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Topic 3: Metals and Metal Extraction (3 weeks) Topics to cover • • • • • • • Minerals Metals and their uses Mine to Metal – the processes involved The activities series Metal ores The extraction process of iron and aluminium Precipitation reactions Key Idea 1: Minerals are natural resources that are important to Australia’s economy • Define the term mineral • State how minerals are mined from the ground in the form of an ore • Discuss the economic considerations of mining an ore deposit The natural occurrence of metals • Most metals occur in the earth’s crust as compounds called minerals. • Minerals are substances formed naturally in the Earth. • They are solid, inorganic and have a definite chemical composition and structure. • There are over 3000 minerals known. Some are rare and precious such as gold and diamond, while others are more ordinary, such as quartz. Mineral - Definition 1. 2. 3. 4. Naturally occurring Inorganic Definite chemical composition Solid with a crystal structure due to internal arrangement of atoms 1. Naturally occurring in the earth Mineral formation • Mineral formation can occur during the cooling of a melt. • Magma cools slowly as it rises to earth and solid rocks form with large crystals. • Lava is on the Earth's surface so it cools quickly compared to magma in Earth. As a result, rocks form quickly and mineral crystals are very small 1. Naturally occurring in the earth Mineral formation • Minerals are deposited from salty water solutions on Earth's surface and underground called crystallisation. In order for a mineral to crystallise, ions from the nearby environment must be brought together and link together to form mineral crystals. • The size and texture of the crystals formed depends on the rate of change in temperature and pressure which essentially determines how much time is available for the crystals to develop. 2. Minerals are Inorganic That is to say, they are not organic compounds! (formed form biological processes) 3. Minerals have a definite chemical composition • Each mineral is made of a particular mix of chemical elements and can be written as a chemical formula. E.g. Limestone (CaCO3) 4. Minerals have a solid, crystalline structure Minerals are solid substances with a crystalline structure. To be crystalline means that the atoms within the solid are arranged in a in an ordered, three-dimensional, structure. The distances and angles between an individual atom and the neighbours it is bonded to are constant. 4. Minerals have a solid, crystalline structure The result of this is that the structure of a crystal is both geometrical and highly symmetrical, forming a pattern unique to each mineral. Mineral Formation • The crystal structure that is formed is based upon the chemical composition and the type of bonding. • Ionic bonding: The electrostatic forces between the positive and negative ions (usually metal and non-metal) as in halite (formed from NaCl). • Covalent bonding: The atoms share electrons, as in diamonds (made of C). Minerals - Polymorphs • Polymorphs are minerals that have the same elements in the same proportions, but the atoms are arranged differently. For example: diamond and graphite both are pure carbon. Classification of Rock-forming Minerals • There are two classifications of minerals: – Silicate minerals, and – Non-silicate minerals. • Silicate minerals make up more than 90% of the Earth’s crust. • Silicate minerals are made up of silicon (Si) and oxygen (O) atoms along with other elements (Al, Mg, Fe, Mn, and Ti). Identifying Minerals • Properties which are used to identify minerals include: Colour Lustre Streak Cleavage and fracture Hardness Density Any special properties Mineral Hardness CRYSTAL SHAPE (FORM) • Ability to scratch another mineral • Mohs scale from 1 (talc) to 10 (diamond) • Quartz (most common mineral and most dust particles) is 7 LUSTRE COLOUR How light reflects off the surface Main categories are “metallic” & “non-metallic” For example: Metallic/glassy – shiny Non-metallic - dull External structure due to internal arrangement of the atoms Six basic groups of shapes, with about three dozen variations Colour results from the ability to absorb some wavelengths & reflect others some minerals have characteristics colors others vary due to chemical differences or impurities - unreliable Streak MINERAL CLEAVAGE/ FRACTURE • Color of the powder when rubbed on a “streak plate” (unglazed porcelain) • May be same as handspecimen or different • Some paint is based on powdered minerals (streaks). Some minerals split along flat surfaces when struck hard--this is called mineral cleavage Other minerals break unevenly along rough or curved surfaces-this is called fracture A few minerals have both cleavage and fracture Other special properties • Magnetism is a distinctive property in a few minerals (magnetite) • Some minerals fluoresce under UV light (calcite and fluorite). • Some minerals are radioactive (radium and uranium). Ores • Elements are the building blocks of minerals • Minerals form the building blocks of rocks. are made of Rocks minerals elements are made of • An ore deposit is a small region in the crust where the concentration of metal is high enough to make it financially viable to extract it. • Some unreactive metals such as gold can be found as the metal itself and chemical separation is not needed. Ores are rocks containing valuable minerals Gold in quartz Galena - lead Hematite – iron ore Malachite - copper Mineral Summary A mineral is a naturally occurring substance that is solid and stable at room temperature, represented by a chemical formula. Minerals are different from rocks, which can be any combination of minerals or non-minerals, and do not have a specific chemical composition. Mineral Summary • Minerals have an orderly arrangement of atoms. • Rocks are aggregates (mixtures) of minerals. • Most minerals are compounds of two or more elements. • The properties of a mineral are derived from the elements it is comprised of. • Minerals have Ionic or Covalent lattices. • Generally considered inorganic. Key Idea 1: Minerals are natural resources that are important to Australia’s economy Define the term mineral Minerals in Australia • Minerals are Australia's largest export. The Australian Bureau of Statistics reports that at June 2012 the mining industry employed around 266 000 people directly. • Australian mining companies trade freely in the global marketplace, exporting goods on a commercial basis around the world with principal markets in China, Japan, South Korea and India. • Australia has the world's largest resources of gold, iron ore, lead, nickel, rutile, uranium, zinc and zircon as well as the second largest resources of bauxite, cobalt, copper, ilmenite, niobium, silver, tantalum and thorium. Australia's resources of black coal, brown coal, magnesite, tungsten, lithium, manganese ore, rare earths and vanadium are ranked in the top five in the world. Minerals in Australia • Australia is one of the top mineral producers in the world and has a large resource inventory of most of the world's key minerals commodities. • Australia is the world's leading producer of bauxite, ilmenite, iron ore, rutile and zircon; • The second largest producer of gold, lead, lithium, manganese ore and zinc; • The third largest producer of uranium; • The fourth largest producer of black coal (also the largest exporter), nickel and silver; • The fifth largest producer of cobalt, copper and diamond Australian Government, Geoscience Australia http://www.ga.gov.au/scientific-topics/minerals/basics Some common metals • Gold? 0.0000004% Mining Techniques • Surface mining – Remove surface vegetation, dirt & layers of bedrock – Open-pit mining: • Recovery of materials from an open pit. • Quarrying: gathering building materials from an open pit mine – Strip mining: • Stripping surface layers off to reveal ore/seams underneath – Mountain top removal • Common for coal mining • Taking the top of a mountain off to reach ore deposits at depth Open-pit mining of diamonds Mining Techniques Subsurface mining – Digging tunnels or shafts into the earth to reach buried ore deposits – Ore (for processing) and waste rock (for disposal) are brought to the surface through the tunnels and shafts. – Drift mining • Horizontal access tunnels – Slope mining • Diagonally sloping access tunnels – Shaft mining • Vertical access shafts Mining in Australia • The mining industry is important to Australia. It brings in billions of dollars of export income. It provides work for over 750,000 Australians. It supports communities all across the country, today and into the future. Many different ores and minerals are mined throughout the country. • Mining has had a substantial environmental impact in some areas of Australia. Although mining services, equipment and technology are being exported, the mining sector employs 2.2% of the total labor force. Australian Pink Diamonds The Argyle Diamond Mine (far north of Western Australia) is the only known significant source of pink diamonds, producing over 90% of the world's supply. It additionally provides a large proportion of other naturally coloured diamonds, including champagne, cognac and rare blue diamonds. Argyle is currently transitioning from an open pit mine to an underground mine. Key Idea 1: Minerals are natural resources that are important to Australia’s economy • Define the term mineral • State how minerals are mined from the ground in the form of an ore • Discuss the economic considerations of mining an ore deposit Key Idea 2: Many metals are extracted from minerals • State the uses of some common metals and their importance to our everyday life Aluminium • Packaging • Transport • Building Copper • • • • • Electrical wires and cables Plumbing pipes Switches Pots and pans etc Coins (as an alloy) Nickel • Coins • Batteries • Hardener in alloys such as armour plating and machine parts • Anti-corrosion coating Iron • • • • Buildings Magnets Automobiles Household implements Key Idea 2: Many metals are extracted from minerals • State the uses of some common metals and their importance to our everyday life Aluminum--packaging, transport, building Beryllium--gemstones, fluorescent lights Copper--electric cables, wires, switches Feldspar--glass and ceramics Iron--buildings, automobiles, magnets Calcite--toothpaste, construction Reaction of alkali metals with water https://www.youtube.com/watch?v=HvVUtpdK7 xw The activities series song https://www.youtube.com/watch?v=DLlykUHH AcQ Topic 3: Metals and Metal Extraction (3 weeks) Topic 3: Metals and Metal Extraction Kahoot https://kahoot.it https://getkahoot.com/