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Scientist: Per: Date: UNIT 1: STRUCTURE OF MATTER ____________________ _________ _________ #7 DEVELOPING THE ATOMIC MODEL Objective: I can evaluate which model of the atom is supported by historical experiments by analyzing 4 different atomic models, considering current evidence and writing a TIEA paragraph. Over time, scientists have proposed many different models (or ideas) about what the atom might be like. The pictures and descriptions below show four of the most well-known models of the atom: Plum Pudding Model Solid Sphere Model That atom can be divided into fluid (the “pudding”) and electrons (the “plums”). Most of the atom is made of fluid. The fluid spreads out over the whole atom and is positive. The electrons are scattered throughout and are negative. Bohr Model (Planetary Model) The atom is a tiny, solid sphere that cannot be divided up into smaller particles or pieces. The nucleus contains protons and neutrons and is located in the center of the atom. The protons are heavy and positively charged. The neutrons are also heavy, but they are neutral. The electrons are tiny and negatively charged and circle the nucleus in fixed energy levels (shells) The atom can be divided into a nucleus and electrons. The nucleus occupies a small amount of space in the center of the atom. The nucleus is dense and positively charged. The electrons are tiny and negatively charged. Most of the atom is empty space. Nuclear Model J.J. Thompson (1897): Cathode Ray Experiment On each figure below, talk to the text: Figure 1 J.J. Thompson passed an stream of electric current through many types of atoms in a vaccum tube. When he did this, he observed a glowing ray called the “cathode ray” come out of the various atoms. The cathode rays passed through thin sheets of foil, so J.J. Thompson knew that the cathode rays coming from the atoms were made of particles much smaller and lighter than normal atoms. Figure 2 When J.J. Thompson exposed the tiny particles in the cathode rays to positive and negative charge, they were attracted to positive charge (moved toward it) and repelled by negative charge (moved away from it). He reasoned that the small particles were negative (since they were attracted to positive charge); he called these negative particles ‘electrons’ inside of the atom. Question: Which atomic model can we eliminate based on Thomson’s experiment? Claim: Evidence: Reasoning: 2 Ernest Rutherford (1911): The Gold Foil Experiment Figure 1 In the early 1900’s, it was discovered that certain types of rock emitted (shot out) positive particles, called ‘alpha particles’. These positive particles contained two positive charges (2+), and had the same mass as a helium atom. Figure 2 Rutherford fired a stream of alpha particles at an extremely thin piece of gold foil. Given the high energy of the particles, Rutherford expected the particles to shoot straight through the metal. To his great surprise however, about 1% of the alpha particles were deflected, or bounced, to the side or Expected Results Actual Results backwards. Figure 3 Rutherford reasoned that, since most of the alpha particles went straight through the foil, most of the gold foil was empty space. But what was causing the alpha particles to bounce to the sides and backwards? He realized that some of the alpha particles were hitting a dense (small and heavy), positive center. He called this center the ‘nucleus’. Question: Which atomic model can we eliminate based on Rutherford’s experiment? Claim: Evidence: Reasoning: 3 What’s in the nucleus? Ernest Rutherford (1918) and James Chadwick(1932): Experiments by Rutherford in 1918 detected heavy positive particles that were emitted from atoms. He called these positive particles ‘protons’, and reasoned that they must be in the positive nucleus. However, the atomic model was still not complete. Experiments by Chadwick in 1932 detected a yet another new particle. Colliding atoms together at high speed, he detected uncharged (neutral) particles which he called ‘neutrons’. When Chadwick measured the mass of a neutron, he found that it was heavy, so the neutrons must be located inside the small, heavy (dense) nucleus of the atom with the protons. Where are the electrons? Niels Bohr (1913) With the model of the nucleus emerging, one big question remained unanswered. Where were the electrons? Scientists struggled with the question as they couldn’t imagine a stable configuration between the positively charged nucleus and the negatively charged electrons. If protons and electrons held opposite charges, shouldn’t the negatively charged electrons be attracted to (and fall into) positively charged nucleus? In examining electromagnetic radiation emissions of the hydrogen atom, Niels Bohr concluded that the electrons must be located in specific “energy levels” (sometimes called “shells”). He imagined the electrons orbiting the nucleus much like the planets orbit the Sun. It is a model that is not perfect, yet remains useful for introducing students to basic atomic structure. Bohr’s model proved groundbreaking in many respects and he won the 1922 Nobel Prize for his efforts. But Bohr’s model was based on the hydrogen atom and failed to account for new experimental data produced when using other elements, such as helium. His model was later superceded by the Quantum Mechanical Model put forth by Heisenberg and Shroedinger. Nevertheless, the Bohr model of the atom remains useful as an instructional tool and student model to this day. 4 Atomic Model Conclusion: Which Model Best Explains the Evidence? Now that you have eliminated all of the atomic models except for one, you need to present your conclusions about the structure of the atom to other scientists. Scientists communicate to each other by writing, so you must write a well-reasoned TIEA paragraph that explains your conclusions. Write your paragraph in response to the following prompt: Which model of the atom best explains the experiments you read in class? Use evidence from each experiment (Thompson, Rutherford, and Bohr) to justify your answer. T: According to the current model of atomic structure, the atom is made of ______________________________________________ ____________________________________________________________________________________________________________________________________ _____________________________________________________________________________________(describe the basic structure of the atom). I: Throughout scientific history, several famous scientists including _______________________, ____________________________, and ______________________________ conducted experiments to discover the structure of the atom. E1: For example, _____________________________ (name of scientist) found that ________________________________________________ ____________________________________________________________________________________________________________________________________ ___________________________________________________________________________________________________________________________________. A1: This fits with the current model of atomic structure, because _________________________________________________________ ____________________________________________________________________________________________________________________________________ ___________________________________________________________________________________________________________________________________. E2: Later, _____________________________ (name of scientist) found that ________________________________________________________ ____________________________________________________________________________________________________________________________________ ___________________________________________________________________________________________________________________________________. A2: This fits with the current model of atomic structure, because _________________________________________________________ ____________________________________________________________________________________________________________________________________ ___________________________________________________________________________________________________________________________________. E3: Finally, _____________________________ (name of scientist) found that ______________________________________________ ____________________________________________________________________________________________________________________________________ ___________________________________________________________________________________________________________________________________. A3: This fits with the current model of atomic structure, because _________________________________________________________ ____________________________________________________________________________________________________________________________________ ___________________________________________________________________________________________________________________________________. C(conclusion): These experiments led to the discovery of _________________________________________________________________ ____________________________________________________________________________________________________________________________________ ___________________________________________________________________, which are all included in the current model of the atom. 5