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7 110 Subduction zones, island arcs and active continental margins depth [km] 0 volcanic arc ocean 200 backarc basin deep sea trench 400 continent 200 600 400 600 80 0 800 1000 10 00 200 1200 subducting plate 1400 14 00 80 0 400 1600 10 00 12 00 600 0 200 depth [km] 200 deep sea trench 600 800 distance from trench [km] volcanic arc magmatic gap oceanic crust 400 continental crust 0 20 40 60 300 Abukuma-type metamorphism 300 600 600 lithospheric mantle 80 incipient formation of eclogite 100 1100 1100 120 140 160 asthenosphere 50 km Fig. 7.25 Diagrammatic cross sections through subduction zones. Upper: computer-modeled temperature distribution, in °C, of a subduction system and, lower: cross section through an active continental margin showing an estimation of the isograds (lines of the same temperature) (Schubert and Turcotte, 1975). Oceanic crust is dewatered during subduction. Basaltic rocks contain abundant water because interaction with seawater near the mid-ocean ridge forms water-containing minerals (zeolite, chlorite, epidote, amphibole; Ch. 5). Under conditions of subduction metamorphism, the water-containing minerals become unstable and are replaced. Water set free by metamorphism of these minerals is partly bound in other water-containing but highpressure resistant minerals (e. g., lawsonite, zoisite, glaucophane); however, the major portion is emitted into the mantle above the subduction zone. Subducting rocks are thus gradually dewatered and that is the reason why eclogite, to a large extent, is a “dry” rock. In addition to basalt, dolerite and gabbro, sedimentary rocks and splinters of continental crust carried with the subducted material experience high-pressure metamorphism. However, the mineral composition in these rocks is not easy to identify as having formed under high-pressure conditions. Many groups of minerals (garnets, amphiboles, micas, chloritoids, etc.) have special members formed under high-pressure conditions which are chemically different from their relatives formed under different pressure-temperature conditions. Only a detailed microchemical analysis of the minerals using an electron-microprobe can detect whether they were formed under highpressure or normal conditions of metamorphism. Under conditions of high-pressure metamorphism, iron-magnesium silicates mostly have compositions similar to those of the Mg end-members because the small ion radius of magnesium supports denser packing of atoms. Sediments contribute significantly to the dewatering in a subduction zone although following high-pressure metamorphism they continue to include water-containing minerals such as phengite (a type of mica), karpholite, chloritoid and lawsonite. Water released in the subduction zone causes intense changes in the mantle above and, from a certain depth, melting processes which are responsible for magmatism above a subduction zone. It is difficult to explain how rocks that have been metamorphosed at great depths in subduction zones are exhumed at the surface. Such highpressure metamorphic rocks occur in mountain ranges in lenses or in larger bodies within ophiolite sequences and their adjacent rocks. Typically they occur within long narrow zones that contain ophiolites and mark the suture zone of collisions between two continental masses. Commonly, high-pressure mineral associations are only preserved as relics. This is because highpressure minerals adapt to decreasing pressure and temperature conditions that accompany slow isostatic ascent. Only rapid uplift accompanied by relatively low temperatures or rapid cooling maintains high-pressure minerals in rocks. Investigations of textures in eclogites suggest that regions of extreme crustal extension above high-pressure metamorphic rocks generate the conditions in which high-pressure minerals can be preserved; such conditions permit rocks from deep-seated subduction zones to rapidly reach the surface (Platt, 1986). Processes associated with erosion by water and ice occur much too slowly to remove the overlying rocks rapidly enough. The geologic setting of the Western Alps clearly illustrates this last point. The mineral assemblage Licensed to jason patton<[email protected]>