light in not intense and Laser light in much intense bright and bright 44. What is the use of nitrogen and helium laser? In CO2 laser the nitrogen helps to increase the population of atoms in the excited state of carbon dioxide, while helium helps to deport the atoms in the ground state of CO2 and also helps in cooling the discharge tube. 45. Give some examples of direct and indirect band gap LED material? Direct band gap LED materials a. GaAs b. GaAsP Indirect band gap LED material a. GaP doped with nitrogen b. GaP doped with zinc 46. Define holography Holography deals with construction of image by means of interference techniques without using lenses. The amplitude and phase distribution is recorded in 3D manner so as to get complete information of the object to be photographed. 47. State some of application of lasers in engineering and industry. a. Used for welding and cutting. b. It is used to test the defects such as pores, cracks, flaws, holes, etc, in the material. c. High power lasers are useful to blast holes in hard steel and diamond. 48. How is a LED different from a semiconductor laser? S. No. 1. LED It requires low density LASER current It requires high density 2. Power output is less Power output is high 3. Less intensity Intensity in very high 4. Minority carrier takes place. injection Stimulated place emission current takes PART B – QUESTIONS 1. Explain the construction and working of Michelson’s interferometer and hence explain how it is used to find the refractive index of a transparent layer. 2. With necessary theory an experiment to measure the thickness of a very thin foil using the principle of interference. 3. Explain the construction, types of fringes and application of Michelson’s interferometer. 4. Explain with suitable mathematical derivations, the formation of plane, circularly, and elliptically polarized lights. 5. Explain in detail the production and analysis of plane, circularly and elliptically polarized lights. 6. Explain photo elasticity and discuss stress optic law. What are isoclinic and isochromatic fringes? 7. Give the block diagram of a photo elastic bench and describe its components. 8. Write a note on the arrangements of optical elements in plane and circular polariscopes. 8. Describe the construction and working of the He-Ne laser and CO2 laser. - 9. Describe the construction and working of the Nd - YAG laser. What are its advantages over Ruby laser? Discuss briefly the industrial applications of lasers. 10. Explain the propagation of light through optical fiber and applications of optical fiber as wave-guide and sensor. Derive expressions for acceptance angle and numerical aperture. 11. Give an account of sources, detectors and connectors and multiplexers used in the optical communication system. What are the advantages of optical fiber communication over conventional communication system? 12. a) What is meant by mode in an optical fibre? Arrive at an expression for the numerical aperture. b) Explain in detail the working of any one optical fibre sensor. 13. Write an essay on the working of fiber optic communication system. UNIT III CONDUCTING MATERIALS & QUANTUM PHYSICS PART A – QUESTIONS & ANSWERS 1. Define electrical conductivity. The electrical conductivity is defined as the quantity of electricity flowing per unit area per unit time maintained at unit potential gradient. ne 2 1 1 m m where n – number of free electrons per unit volume e – charge of the electron - relaxation time m – mass of an electron 2. Define mobility of electrons. When an electric field E is applied to metals, the electrons move in a direction opposite to the field direction with the velocity v then mobility of an electron is defined as the velocity acquired by the electron per unit electric field. v E 3. Define drift velocity. Drift velocity is defined as the average velocity acquired by the free electron in a particular direction, due to the application of the electric field. e E vd c m where e - charge of the electron c – mean collision time E – electric field applied m – mass of the electron 4. Distinguish between relaxation time and collision time. S. No. 1. 2. Relaxation time Collision time Time taken by the free Average time taken by a free electron to reach its electron between two equilibrium position from its successive collisions. disturbed position due to the electric field applied. = 10-14 seconds c = c seconds 5. What are the special features of classical free electron theory? The classical free electron theory visualizes a metal as an array of atoms (ions) permeated by a gas of free electrons. There is no mutual interaction among the free electrons or between ions and electrons. The free electrons can move freely in random directions under the constant potential provided by the fixed ions of the lattice. 6. What are the failures or drawbacks of classical free electron theory? a. Experimentally the electronic specific heat is about 0.01R. b. The ratio between thermal conductivity and electrical conductivity is not a constant at low temperatures. c. The theoretical value of paramagnetic susceptibility is greater than the experimental value. d. The electrical conductivity of semiconductors, ferromagnetism, photoelectric effect and black body radiation cannot be explained. 7. State Wiedemann – Franz law. Give the value of Lorentz number and state whether it holds good for all metals and at all temperatures. Wiedemann – Franz law states that ‘the ratio between the thermal conductivity K and the electrical conductivity is directly proportional to the absolute temperature T of the metal. K T K LT where L – Lorentz number = 2.44 x 10-8 WK-2 at T = 293 K. This law holds well for all metals but not at low temperatures. 8. Define mean free path of an electron. The average distance traveled between two successive collisions is called mean free path. c c where - mean free path c - root mean square velocity of the electron c - Collision time 9. What are the main stages of electron theory of solids? a. Classical free electron theory or the Drude – Lorentz free electron theory A macroscopic theory according to which metals contain free electrons and these free electrons, which are assumed to move in a constant potential, are responsible for the electrical conduction in the metal. This theory obeys the laws of classical mechanics. b. Quantum free electron theory or Sommerfeld Quantum theory A macroscopic theory according to which the electrons move in a constant potential and they obey the laws of quantum mechanics. c. Zone theory or Band theory of solids According to the band theory of solids, the free electrons move in a periodic potential provided by the periodicity of the crystal lattice. Electrical conductivity is explained based on energy bands. 10. Define thermal conductivity. The amount of heat flowing per unit time through the material having unit area of cross section and maintaining unit temperature gradient. dT Q K dx Q K dT dx where K – coefficient of thermal conductivity of the material Q – heat flux or heat flow density dT - temperature gradient dx 11. What is the band theory of solids? According to the band theory of solids, the free electrons move in a periodic potential produced by the positive ion cores. The electrons are treated as weakly perturbed by the periodic potential. 12. Distinguish between energy state, energy level and energy band. Energy state – The energy state is described by the wave function and four quantum numbers n, l, ml and ms. Energy level – The energy of the electron in a shell or orbit is expressed in terms of energy level. An energy level may contain one or more energy states. Energy band – The band is formed in crystals or solids. The closed packing of an array of energy levels forms a band. 13. Write the Fermi Dirac distribution function. The probability F(E) of an electron occupying a given energy level at absolute temperature is called the Fermi Dirac distribution function. 1 F (E) 1 e E EF kT where F(E) – Fermi function or Fermi factor or Fermi distribution function E – energy of the level whose occupancy is being considered EF – Fermi energy or Fermi level of the system k – Boltzmann’s constant T – absolute temperature 14. Define Fermi level and Fermi energy. Fermi level – The energy level at any finite temperature above 0K in which the probability of electron occupation is 0.5 or 50%. It is also the level of maximum energy of the filled states at 0K. Fermi Energy – The energy of a state at which the probability of electron occupation is 0.5 at any temperature above 0K. It is the maximum energy of filled states at 0K. 15. Draw the Fermi distribution curve for 0K and at any temperature TK or how does the Fermi function vary with temperature? Case (i) At T = 0K and for E < EF Then F(E) = 1 There is 100% chance that the electrons can occupy the energy levels below the Fermi level. At T = 0K and for E > EF Then F(E) = 0 There is 0% chance for the electrons to occupy the energy levels above the Fermi level. Case (ii) At T > 0K and for E = EF Then F(E) = ½ There is 50% chance that the electrons can occupy the Fermi energy level. 16. Define density of states. What is its use? The number of energy states per unit volume in an energy interval is defined as the density of states. It is used to calculate the number of charge carriers per unit volume of the solid. 17. Define band gap, valence band and conduction band. Band Gap – The energy difference between the minimum energy of the conduction band and the maximum energy of the valence band. Valence band – The region of energy levels where the valence electrons occupy their positions. Conduction Band – The region of energy levels where the conduction electrons or free electrons occupy their positions. 18. What is work function? The minimum amount of external energy imparted to an electron to make it leave the surface of the metal is known as the work function. EW = EB – EF = eQ PART B – QUESTIONS 1. Define density of states and derive an expression for free electrons. Deduce the Fermi energy at 0K. 2. Obtain the Schroedinger’s wave equation for a particle in the box. 3. Explain Compton effect and derive an expression for the wavelength of the scattered photon. 4. Derive an expression for the energy levels of a particle enclosed in one-dimensional potential box of width ‘a’ and infinite height. 5. Derive Richardson – Dushman equation for electronic work function in metals. 6. Explain relaxation time and mean free path. Derive Wiedemann – Franz law relating to electrical and thermal conductivity of metals. 7. Obtain an expression for the electrical conductivity of a metal. Write a note on electrical conductivity at high frequencies. 8. Discuss the essential features of the electron energy band structure of solids. 9. Derive Schroedinger’s equations. time dependent and time independent 10. How is the electrical conductivity of a metal affected by temperature and alloying. 11. What are the basic postulates of quantum theory of radiations? Derive Planck’s law of radiation. UNIT IV SEMICONDUCTING AND SUPERCONDUCTING MATERIALS PART A – QUESTIONS AND ANSWERS 1. What is a semiconductor? Give examples. A material whose resistivity or conductivity lies in between a conductor and an insulator is known as a semiconducting material. Resistivity is of the order of 10-4 to 0.5 ohm metre. Semiconductors have a nearly conduction band and an almost filled valence band with a very small energy band gap (= 1eV). Examples: Germanium (Ge), Silicon (Si), Gallium (Ga), Arsenic (As) 2. State the properties of a semiconductor. a. Resistivity lies between 10-4 to 0.5 ohm metre. b. At 0K they behave as insulators. c. Conductivity of a semiconductor increases due to both temperature and impurities. d. Semiconductors have negative temperature coefficient of resistance. e. Holes and electrons are charge carriers in semiconductors. 3. Compare elemental and compound semiconductors. (or) What are the differences between direct and indirect band gap semiconductors? S. No. Elemental or Indirect band gap Compound or Direct band gap Semiconductor Semiconductor 1. Single element semiconductors. They are made of compounds. Eg. Ge, Si, etc. Eg. GaAs, GaP, CdS, etc. 2. Electron - hole recombination Electron - hole recombination takes takes place through traps, which place directly with each other. are present in the band gap. 3. Heat is produced recombination. 4. Lifetime of charge carriers is Lifetime of charge carriers is less more due to indirect due to direct recombination. recombination. 5. Current amplification is more. 6. Used in the manufacture of Used in the manufacture of LEDs, diodes and transistors. Laser diodes, ICs, etc. due to Photons are recombination. emitted during Current amplification is less. 4. Draw the energy band diagram of a semiconductor. E Empty Conduction Band Small Gap Eg Filled Band Energy Valence 5. What is an extrinsic semiconductor? A semiconducting material in which the charge carriers originate from impurity atoms, added to the material is known as an extrinsic semiconductor or impure semiconductor. This semiconductor is obtained by doping a tetravalent semiconductor with a trivalent or a pentavalent impurity. Examples: Ge or Si doped with As, Sb, P, Al, B, etc. 6. What is an intrinsic semiconductor? A semiconductor in an extremely pure form (without the addition of impurities) is known as an intrinsic semiconductor. Electrical conductivity is entirely due to thermal excitation. Examples: Ge and Si. 7. Distinguish between intrinsic and extrinsic semiconductors. S. No. Intrinsic Semiconductor Extrinsic Semiconductor 1. Pure semiconductors are called Semiconductors doped with intrinsic semiconductors. impurity are called extrinsic semiconductors. 2. Charge carriers are produced Charge carriers are produced due due to thermal agitation. to impurities as well as thermal agitation. 3. They have conductivity. low electrical They have conductivity. high electrical 4. They have temperature. low operating They have temperature. high operating 5. At 0K, Fermi level lies exactly At 0K, Fermi level lies closer to between conduction and valence conduction band in the n type bands. semiconductor and closer to the valence band in the p type semiconductor. Examples: Ge and Si. Examples: Ge or Si doped with As, Sb, P, Al, B, etc. 8. Compare n type and p type semiconductors. S. No. n - type Semiconductor 1. n – type semiconductor is obtained by doping an intrinsic semiconductor with pentavalent impurity. p - type Semiconductor p – type semiconductor is obtained by doping an intrinsic semiconductor with trivalent impurity. 2. Electrons are majority carriers Holes are majority carriers and and holes are minority carriers. electrons are minority carriers. 3. Donor energy levels lie close to Acceptor energy levels lie close to the conduction band. the valence band. 4. When temperature is increased these semiconductors can easily donate an electron from the donor energy level to the conduction band. When temperature is increased these semiconductors can easily accept an electron from the valence band to the acceptor energy level 9. Write the expression for the concentration of holes in the valence band and the concentration of electrons in the conduction band of an intrinsic semiconductor. Expression for the concentration of holes in the valence band of an intrinsic semiconductor 3 2mh * kT 2 EV EF kT p 2 e 2 h Expression for the concentration of electrons in the conduction band of an intrinsic semiconductor 3 2me * kT 2 EF EC kT n 2 e 2 h 10. What is meant by Hall effect, Hall voltage and Hall coefficient? Hall Effect – When a current carrying conductor is placed in a transverse magnetic field, an electric field is produced inside the conductor in a direction normal to both the current and the magnetic field. Hall Voltage – the generated voltage is the Hall voltage. Hall Coefficient – Hall field per unit current density per unit magnetic induction is called Hall coefficient. 11. PART B – QUESTIONS 1. Discuss the following properties of superconductors a. Meissner effect b. Isotope effect c. Quantum interference leading to SQUID 2. Derive expressions for electron and hole concentrations for an intrinsic semiconductor. 3. Discuss the theory of Hall effect and explain an experimental procedure for the study of it. 4. Derive the relation for carrier concentration in n-type semiconductor. Explain the generation and diffusion of charge carriers in semiconductors. 5. Explain the BCS theory of superconducting materials. Distinguish between Type I and Type II superconductors. Describe high T C superconductors. 6. Discuss the properties and applications of superconductors. 7. Discuss the variation of Fermi level with carrier concentration and temperature in n-type semiconductor. 8. Derive an expression for the density of holes in the valence band and also explain how does the Fermi level vary with the concentration of impurities in the p-type semiconductor. 9. Discuss carrier concentration, the variation of Fermi level with temperature in the case of p-type and n-type semiconductors for high and low doping levels. 10. Show that for a p-type semiconductor the Hall coefficient RH is given by 1 . Discuss the applications of Hall effect. pe UNIT V DIELECTRICS, NEW MATERIALS AND NDT PART A – QUESTIONS AND ANSWERS 1. Distinguish between radiography and fluoroscopy. S. No. 1 Radiography Image is developed photographic films Fluoroscopy on Image is developed on fluorescent screen. 2 High resolution and high Fair resolution and low contrast contrast 3 Immediate image cannot be Immediate image can be obtained viewed through the monitor 4 X-ray energy is converted X-ray energy is converted into chemical energy into visible light 5 Expensive Inexpensive 6 Time consumption is high Time consumption is low 2. What is NDT method? NDT method is a method of testing the application without impairing or changing its usefulness for future service. It is used to examine the material and to detect the flaws present in the material without damaging it. 3. Give the importance of NDT method By using NDT testing, the location, dimension flaws and material structure are determined. Due to the determination of factors in the earlier stage, we can increase. a. The quality of the product. b. Productivity and profits c. The serviceability 4. Give any four techniques of testing a material by NDT. a. Liquid penetrant method b. Ultrasonic inspection c. Radiography methods d. Thermography 5. What is the principle of ultrasonic flaw detector? Whenever there is a change in medium, the ultrasonic waves will be reflected. From the intensity of the reflected echoes the flaws are detached. PART B – QUESTIONS 1. Discuss the internal or local field theory of dielectrics and deduce the Claussius – Mossotti equation. 2. What are shape memory alloys? Discuss their properties and applications. 3. Describe pulse echo and through transmission method to identify the flaw in a metal. Describe the different stages of liquid penetrant method. 4. Write a short not on x-ray radiography technique for the determination of depth of the flaw. Also compare its merits and demerits with that of γ – ray spectrography. 5. a) Draw the block diagram of an ultrasonic flaw detector and explain the function of its various components. b) Explain the tube shift method of finding the depth of flaw in a material using x-rays. 6. Discuss the principle of radiography in NDT. Hence describe the x-ray radiographic method of NDT. 7. Explain the theory of dielectric loss mechanism and discuss the different dielectric breakdown methods. 8. Explain ionic, electronic, space charge and orientational polarizations. 9. What are metallic glasses? How will you prepare metallic glasses by melt spinning method? Mention any four applications. 10. Discuss any two methods (other than liquid penetrant method) of NDT, pointing out their limitations. 11. What is the basic principle of radiographic inspection? Explain their inspection techniques. What are its limitations? 12. Discuss different polarizations mechanisms and explain their frequency and temperature dependence. 13. Obtain an expression for the frequency dependence of the electronic polarisability and show that the imaginary part of the polarisability gives rise to absorption of energy by the system from the field.