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Double Certificate GCSE Science Pack 3 Unit 2 The structures of atoms There are only about 109 different kinds of atoms which make up the entire universe (see Unit 3). Every atom has the same basic structure and is in two parts: Nucleus Electron ‘cloud’ containing ‘orbiting’ electrons Chemical reactions involve interactions between the electron clouds of different atoms. The cloud is made up of shells – like the inside of an onion. e- The second shell can hold up to eight electrons e- e- The first shell can hold up to two electrons e- e- e- e- e- The third shell can hold up to eight electrons e- ee- e- Nucleus e- e- e- e- e- e- The three innermost electron shells – e- represents one electron Since electrons have almost no mass, practically all the mass of an atom is made up of the protons and neutrons in its nucleus. However, the nucleus of an atom has no influence on chemical activity. The nucleus is made up of a cluster of protons and neutrons. Each proton has one positive (+) charge; each neutron has no charge. Proton Neutron The units of mass for atoms are atomic mass units (amu). • The mass number of an atom = the number of protons + neutrons in the nucleus. • The atomic number of an atom = the number of protons in the nucleus. • The mass number - the atomic number = the number of neutrons in the nucleus. Particle Mass (amu) Charge proton (p) 1 1 neutron (n) 1 0 electron (e) almost nil -1 The nucleus of an atom of sodium contains 11 protons and 12 neutrons. There are 11 electrons in its shells – 2 in the first, 8 in the second and 1 in the outer. The atom of sodium can be represented by the symbol 23 11Na where 11 is the atomic number and 23 is the atomic mass. The total number of (-) electron charges in the cloud exactly equals the number of (+) proton charges in the nucleus. So there is no overall charge on an atom – it is neutral. When different kinds of atoms react with each other, they upset this neutral condition by exchanging or sharing electrons from their clouds – see Units 12 and 13. Pearson Publishing, Chesterton Mill, French’s Road, Cambridge CB4 3NP 5 Double Certificate GCSE Science Pack 3 Unit 2 5 Atoms of different elements can join together to form chemical compounds. To do this the atoms: Questions Tick the box next to the correct answer. 1 Atoms of elements: A B C D n n n n have an overall positive charge are neutral overall have an overall negative charge are always charged either positive or negative A B C D join their nuclei together share their outer electrons exchange nuclei bond protons with their partner’s electrons n n n n 6 Atoms of different elements must have: 2 The atomic number of an element tells you: A B C D the number of protons in its nucleus the number of neutrons in its nucleus the number of electrons in its nucleus the number of electrons in its shells n n n n 3 An atom of aluminium can be represented by the symbol 27 13Al. Which line in the table gives the correct number of protons, neutrons and electrons in an atom of aluminium? Protons Neutrons Electrons A 13 14 13 B 14 13 27 C 13 13 14 D 14 27 13 A n B n C n D n 4 The mass number of an atom is the number of: A B C D protons in the nucleus neutrons in the nucleus all the particles in the atom the number of protons and neutrons together n n n n Pearson Publishing, Chesterton Mill, French’s Road, Cambridge CB4 3NP A different mass numbers B the same number of neutrons in their nuclei C different numbers of electrons in their shells D different numbers of protons in their nuclei n n n n 7 How many neutrons are there in an atom of fluorine 199 F? A B C D 9 19 10 28 n n n n 8 If a neutral atom of an element has 14 electrons and 19 neutrons, its atomic number is: A B C D 5 14 19 33 n n n n 6 Double Certificate GCSE Science Pack 3 Unit 9 Water and solutions Three-quarters of the Earth’s surface is covered by water. Water is sometimes called a ‘universal solvent’ because so many substances can be dissolved in it. Almost all chemical reactions in biological systems take place in solution in water (in aqueous solution (aq)). Water also has great importance as a solvent and as a coolant in industry. The water cycle The ‘water cycle’ is what keeps an approximately constant amount of water available for us to use. Used in factories and homes Rain, hail and snow return water to the surface Water table Plants transpire Some water enters the ground, forming a saturated layer of rock Water evaporates from sea and land Where the water table intersects the surface springs occur Water treatment plant Hardness in water As water ‘cycles’ through the soil, in particular, it dissolves minerals and salts and causes ‘hardness’; this makes it difficult for soap to form a lather and also produces a scum. SO42- Cl- Ca2+ HCO3- Mg2+ Permanent hardness Temporary hardness Softened by: Softened by boiling A Adding ‘washing soda’ (Na2CO3) (cheap and convenient) B Using ion exchange resins (eg Permutit and others) which remove Ca2+ and Mg2+ (inexpensive but tedious) Ca(HCO3)2 (aq) CaCO3 (s) + H2O(l) + CO2 (g) Scale C Distillation (very expensive) Salts and minerals in the soil Advantages and disadvantages of hard water Both types of hardness are found in most water supplies to varying degrees. ‘Hard’ water causes problems with ‘scaling’, which narrows pipes and reduces the efficiency of immersion heaters, and with poor lather formation from the use of soaps and detergents. ‘Hard’ water tastes nicer, however, and is healthier in several ways since it contains minerals which are good for the body. Pearson Publishing, Chesterton Mill, French’s Road, Cambridge CB4 3NP 33 Double Certificate GCSE Science Pack 3 Unit 9 Questions 6 Permanently hard water: Tick the box next to the correct answer. 1 The water cycle shows: A the network of rivers and canals in the UK B how water is purified C the steps in recycling water over the Earth D how climates change due to sea breezes n n n 25% 50% 75% 100% n n n n A calcium and magnesium ions dissolved in the water B isotopes of oxygen in the water molecules C bacteria in the water D the presence of any metal ions in the water n n n n 8 Hard water has some advantages over soft water. One of these is that hard water: n n n n A dissolves substances more quickly than soft water B is more efficient in central heating systems C boils quicker than soft water D contains minerals useful to the body n n n n 9 Which of the following statements is not correct? 4 Water is said to be ‘hard’ when it: A can be easily compressed B is not easy to find in drought conditions C contains many impurities D makes it difficult to get lather with soap n n n 7 Hardness in water is caused by: 3 Water is sometimes called a ‘universal solvent’ because: A the human body is over 90% water B so many substances can be dissolved in it C so much of the Earth’s surface is covered by it D it is essential for all plant and animal life n n 2 What percentage of the Earth’s surface is covered by water? A B C D A can be softened by adding ‘washing soda’ B can never be softened C must be boiled to remove hardness D means that there are impurities in the water n n n n A Using soft water is cheaper than using hard water B Temporarily hard water can be softened by boiling C Scum is the result of using soap with hard water D Soft water is better for plants than hard water n n n n 5 Temporarily hard water is caused by calcium and magnesium ions and also: A B C D hydrogencarbonate ions other metal ions minerals which cause scale sulphate and chloride ions n n n n Pearson Publishing, Chesterton Mill, French’s Road, Cambridge CB4 3NP 34