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Chemistry II, AP Final Exam – Suggested topics for review December 2008 All Multiple Choice 85 questions You will get to use the AP exam equation sheets on the test, but that’s it. So if think you’ll need any additional equations, memorize them. And don’t forget those solubility rules. Chapter 1 – Matter, Measure Intensive/extensive properties Separation techniques SI units Density relationship, calculations Precision/accuracy Sig figs Dimensional analysis problems Chapter 2 – Atom, Molecules, Ions Atomic theory; experimental situations that led to current ideas Atomic structure; protons, neutrons, electrons Average atomic mass Nomenclature and formula writing (ionic, covalent, acids) Chapter 3 - Stoichiometry Balancing equations Types of reactions (combination, decomposition, combustion) Percent composition Mole conversions (Avogadro’s number, molar mass) Empirical/molecular formula problems Stoichiometry (calculations with balanced equations) Limiting reactant, excess reactant Theoretical/percent yield Chapter 4 - Aqueous solutions Electrolytes (strong, weak, non) Precipitate formation (solubility rules) Double replacement reactions Ionic and net ionic equations Acid base reactions (neutralization) Redox reactions (what’s been ox/red, oxidizing/reducing agent) Assign oxidation numbers Single replacement reactions (displacement reactions) Predicting SR reactions Molarity of solutions, use of molarity in stoichiometry Dilution Titrations and associated calculations Chapter 5 - Thermochemistry Work Energy equation, E = q + w Endo/exothermic; stoichiometry calculations State function Enthalpy of reaction Calorimetry, q = mcT Hess’s Law type problem H of formation, use to find H of reaction Chapter 6 – Electronic structure of the atom Use of wave equation, c = EM spectrum Planck’s equation, E = hv, quantum concept Explanation of line spectra, especially hydrogen Calculation of frequency/wavelength as electron falls Wave behavior of electron in the atom Quantum numbers Orbital shapes, energies Electron configurations/orbital diagrams (Aufbau, Pauli, Hund); exceptions Chapter 7 - Periodicity Effective nuclear charge Atomic radius trends Ionic radius trend Ionization energy trend Electron affinity trend Metallic character trend Reactions of alkali metals, alkaline earths Chapter 8 – Bonding Lewis dot structure of atoms Ionic bonding; metal nonmetal Born-Haber cycle problem Lattice energy factors Electron configuration of ions Covalent bonds; nonmetals Lewis structures Electronegativity trend Polar bonds Formal charge Resonance H of reaction from bond enthalpies Bond strength, bond length Chapter 9 – Molecular Geometry Molecular geometries Bond angles Polarity of molecule Hybridization Sigma and pi bonds Delocalized bonding Chapter 10 – Gases Gas law relationships (Boyle, Charles, Gay-Lussac, Avogadro) Ideal gas law, calculations, conditions for ideal behavior Root mean square velocity Kinetic molecular theory Graham’s law of Effusion Dalton’s Law of Partial Pressures Gas Density Chapter 11 – IMF, Liquids, and Solids van der Waals forces (dipole-dipole, H-bonding, Dispersion (induced dipole)) Intermolecular forces and …boiling point, melting point, vapor pressure, viscosity, surface tension, states of matter Phase diagrams Phase changes, terms, endo/exothermic Heating curve calculations; heat loss – heat gain problem Vapor pressure/temperature relationship o Clausius-Clapyron relationship Different types of solids (metallic, ionic, covalent network, molecular) Chapter 21 - Nuclear Types of radioactivity decay Nuclear equations (decay, bombardment, fission, fusion) Predict mode of decay based on n/p ratio Half-life problems Energy changes in nuclear reactions (binding energy, energy of fission/fusion) Nuclear reactor components Chapter 25 – Organic Naming compounds and writing formulas – organic Alkanes, alkenes, alkynes Isomers Hydrocarbon reactions (combustion, addition, substitution) Aromatic compounds (benzene, ortho, meta, para) Functional group recognition (alcohol, ether, amine, aldehyde, ketone, carboxylic acid, ester) Compound name/formula (alcohol, acid, ester)