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Heat Mass Transfer (2007) 43:677–686 DOI 10.1007/s00231-006-0148-0 ORIGINAL Effect of vapor condensation on forced convection heat transfer of moistened gas Yongbin Liang Æ Defu Che Æ Yanbin Kang Received: 22 November 2005 / Accepted: 16 May 2006 / Published online: 14 June 2006 Springer-Verlag 2006 Abstract The forced convection heat transfer with water vapor condensation is studied both theoretically and experimentally when wet flue gas passes downwards through a bank of horizontal tubes. Extraordinarily, discussions are concentrated on the effect of water vapor condensation on forced convection heat transfer. In the experiments, the air–steam mixture is used to simulate the flue gas of a natural gas fired boiler, and the vapor mass fraction ranges from 3.2 to 12.8%. By theoretical analysis, a new dimensionless number defined as augmentation factor is derived to account for the effect of condensation of relatively small amount of water vapor on convection heat transfer, and a consequent correlation is proposed based on the experimental data to describe the combined convection–condensation heat transfer. Good agreement can be found between the values of the Nusselt number obtained from the experiments and calculated by the correlation. The maximum deviation is within ±6%. The experimental results also shows that the convection–condensation heat transfer coefficient increases with Reynolds number and bulk vapor mass fraction, and is 1~3.5 times that of the forced convection without condensation. List of symbols A heat transfer area (m2) cp specific heat at constant pressure (J/(kg K)) Y. Liang Æ D. Che (&) Æ Y. Kang School of Energy and Power Engineering, Xi’an Jiaotong University, Xian 710049, China e-mail: [email protected] d D gm h Hfg m m¢ ¢ Nu P Pr q Q Re Sc Sh T W q tube outer diameter (m) diffusion coefficient (m2/s) mass transfer coefficient (kg/(m2 s) heat transfer coefficient (W/(m2 K)) latent heat of condensation (kJ/kg) mass flow rate (kg/s) interfacial condensate flux (kg/(m2 s) Nusselt number hd/k pressure (Pa) Prandtl number heat flux (W/m2) heat transferred (W) Reynolds number (ud/v) Schmidt number Sherwood number (gm d/q D) temperature (C) mass fraction density (kg/m3) Subscripts b bulk c cooling water conv convection cond condensation g bulk vapor–gas mixture i interface nc non-condensable gas pc pure component sat saturation tot total w outer tube wall v vapor 123 678 Heat Mass Transfer (2007) 43:677–686 1 Introduction The energy loss in a boiler is mainly due to the heat released by the exhaust flue gas to the atmosphere. For a conventional boiler, in order to avoid low temperature corrosion, the exit flue gas temperature is usually higher than 150C, sometimes as high as 200C. At such temperatures, the water vapor entrained in the exhaust flue gases does not condense, so that the released heat consists of both sensible heat and latent heat. Recently, for the purpose of environmental protection, the Chinese government has enforced the energy policy that will lead to a larger market share of gas fired boilers in China. As fuel gas, natural gas in particular, contains more hydrogen atoms instead of carbon, compared to anthracite or bituminous coal, larger fraction of water vapor in combustion products results. Generally the volumetric fraction of the water vapor in flue gases can be in the range of 10–20%, large amount of latent heat of vaporization is lost to the atmosphere. Figure 1 shows the theoretical relationship of boiler efficiency based on lower heating value versus exit flue gas temperature. It can easily be seen that after a relatively gradual change in the temperature range of 60– 180C, the boiler efficiency rises sharply at the dew point (about 60C) and a value larger than 100% can be attained at very low exhaust gas temperatures [1]. As such, it is profitable to recover the latent heat by condensing as much water vapor as possible in the flue gases from a gas fired boiler. There is a large amount of literature available on condensation, but the literature directly related to the content in this paper is few. Literature survey shows that the condensation of vapor in vapor–gas mixture was studied long time ago, but all the investigations hM 1:17 ¼ 0:11 ; hNu C ð1Þ where C is the air mass fraction and ranges from 0.002 to 0.04. Later, Hampson [3] studied the condensation of steam on a vertical plate, using nitrogen as the noncondensable gas instead of air, and suggested that the heat transfer ratio should vary as: hM ¼ 1:2 20:0X; hNu ð2Þ where the weight ratio X of nitrogen to steam ranges from 0 to 0.02. In terms of the data obtained for steam– air and toluene–nitrogen mixtures condensing on a horizontal pipe, Henderson and Marchello [4] proposed the ratio in the following form: hM 1 ¼H¼ : 1 þ C 1 y þ C 2 y2 hNu 108 Boiler efficiency, % (Based on lower heating value) conducted were on the condensation in the presence of a relatively small amount of non-condensable gases (approximately £20%), with the aim being at clarifying the effect of non-condensable gases during condensation. In the investigations of vapor condensation in the presence of non-condensable gases, it is a common practice to modify the classical Nusselt equation or other simplified equation by introducing a correction factor that takes into account the effect of non-condensable gases. Additionally, several empirical correlations and mechanistic models were derived [2–6]. Meisenburg [2], who investigated the effect of noncondensable gases on the condensation of steam on a vertical tube, found that the ratio of observed heat transfer coefficient, hM, to the heat transfer coefficient predicted by the Nusselt equation, hNu, could be described by the following equation: ð3Þ 106 Excess air ratio =1.05 104 102 100 Dewpoint 98 96 94 92 90 88 0 20 40 60 80 100 120 140 160 180 200 Exit flue gas temperature,°C Fig. 1 Relationship of boiler efficiency versus exit flue gas temperature 123 It can be seen that the treatment result in a polynomial expression for H in terms of the molar percentage of gas y. The experimental data were fitted by least square method to obtain the constants C1 and C2. Abdullah et al. [5] studied the condensation of steam and R113 on a bank of horizontal tubes in the presence of a non-condensable gas. They concluded that the detrimental effects on heat transfer were due to the reduction in vapor velocity and the presence of air (non-condensable gas). To take into account these adverse effects, an expression based on Nusselt equation for vapor side was derived as follows: Heat Mass Transfer (2007) 43:677–686 Nu ¼ a q2L ghfg d3 lL kL DT 679 1=4 ð4Þ where a was a constant to modify the Nusselt equation and was determined by experiments. Groff et al. [6] developed a correlation for the Nusselt number during laminar, forced-convection film condensation from steam–air and steam–hydrogen mixtures on horizontal isothermal plates, which is: Nux pffiffiffiffiffiffiffiffiffiffiffi ¼ Rex;L Nux pffiffiffiffiffiffiffiffiffiffiffi Rex;L ! Gi ; ð5Þ 0 pffiffiffiffiffiffiffiffiffiffiffi where Nux = Rex;L 0 was the value for pure vapor at the same T¥ and DT. Gi, which accounts for the heat transfer reduction due to the presence of the noncondensable gas, is a function of T¥, W¥ and DT. For the wet flue gas from a gas fired boiler, the water vapor volume fraction is only about 10–20% and the non-condensable gas mass fraction is lager than 80%. When latent heat recovery is performed, the correlations mentioned above are inappropriate. According to previous studies [7–12], the heat transfer coefficient in this situation is higher than that of the forced convection without condensation, but on the same order, and much lower than that of the condensation of pure steam. Therefore, the effect of water vapor condensation in the wet flue gas on convection heat transfer, rather than the effect of non-condensable gases during condensation, should be investigated. Unfortunately, there is a great shortage of investigations on this issue. By introducing the Colburn-Hougen method, Che et al. [8] analyzed the heat and mass transfer process of high moisture flue gases flowing downward in a bank of horizontal carbon steel tubes. They indicated that the influential factors of convective-condensation coefficient include the partial pressure of the vapor pv, the temperature of the outer tube wall Tw, the mixture temperature Tg, Re and Pr. Based on dimensional analysis, a dimensionless number Ch called condensation heat transfer factor was obtained to describe the effect of vapor condensation, which is expressed as: Ch ¼ TsatðpvÞ Tw ; Tg Tw ð6Þ where Tsat(pv) is the saturation temperature corresponding to the partial pressure of vapor pv. Finally, a normalized correlation of convection–condensation heat transfer was derived and expressed as: Nuh ¼ aReb Pr1=3 Chc : ð7Þ But there is a limitation of the factor Ch, i.e., a contradictory physical meaning will be induced for Ch, if the vapor fraction is extremely small. Whenever the vapor fraction is vanishing, the value of Tsat(pv) will be approaching even less than zero, and the value of Tsat(pv) – Tw can be minus. Therefore, Ch is only applicable to relatively high vapor fraction. In this paper, an in-depth research is conducted both theoretically and experimentally to investigate the forced convection condensation on a bank of horizontal tubes with vertical downflow of steam–air mixture. The effect of vapor condensation is considered. Firstly, by theoretical analysis, a new dimensionless number defined as augmentation factor is obtained to take into account the effect of condensation of relatively small amount of water vapor on convection heat transfer, and a consequent correlation is derived to describe the combined convection–condensation heat transfer. Secondly, experiments have been conducted to determine the unknown constants in the correlation, and to investigate the effects of various influential factors. The parametric study is conducted by varying the moistened air flow rate (Re) and temperature, the vapor mass fraction in the free mixture stream, the cooling water mass flow rate and temperature and the tube wall temperature. During the experiments, the air–steam mixture is used to simulate the flue gas of a natural gas fired boiler, the vapor mass fraction ranges from 3.2 to 12.8%. 2 Theoretical analysis 2.1 Fundamentals of heat and mass transfer There is a great difference between the condensation process in the presence of a non-condensable gas and that of pure vapor. In the analysis on the condensation in the presence of non-condensable gases, Colburn and Hougen [13] proposed that condensation mass transfer is controlled by diffusion across a thin film at which the accumulation of non-condensable gas occurs (noncondensable gas boundary layer). The temperature and pressure distributions of both situations are illustrated in Fig. 2. The solid and dashed lines represent the vapor–liquid interfaces in the cases of the condensation of pure vapor and the condensation of the vapor with non-condensables, respectively. When non-condensable gases are absent, the bulk vapor temperature Tb,pc and the liquid–vapor interface 123 680 Heat Mass Transfer (2007) 43:677–686 Non-condensable Interface gas boundary layer (pure component) Pure component Tb,pc= Tsat Ti,pc Coolant side Tw,pc Ti Tg With non-condensables Ptot Tc Tw Qtotal Tube wall Pi,v Pi,nc Pb,v In Eq. 9, hcv is the forced convection heat transfer coefficient due to sensible heat; in Eq. 10, m¢ ¢cond is the interfacial condensate flux, Hfg is the latent heat of vaporization of the vapor under the corresponding partial pressure. According to Newton’s law of cooling, the overall heat transfer coefficient hoverall can be determined by the following. hoverall ðTg Ti Þ ¼ hcv ðTg Ti Þ þ m00 cond Hfg : Pb,nc Interface (with non-condensables) Qconv Qcond As we know, forced convection heat transfer and mass transfer can be described by the Nusselt number Nu and the Sherwood number Sh as: Nu ¼ CRem Pr1=3 Condensate film ð11Þ 0 ð12Þ Fig. 2 Boundary layer temperature and pressure distributions Sh ¼ C0 Rem Sc1=3 ; temperature Ti,pc are identical and equal to the saturation temperature of pure vapor Tsat; when non-condensable gases exist, there is a drop between the vapor saturation temperature in the bulk and the temperature at the liquid–vapor interface, which is due to the reduction in vapor partial pressure (Pb,v > Pi,v) and can be considered as a penalty in the condensation process. It can be imagined that the vapor must diffuse through the non-condensable gas boundary layer for it to attain the liquid–vapor interface, so that the vapor concentration difference between the bulk and the interface is the driving force of mass transfer. In addition, there is a drop from bulk gas temperature Tg to the interfacial temperature Ti, which is the driving force of convection heat transfer. Based on this model, a heat balance at the liquid–gas interface between the heat transfer through the noncondensable gas boundary layer and the heat transfer through the condensate film can be obtained. As the heat transfer though non-condensable gas boundary layer consists of two components: the sensible heat flux qconv due to temperature difference between bulk vapor–gas mixture and interface, and the latent heat flux qcond given up by the condensing vapor, therefore where Re=ud/v is the Reynolds number. In the investigation on forced convection heat transfer inside tube or over tube bundles, it is a common practice to define the Reynolds number by taking the tube diameter or equivalent diameter as the characteristic dimension, regardless of whether or not the fluid flow is one-dimensional or two-dimensional. This definition has been used by many scholars. For example, Zukauskas [14] and Grimson [15] used the definition of the Reynolds number based on the tube diameter when they conducted their study on forced convection heat transfer on horizontal tube bundles. For a given process, if the boundary conditions are same, there is an analogy between the heat transfer and the mass transfer [16, 17]. Thus the coefficients and the exponents in Eqs. 12 and 13 should be identical, i.e., C=C¢, m=m¢. Therefore qtot ¼ qconv þ qcond ; where h and gm are the heat and mass transfer coefficients, respectively, Le=Pr/Sc=a/D is known as the Lewis number [18]. ð8Þ where qconv and qcond can be expressed, respectively, as follows: qconv ¼ hcv ðTg Ti Þ qcond ¼ m00 cond Hfg : 123 ð9Þ ð10Þ ð13Þ Nu ¼ Sh 1=3 Pr Sc ð14Þ h ¼ gm 1=3 a 2=3 D k ¼ qcp ¼ qcp Le2=3 ; a D D ð15Þ 2.2 Convection–condensation heat transfer As mentioned above, the vapor must diffuse through the non-condensable gas boundary layer to reach the Heat Mass Transfer (2007) 43:677–686 681 liquid–vapor interface, so that a mass balance at the interface yields the following equations: m00 cond @Wv ¼ qD þ Wv;i ðm00 tot Þi @y i ð16Þ m00 nc ¼ @Wnc qD þ Wnc;i ðm00 tot Þi ; @y i ð17Þ where (m¢ ¢tot)i is an imaginary compensatory mixture flow at the interface to account for the situation that the diffusion process is in one direction only, Wv,i and Wnc,i are the vapor and gas mass fraction at the interface, respectively. As the condensate surface is impermeable to the non-condensable gases, the value of m¢ ¢nc should be zero, and Eq. 17 can be simplified as @Wnc qD ¼ Wnc;i ðm00 tot Þi : @y i ð18Þ In this study, the mixture is composed of two components: condensing vapor and non-condensables, thus the following correlation can be obtained Wnc þ Wv ¼ 1: ð19Þ Therefore @Wnc @Wv þ ¼ 0: @y @y m cond hcd ¼ m00 cond Hfg 1 ¼ gm B Hfg : ðTg Ti Þ ðTg Ti Þ By using the definition of the Nusselt number, Nucd=hcd d/k, Eq. 24 can be rewritten as Nucd ¼ gm B Hfg d : ðTg Ti Þk By using the definition of the Sherwood number, Sh=gm d/q D, Eq. 25 can be written as the following dimensionless form Nucd ¼ Sh B Hfg Pr ; Sc Cp ðTg Ti Þ m00cond ¼ 1 Wv;i ð26Þ where Pr/Sc is the Lewis number, represented by Le, the group Hfg /Cp (Tg – Ti) is the ratio of the phase change energy to the sensible heat transfer, and is known as the Jakob number, represented by Ja [18]. According to the work of Osakabe [12], under the present situation, the boundary conditions are same, and the heat and mass transfer are analogical, therefore the expressions are identical, i.e., the relevant coefficients and exponents in Eqs. 12 and 13 should be the same. Substituting Eq. 13 into the above equation yields the following correlation ð21Þ Nuoverall ¼ hoverall d ðhcv þ hcd Þd ¼ ¼ Nucv þ Nucd : k k ð28Þ i ð27Þ The Nusselt number for the overall heat transfer coefficient of both sensible and latent components can be obtained as Simplifying Eq. 21 gives v qD @W @y ð25Þ Nucd ¼ CRem Pr1=3 Le2=3 B Ja: @Wv qD @Wv ¼ qD þ Wv;i : Wnc;i @y i @y i ð24Þ ð20Þ Combining Eqs. 16, 18 and 20 and rearranging yield the equation of condensate flux at the interface as follows: 00 Therefore From Eqs. 12 and 27, Eq. 28 can be rewritten as ðWv;b Wv;i Þ ¼ gm B ¼ gm ð1 Wv;i Þ ð22Þ where gm is the mass transfer coefficient, and B=(Wv,b – Wv,i)/(1 – Wv,i) is the driving force of mass transfer. The condensation heat transfer coefficient hcd accounting for the latent heat transfer can be defined as follows: hcd ðTg Ti Þ ¼ m00 cond Hfg ð23Þ Nuoverall ¼ CRem Pr1=3 ð1 þ Le2=3 BJaÞ: ð29Þ Equation 29 is the normalized correlation of convection–condensation heat transfer, in which C and m are constants to be determined by experimental data. The Prandtl number Pr and the Schmidt number Sc in the investigated range can be considered to be invariant, and calculations have shown that Pr 0.696 and Sc 0.670, therefore, Le=Pr/Sc 1.04. On the 123 682 Heat Mass Transfer (2007) 43:677–686 other hand, as the non-condensable gas mass fraction is above 80% in the range investigated in this paper, according to previous studies [11], the thickness of the condensate film is very thin and the heat resistance of the condensate film is negligible, the tube wall temperature can be considered to be equal to the temperature at the interface, i.e., Ti=Tw. The work of Osakabe [12] shows that under the present situation the thickness of the condensate film is within the range of 0.04–0.17 mm, and it is also indicated that the temperature difference across the film is less than 2.5 K, the treatment to neglect the condensate film will lead to very small deviation. Some other researchers, such as Jia et al. [9], Cao [7], used this treatment as well, and good performance could be found. A qualitative analysis on Eq. 29 shows that if the vapor mass fraction is zero, i.e., Wv,b=Wv,i=0, B=(Wv,b – Wv,i)/(1 – Wv,i) will be equal to zero, and (1+Le2/3 BJa) is reduced to unit. Consequently, Eq. 29 is reduced to the form of Nuoverall=CRem Pr1/3, which is the formula for single-phase convection heat transfer (without condensation). By an in-depth analysis, (1+Le2/3 BJa) can be considered as an augmentation factor to account for the enhancement effect induced by the condensation of water vapor on forced convection heat transfer. In the condensation process, the mass fraction Wv,i at the interface is maintained to be equal to the value at the saturated gas state corresponding to the interface temperature Ti. 10 T I-8 5 T I-7 6 E-20 E-8 3 E-21 E-12 TI-9 12 Figure 3 is the schematic of the experimental apparatus. As shown in Fig. 3, air is blown by forced draft fan into the channel in which electric heaters are located. After preheated in the primary heater (right half of the channel), the air meets the steam supplied from an electrically heated boiler at the middle of the channel. The air–steam mixture flows over the secondary heater (left half of the channel) where it is heated to the temperature as required, and then flow downwards though the heat exchanger where condensation occurs. After the steam entrained in the gas is condensed, latent heat is released and reclaimed. The condensed water is collected by a tray and is weighed. The cooling water flows into the heat exchanger from bottom, in a counter-flow arrangement with the air–steam mixture stream. The flow rate of air, steam and cooling water are changed by regulating valves and is measured by pitot tube flow meter, vortex shedding flow meter and rotameter, respectively. The room temperature, the moistened gas stream temperature, the condensing heat exchanger tube wall temperature and the cooling water temperature are measured by nickel chromium– nickel silicon thermocouples for its high sensitivity and good thermo-electrical performance. The thermocouple signals are transferred to a personal computer for analysis. For safety, electrical power is adjusted by voltage regulator during the operation. In the experiments, carbon steel tubes are employed. Show in Fig. 3 is the arrangement of test tubes. The heat exchanger consists of an in-line tube bank of 3 rows and 60 stages in total. The detailed geometrical parameters are listed in Table 1. 2 The parametric study is conducted by varying the moistened air flow rate (Re) and temperature, the vapor mass fraction in the free mixture stream, the cooling water mass flow rate and temperature and the E-7 FI 8 3.1 Test rig 3.2 Measurement and data reduction 4 E-9 3 Experimental 9 11 1 Table 1 Geometrical parameters of heat exchanger 7 Fig. 3 Experimental apparatus. 1 Forced draft fan; 2 Pitot tube flow meter; 3 Electric boiler; 4 Vortex shedding flow meter; 5 Heating up section; 6 Condensing heat exchanger; 7 Water pump; 8 Rotameter; 9 Condensed water collecting pan; 10 Thermocouples; 11 Transformer; 12 Electrical heater 123 Out side diameter Wall thickness Cross-section Transverse pitch Longitudinal pitch Number of tubes 20 mm 2 mm 500 mm · 120 mm 40 mm 40 mm 180 Heat Mass Transfer (2007) 43:677–686 683 Table 2 Experimental ranges and uncertainties 4.6 Uncertainty Range Coolant flow rate Moistened air velocity Free stream vapor mass fraction Inlet coolant temperature Outlet coolant temperature Inlet moistened air stream temperature Tube wall temperature 0.5 m3/h 0.4 m/s 0.3% 0.1C 0.1C 0.1C 1–4.5 m3/h 4–7 m/s 3.2–12.8% 10.7–15.1C 17.7–29.7C 106.2–154.9C 0.1C 12.3–42.1C (1+Le2/3BJa)=1.67 4.4 lnNuoverall Parameter 4.2 4.0 3.8 tube wall temperature. The ranges and uncertainties of the measurements are given in Table 2. During steady operations, the total heat Qtot transferred from the steam–air mixture is equal to the heat absorbed by the cooling water and can be calculated by Qtot ¼ mc cp;c ðT 0 c T 00 c Þ; ð30Þ where mc is the mass flow rate of the cooling water, cp,c is the specific heat of cooling water, T¢c and T¢ ¢c are the outlet and inlet temperatures of the cooling water, respectively. The overall heat transfer coefficient for convection– condensation heat transfer is obtained by: hoverall ¼ Qtot w Þ: AðTg T ð31Þ w are the mean temperatures of steam– g and T where T air mixture and outer tube wall, respectively. Wilke method [19] and Lindsay method [20] are used to calculate the viscosity and heat conductivity of the mixture, respectively. Other physical properties such as density can be obtained in terms of the law of mixed gases. The method of Kline and McClintock [21] is employed to evaluate the uncertainties of the experimental results. The maximum uncertainty in the Reynolds number was estimated to be 8% and the uncertainty in the Nusselt number was 8.5% and the maximum uncertainty in the total heat transfer was 8.3%. 4 Results and discussions Experiments have been performed to examine the effects of various factors, including mixture flow rate (Reynolds number Re), mass fraction of water vapor Wv,b etc, on the convection–condensation heat transfer coefficient. Based on the experimental data, the effects of the Reynolds number Re and the augmentation factor are discussed. The relationship of the Nusselt number 3.6 8.0 8.2 8.4 lnRe 8.6 8.8 Fig. 4 Relationship between Nuoverall and Re Nuoverall versus Re and (1+Le2/3 BJa) are shown in Figs. 4 and 5. It can be seen that Nuoverall is increased with Re and (1+Le2/3 BJa). If Re is raised, the sensible heat transfer is enhanced. From Eq. 29, it can be found that for a given value of (1+Le2/3 BJa), the increase of sensible heat transfer leads to the increase of total convection–condensation heat transfer. In the expression of the augmentation factor (1+Le2/3 BJa), Ja=Hfg /Cp (Tb – Ti) is the ratio of the phase change energy to the sensible heat transfer; B=(Wv,b – Wv,i)/(1 – Wv,i) is the driving force of mass transfer, and its value increases as the vapor mass fraction increases. In the case of higher vapor mass fraction (i.e., higher value of B), more water vapor can be condensed and more latent heat can be released, the overall heat transfer coefficient is higher. Therefore, higher value of (1+Le2/3 BJa) means higher value of Nuoverall. Figure 6 shows the relationship between Nuoverall and Wv,b. It can be found that Nuoverall is increased with increased Wv,b, which agrees well to the above discussions. A comparison can be made between the condensation factor Ch=(Tsat – Tw)/(Tg – Tw) proposed in [8] and (1+Le2/3 BJa). In Ch, the numerator Tsat – Tw is the deference between the saturation temperature corresponding to the partial pressure of water vapor and the tube wall temperature, i.e., the tube wall subcooling, whose physical meaning is the driving force of mass transfer. It has the same meaning as B in (1+Le2/3 BJa). The values of both Hfg and Cp in the experimental range vary little and can be considered to be constant, thus Ja is a function of Tg – Tw only, which can be reduced to the denominator in Ch. Therefore, generally, it can be concluded that Ch and (1+Le2/3 BJa) has the same physical meaning. 123 684 Heat Mass Transfer (2007) 43:677–686 140 2.6 2.4 Re=5600 Re=5600 100 2.2 (1+Le2/3BJa) Nusselt number Nuoverall 120 80 60 40 2.0 1.8 1.6 1.4 20 1.2 0 0.0 0.4 0.8 1.2 1.6 2.0 2.4 2.8 0.02 0.04 (1+Le2/3BJa) Fig. 5 Relationship between Nuoverall and (1+Le2/3 BJa) ð32Þ Nusselt number Nuoverall Re=5600 120 100 80 60 40 0.02 0.04 0.06 0.08 0.10 0.12 Water vapor mass fraction Wv,b Fig. 6 Relationship between Nuoverall and Wv,b 123 Equation 32 is applicable to the parametric range as follows: 0.032 < Wv,b < 0.128 3,900 < Re < 7,300 1.21 < (1+Le2/3 BJa) < 2.57. This paper mainly investigates the heat and mass transfer of high moistened gas in the condensing heat exchanger of a condensing boiler. Therefore, the velocity corresponding to the chosen Re falls in the range recommended in boiler design, and the correlation can be applied to the design practice of condensing boiler. Of course, more experimental data will be needed to apply the correlation in a wider range of Re. Figure 8 shows the comparison of the Nusselt numbers calculated by Eq. 32 with those obtained by Nusselt number Nuoverall (Experimental) 160 140 0.14 Fig. 7 Relationship of (1+Le2/3 BJa) versus Wv,b But there is a disadvantage for the condensation factor Ch. As mentioned above, when the vapor mass fraction is extremely small, the value of Ch will be zero or be minus. An improvement of the augmentation factor lies in that it overcomes the disadvantage of Ch. Shown in Fig. 7 is the relationship of (1+Le2/3 BJa) and Wv,b, it can be seen that (1+Le2/3 BJa) decreases continuously as Wv,b decreases and approaches 1.0 at very low Wv,b. By employing the multivariate regression method, the unknown constants in Eq. 29 can be determined by experimental data, and the final correlation is obtained as follows Nuoverall ¼ 0:0641Re0:772 Pr1=3 ð1 þ Le2=3 BJaÞ: 0.06 0.08 0.10 0.12 Water vapor mass fraction Wv,b 0.14 140 120 100 80 60 40 40 60 80 100 120 Nusselt number Nuoverall (Calculated) Fig. 8 Calculated and experimental Nuoverall 140 Heat transfer coefficient hcv, hoverall (W/m2K) Heat Mass Transfer (2007) 43:677–686 685 180 160 3. hoverall (Vapor-air Mixture) hcv (Air) 140 120 100 80 60 40 20 0 0.02 0.04 0.06 0.08 0.10 0.12 Water vapor mass fraction Wv,b 0.14 condensable gases on the condensation of vapor, should be emphasized. By theoretical analysis, a new dimensionless number defined as augmentation factor (1+Le2/3 BJa) is obtained to take into account the effect of condensation of relatively small amount of water vapor on convection heat transfer. Based on the experimental data, a simple correlation to describe the combined convection–condensation heat transfer is put forward, which is expressed as Nuoverall=0.0641Re0.772 Pr1/3 (1+Le2/3 BJa) in the experimental range. Satisfactory agreement has been obtained, and the maximum deviation is within ±6%. Fig. 9 Comparisons of heat transfer characteristic of air and vapor–air mixture References the experiments. The maximum deviation is within ± 6%, which shows satisfactory agreement. The experiments on the heat transfer characteristics of forced convection of air (without condensation) have been conducted as well in comparison with the heat transfer characteristic of vapor–air mixture, as shown in Fig. 9. The experimental conditions are Re=5,600, Pr=0.696, (1+Le2/3 BJa)=1.59. It can be found that the convection–condensation heat transfer coefficient is 1~3.5 times higher than that of the forced convection without condensation, and they are on the same order. The experimental results in this paper are close to the results reported in [7–9]. 5 Conclusions 1. 2. The convection–condensation heat transfer coefficient increases as the gas–vapor mixture flow rate and the mass fraction of water vapor increase, and in the experimental range, it is 1~3.5 times that of the forced convection heat transfer without condensation. The convection–condensation of high moisture flue gas differs greatly from the vapor condensation in the presence of a small amount of non-condensable gases. In the former situation, the heat transfer coefficient of sensible heat is on the same order as that of latent heat, and it can be considered that the condensation of vapor enhances the overall heat transfer. Therefore, the enhancement effect of vapor condensation on the convection heat transfer, instead of the detrimental effect of non- 1. Che DF, Liu YH, Gao CY (2004) Evaluation of retrofitting a conventional natural gas fired boiler into a condensing boiler. 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