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Name _Answers___________________________ Date ____________________ Hour _________ Chemical Practice Examples: Oxidation numbers need to be balanced / canceled out! 1. If an element has +3 oxidation #, it has _3_ valence electrons and wants to (lose/gain) _3_ electrons. +2 oxidation means there is _2_ valence electrons and wants to (lose/gain) _2_ electrons. - 2 oxidation means there is _6_ valence electrons and wants to (lose/gain) _2_ electrons. - 1 oxidation means there is _7_ valence electrons and wants to (lose/gain) _1_ electrons. +1 oxidation means there is _1_ valence electrons and wants to (lose/gain) _1_ electrons. The noble gasses have _full_ valence electrons and want to (lose/gain) _0_ electrons. 2. What is ionic bonding? Ionic bonding describes the process where electrons are transferred between elements creating oppositely charged ions that then are attracted to each other. 3. What is the definition of an oxidation number? Oxidation numbers are the charges of an ion. So, an oxidation number includes both a charge (positive or negative) and a number. 4. If an element has an oxidation number of +2, what will it want to do? Those elements will want to lose 2 electrons. 5. Hydrogen cannot combine with Neon to form a compound. Why? Neon is a noble gas, meaning that it already has a full valence. As a result, neon is already stable and does not want to gain or lose electrons. 6. Calcium and Potassium cannot combine to form a compound. Why? Calcium has an oxidation number of +2, meaning it would like to lose 2 electrons. And, potassium has an oxidation number of +1, meaning it would like to lose 1 electron. Transferring electrons is not possible and like charges repel. 7. In order for an ionic bond to happen, a _+_ ion must mix with a _-_ ion. 8. If an element loses three electrons, what is its new charge? That element would have a charge of +3. 9. How can you explain why the elements in Carbon’s family have either +4 or – 4 oxidation number? It is equally easy for elements with 4 valence electrons to lose or gain 4 electrons so depending on what happens, they can have either a positive or negative charge. 10. To balance out the oxidation #’s for a +1 and -2 bond, there needs to be 2 (+1) for every 1 (-2). To balance out the oxidation #’s for a +3 and -3 bond, there needs to be _1_ (+3) for every _1_ (-3). To balance out the oxidation #’s for a +2 and -1 bond, there needs to be _1_ (+2) for every _2_ (-1). To balance out the oxidation #’s for a +1 and -4 bond, there needs to be _4_ (+1) for every _1_ (-4). To balance out the oxidation #’s for a +2 and -3 bond, there needs to be _3_ (+2) for every _2_ (-3). To balance out the oxidation #’s for a +3 and -2 bond, there needs to be _2_ (+3) for every _3_ (-2). 11. What will happen if you mix some of an element that wants to gain three electrons with some that wants to lose one electron? [Hint: consider the ions each would form.] An element that wants to gain 3 electrons would acquire a charge of -3. An element that wants to lose 1 electron would acquire a charge of +1. These elements would form an ionic bond. Each molecule of the compound would have one -3 ion and three +1 ions. 12. What will happen if you mix together a bunch of two different elements, one with an oxidation of +2 and one with the oxidation of – 1? [Hint: the oxidation numbers need to cancel out.] An ion with an oxidation of +2 would form an ionic bond with an ion with oxidation of -1. Each molecule of that compound would have one +2 ion and two -1 ions. 13. What will happen if you mix +2 ions with – 3 ions? [Hint: the oxidations need to cancel out.] Again, an ionic bond would form. The molecule of the compound form would contain three +2 ions and two -3 ions. 2 14. Write in the Oxidation numbers of the elements on the left column and the top row on the table below. Then, write the formula of the combination of ions on the left column and the top row. Study the ones done for you. P _-3_ S _-2_ F _-1_ Li _+1_ Li3P Li2S LiF Be _+2_ Be3P2 BeS BeF2 Al _+3_ AlP Al2S3 AlF3 Cu +1 Cu3P Cu2S CuF Cu +2 Cu3P2 CuS CuF2 Fe +2 Fe3P2 FeS FeF2 Fe +3 FeP Fe2S3 FeF3 15. The metals in families 3 – 12 behave differently than the other families in terms of forming ions. Copper (Cu) and Iron (Fe) are examples of these metals. The oxidation number of these metals will be given to you. What is one simple observation you can make about one of these metal ions? Some of these metals have more than one oxidation number. 16. Take a guess…..why you think some metal ions might have two oxidation numbers? Answers may vary … It’s possible that these metals can have different electron arrangements and so have different valences. 17. What is a polyatomic ion? A polyatomic ion is an ion (charged particle) made of more than one atom. {Your polyatomic ions can be found on the back of your periodic table.} Formulas and Naming Compounds READ: Write the oxidation number for each ion (some are given). Write the formula for the ionic bond and the name of this new compound. Always write the cation (+ ion) first in the formula. Use the back of your periodic table to put the names of the two ions together. The names of the ions may be a little different to show that it is now in a compound. The chlorine ion is called chloride, bromine is bromide, sulfur is sulfide, oxygen is oxide….. If they will not combine, write NOT POSSIBLE. Ion with oxidation number Ion with oxidation number Compound formula Name of compound Mg +2 Br –1 MgBr2 Magnesium bromide H _+1_ Cl _-1_ HCl Hydrogen chloride Ca _+2_ Br _-1_ CaBr2 Calcium bromide 3 Ion with oxidation number Ion with oxidation number Compound formula Name of compound H _+1_ S _-2_ H2S Hydrogen sulfide Na _+1_ Ar _0_ Will not bond Not possible Ca _+2_ Na _+1_ Will not bond Not possible Fe +2 O _-2_ FeO Iron (II) oxide Fe +3 O _-2_ Fe2O3 Iron (III) oxide Cl _-1_ Be _+2_ BeCl2 Beryllium chloride Si _+4_ O _-2_ SiO2 Silicon oxide H _+1_ P _-3_ H3P Hydrogen phosphide Xe _0_ Mg _+2_ Will not bond Not possible P _-3_ Al _+3_ AlP Aluminum phosphide Cu +2 Cl _-1_ CuCl2 Copper (II) chloride Cu +1 Cl _-1_ CuCl Copper (I) chloride He _0_ F _-1_ Will not bond Not possible Br _-1_ Al _+3_ AlBr3 Aluminum bromide NH4 _+1_ PO4 _-3_ (NH4)3PO4 Ammonium phosphate NH4 _+1_ NO3 _-1_ NH4NO3 Ammonium nitrate SiO4 –4 K _+1_ K4SiO4 Potassium silicate B _+3_ OH _-1_ B(OH)3 Boron hydroxide Using the back of your periodic table, find the formulas for the following compounds containing polyatomic ions. First write the formula for each ion which is being bonded. Compound Name Ions in Compound Compound Formula Sodium Carbonate: Na +1 ___Na2CO3 +2 CO3 –2 -2 ___ Magnesium Sulfate: Mg _____SO4 _______ ___MgSO4____________ Potassium Nitrate: K+1_______NO3-1______ ___KNO3_____________ +3 -1 Aluminum Hydroxide: Al ______OH _______ ___Al(OH)3___________ Ammonium Carbonate: NH4+1_____CO3-2______ ___(NH4)2CO3_________ Iron (III) Oxide: Fe+3______O-2________ ___Fe2O3_____________ Sulfur Phosphate: S-2________PO4-3_____ ___Not possible________ Calcium Chlorite: Ca+2_______ClO2-1_____ ___Ca(ClO2)2__________ Hydrogen Hydroxide: +1 -1 H ________OH ______ 4 ___HOH______________ (H2O)