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Cornell Notes Topic:___________________________________ Questions Notes Atomic Theory History The Parade of Old Guys Who Discovered the Atom Who first theorized atoms? The History of the Atom • Fourth century BC, Greek philosopher named Democritus was the first to theorize the existence of atoms. • Democritus did not have the technology to test his Atmos Theory and it was not widely accepted. “Atmos” is Greek for indivisible What was the first atomic theory of atoms supported by data? The History of the Atom • 1805 - John Dalton I took Lavoisier's work and made an atomic • the first atomic theory theory out of it. supported by scientific evidence • Used evidence derived from the Law of Conservation of Mass, the Law of Definite Proportions, and the Law of Multiple Proportions • called the Billiard Ball atomic model Dalton’s Atomic Theory States: 1)Matter is made of small particles called atoms. 2)All atoms of an element are identical in size, mass, and other properties; atoms of different elements are different in size, mass, and other properties. 3) Atoms can't be subdivided, created, or destroyed. 4) Atoms combine in whole-number ratios to form chemical compounds. 5) In chemical reactions, atoms are combined, separated, or rearranged. Atomic Structure • Not all aspects of Dalton’s atomic theory have proven to be correct. We now know that: • Atoms are divisible into even smaller particles: protons, neutrons & electrons. • One element can have atoms with different masses- isotopes. What was the first subatomic particle discovered? Atomic Structure Discovery of the Electron • J. J. Thomson - English physicist. 1897 • Thomson discovered the electron • Used a cathode ray tube and a magnet called the plum pudding atomic model Plum pudding is like oatmeal with raisins. The raisins are the negative particles, and the oatmeal is positive. Thomson’s Plum Pudding Model • Said the atom was like plum pudding: • A blob of positive stuff with the negative electrons scattered throughout How did Thompson discover the electron? Cathode Ray Tube Experiment Copy This! _ cathode voltage source + vacuum tube anode Cathode Ray Tube Experiment Copy This! _ voltage source + When turned on, the tube shoots a beam of light from the cathode to the anode. Cathode Ray Tube Experiment Copy This! _ voltage source + + When Thomson added a magnetic field, the beam bent toward the positive pole. Watch this video of the Cathode Ray experiment Click the button Watch Video Or copy & paste this address into your web browser: http://www.youtube.com/watch?v=O9Goyscbazk How did Einstein prove the existence of atoms? Einstein’s Atomic Proof Brownian Motions- irregular, random motions of pollen particles floating in water. In 1905 Einstein proved mathematically that Brownian Motions were caused by the atoms in the liquid impacting on the larger suspended particles. “Brownian motions are caused by moving atoms.” “Therefore atoms must exist” Who discovered the nucleus? Atomic Structure Discovery of the Atomic Nucleus • In 1911Ernest Rutherford discovered the nucleus. • The gold foil experiment led to the Nuclear Model of the atom Rutherford’s Nuclear Model • An atom has a central, small, dense positive nucleus • Electrons revolve around the nucleus •Most of the atom’s volume is empty space • Most of the atom’s mass is in the nucleus How was the nucleus discovered? Atomic Structure The Gold Foil Experiment: • Rutherford used Alpha particles positively charged pieces given off by uranium • Shot them at gold foil which can be made a few atoms thick • When the alpha particles hit a fluorescent screen, it glows. Lead block Polonium Fluorescent Screen Gold Foil Copy This! What he expected What he got Copy This! Watch this video of the Gold Foil experiment Click the button Watch Video Or copy & paste this address into your web browser: http://www.youtube.com/watch?v=Q8RuO2ekNGw How he explained it • Atom is mostly empty space • Small dense, positive particle at center • Alpha particles are deflected by it if they get close enough + How were electron energy levels discovered? Bohr’s Planetary Model • In1913 Niels Bohr replaced the Nuclear model with the Planetary Model. The Planetary Model is often called the Bohr Model. •Bohr studied the light waves given off by hydrogen plasma to calculate the energy of hydrogen’s electrons as it moved from one orbit to the next. Bohr’s Planetary Model • According to Bohr’s model, electrons can be only certain distances (orbits) from the nucleus, like planets orbiting a star. • Each orbit corresponds to a certain quantity of energy that an electron can have. Bohr’s Planetary Model An electron will gain energy as it moves from a low to a high orbit and lose energy as it moves from a high to low orbit. This quantum of energy is seen as light. Watch this video of the Bohr Model Click the button Watch Video Or copy & paste this address into your web browser: http://www.youtube.com/watch?v=mRNNccii-No What is the current atomic theory? Electron-Cloud Model Electron-Cloud Model/ Standard Model- the current theory of the atom •Nucleus: contains protons & neutrons held together by the strong nuclear force •The exact location of individual electrons cannot be determined Orbitals • In this model, electrons are located in orbitals, regions within specific energy levels in the electron cloud. • Orbitals are regions where electrons are likely to be found.